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排序方式: 共有171条查询结果,搜索用时 62 毫秒
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Andrei CM Walmsley JC Brinks HW Holmestad R Blanchard D Hauback BC Botton GA 《The journal of physical chemistry. B》2005,109(10):4350-4356
The microstructure of LiAlD(4) with TiCl(3).1/3(AlCl(3)) and VCl(3) additives has been studied during different steps of the decomposition process using electron energy loss spectroscopy and energy-dispersive X-ray spectroscopy in a scanning transmission electron microscope. Energy filtered transmission electron microscopy was used to show elemental distributions in the samples. The spatial distribution of the additives and the main elements within the alanate particles was examined with a resolution of a few nanometers. The analysis of the electron energy loss spectra reveals the chemical state of Al, O, and the additives. Ti and V do not appear to mix chemically with Al to a significant degree. V was found in high concentration in just a few particles, while Ti is more uniformly distributed. All the samples showed evidence of oxidation despite procedures being adopted to avoid exposing the material to air. The additives are oxidized in all the samples, and Al(2)O(3) forms a thin layer at the surface of the particles. This paper gives a comparison between samples at different stages of the decomposition process using different additives. 相似文献
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Results from LEED dynamical calculations performed on the Ni(100) c(2 × 2)C2H2 structure, produced by adsorption of C2H2 at about 273 K and 1.5 L exposure, are reported. Among the several model geometries tried, the most favoured one appears to be a distorted acetylene molecule with the midpoint of the CC bond (1.20 Å long) placed above the fourfold hollow site at a vertical distance 2.02 Å from the topmost Ni layer and with the CC axis itself tilted by 50° with respect to the surface normal in the [011] direction. In this geometry the NiC distance is 2.2 Å. 相似文献
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A new solution of the Einstein-Yang-Mills system with axial symmetry and cosmological constant is given here. This new metric, which in the absence of matter becomes the de Sitter universe, is the natural generalization of both a recent result of Perry for stellar (asymptotically flat) black holes and a well-knwn family of solutions of the Einstein-Maxwell system with nonvanishing cosmological constant given some time ago by Carter. Calculations have been carried out making extensive use of the coordinates found by Plebanski. 相似文献
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Bock C Paquet C Couillard M Botton GA MacDougall BR 《Journal of the American Chemical Society》2004,126(25):8028-8037
A rapid synthesis method for the preparation of PtRu colloids and their subsequent deposition on high surface area carbons is presented. The reaction mechanism is shown to involve the oxidation of the solvent, ethylene glycol, to mainly glycolic acid or, depending on the pH, its anion, glycolate, while the Pt(+IV) and Ru(+III) precursor salts are reduced. Glycolate acts as a stabilizer for the PtRu colloids and the glycolate concentration, and hence the size of the resulting noble metal colloids is controlled via the pH of the synthesis solution. Carbon-supported PtRu catalysts of controlled size can be prepared within the range of 0.7-4 nm. Slow scan X-ray diffraction and high-resolution transmission electron microscopy show the PtRu catalysts to be crystalline. The Ru is partly dissolved in the face-centered cubic Pt lattice, but the catalysts also consist of a separate, hexagonal Ru phase. The PtRu catalysts appear to be of the same composition independent of the catalyst size in the range of 1.2-4 nm. Particular PtRu catalysts prepared in this work display enhanced activities for the CH(3)OH electro-oxidation reaction when compared to two commercial catalysts. 相似文献
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Federico Mariani Vera Bernardoni Francesco Riccobono Roberta Vecchi Gianluigi Valli Tiziano Sanvito Bruno Paroli Alberto Pullia Marco A. C. Potenza 《Journal of nanoparticle research》2017,19(8):291
We apply to aerosols the optical method of Single Particle Extinction and Scattering recently proposed for characterizing liquid suspensions and specifically adapted to the aim. It provides simultaneous measurements of the real and imaginary parts of the field scattered in the forward direction by single airborne particles passing through a tightly focused laser beam. The intensity of transmitted light is collected in the forward direction, thus realizing a self-reference interferometric scheme relying on the fundamentals of the optical theorem. A high frequency (20 MS/s), extended dynamics (12 bits) sampling is performed by a cheap segmented photodiode, and a specific pulse shape analysis is exploited to validate the signals against a precise mathematical model. We show that accessing two independent physical quantities allows to exploit physical models to recover the aerosol size distribution from the measurement of the refractive index, either real or even complex. Laboratory measurements have been performed with polydisperse aerosols made of water droplets and NaCl in the submicron range, and the system has been accurately characterized. Examples of measurements of graphite nanoparticles and Pyrethrum smoke are shown. Limitations are discussed. 相似文献
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