Exploring Long-Term Anomalies in the Vegetation Cover of Peri-Urban Parks Using the Fisher-Shannon Method

The main goal of this study was to evaluate the potential of the Fisher-Shannon statistical method applied to the MODIS satellite time series to search for and explore any small multiyear trends and changes (herein also denoted as inner anomalies) in vegetation cover. For the purpose of our investigation, we focused on the vegetation cover of three peri-urban parks close to Rome and Naples (Italy). For each of these three areas, we analyzed the 2000–2020 time variation of four MODIS-based vegetation indices: evapotranspiration (ET), normalized difference vegetation index (NDVI), leaf area index (LAI), and enhanced vegetation index (EVI). These data sets are available in the Google Earth Engine (GEE) and were selected because they are related to the interactions between soil, water, atmosphere, and plants. To account for the great variability exhibited by the seasonal variations while identifying small multiyear trends and changes, we devised a procedure composed of two steps: (i) application of the Singular Spectrum Analysis (SSA) to each satellite-based time series to detect and remove the annual cycle including the seasonality and then (ii) analysis of the detrended signals using the Fisher-Shannon method, which combines the Shannon entropy and the Fisher Information Measure (FIM). Our results indicate that among all the three pilot test areas, Castel Volturno is characterized by the highest Shannon entropy and the lowest FIM that indicate a low level of order and organization of vegetation time series. This behaviour can be linked to the degradation phenomena induced by the parasite (Toumeyella parvicornis) that has affected dramatically the area in recent years. Our results were nicely confirmed by the comparison with in situ analyzed and independent data sets revealing the existence of subtle, small multiyear trends and changes in MODIS-based vegetation indices.     

Hydrogenation of acetylene–ethylene mixtures on Pd catalysts: study of the surface mechanism by computational approaches. Metal dispersion and catalytic activity

The hydrogenation mechanism of acetylene–ethylene mixtures on Pd catalysts under different experimental conditions was studied by employing a time-dependent Monte Carlo approach set to use a fixed series of event probabilities. The dependence of the catalyst activity and selectivity on the sizes of the metal particles was simulated at microscopic level and the results, also refined by fitting procedures, suggested proper explanations for the apparent nonuniformity of the related experimental findings. The use of the steric hindrance parameter of the surface species and the available surface energy on the metallic catalyst sites was decisive for reproducing the experimental results. Received: 16 September 1999 / Accepted: 3 February 2000 / Published online: 2 May 2000     

Antioxidant and spectroscopic studies of crosslinked polymers synthesized by grafting polymerization of ferulic acid

A novel, simple synthetic strategy for the preparation of crosslinked polymers with significant antioxidant properties is proposed. Ferulic acid (FA), a well‐known antioxidant compound, due to its reactivity toward free radical process, was inserted into a polymeric network with methacrylic acid (MAA) and ethylene glycole dimethacrylate acting as comonomer and crosslinker, respectively. All the reactants were simultaneously mixed in the polymerization feed and one‐pot radical reaction was carried out. Irregular microparticles were prepared by bulk polymerization and microspheres by precipitation polymerization. The materials were characterized by nuclear magnetic resonance–magic angle spinning (NMR‐MAS) studies, to verify effective FA insertion into polymeric networks, and by morphological, dimensional analyses, and water absorption measurement to study their superficial and swelling properties, respectively. Antioxidant properties of materials were evaluated by linoleic acid emulsion system–thiocyanate assay, determination of scavenging activity on DPPH radicals, determination of available phenolic groups in polymeric matrices, and determination of total antioxidant capacity. Copyright © 2009 John Wiley & Sons, Ltd.     

The Poincaré series of a local Gorenstein ring of multiplicity up to 10 is rational

Let R be a local, Gorenstein ring with algebraically closed residue field k of characteristic 0 and let P _R (z):= Σ _p=0^∞ dim _k (Tor _p ^R (k, k))z ^p be its Poincaré series. We compute P _R when R belongs to a particular class defined in the Introduction, proving its rationality. As a by-product we prove the rationality of P _R for all local, Gorenstein rings of multiplicity at most 10.     

The vibrational progressions of the N-->V electronic transition of ethylene: a test case for the computation of Franck-Condon factors of highly flexible photoexcited molecules

The vibrational progressions of the N-->V electronic transition of ethylene--a test case for the computation of Franck-Condon factors between electronic states exhibiting very different equilibrium geometries--have been calculated by using both the Cartesian and the curvilinear internal coordinate representations of the normal modes of vibration. The comparison of the theoretical spectra with the experimental one shows that the Cartesian representation yields vibrational progressions which are not observed in the experimental spectrum, whereas the curvilinear one gives a very satisfying agreement, even in harmonic approximation.     

Peptide folding dynamics: a time-resolved study from the nanosecond to the microsecond time regime

Time-resolved spectroscopies, spanning from the nanosecond to the microsecond time regime, coupled with molecular mechanics calculations, allowed us to assess the most populated conformations in solution of a series of analogues of trichogin GA IV, a natural undecapeptide showing significant antimicrobial activity. This peptide is characterized by a high content of the conformationally constrained alpha-aminoisobutyric acid and by a glycine-glycine motif in the central part of the sequence. Nanosecond time-resolved fluorescence experiments were performed to determine the conformational properties of the peptide analogues in solution, while transient absorption measurements allowed us to study the peptide dynamics on the microsecond time scale. Because the peptides examined were functionalized by a fluorescent probe at the N-terminus and a nitroxide quencher placed along the backbone at three different positions, the distance-dependent fluorophore-quencher interaction was exploited to obtain a deeper insight into their three-dimensional structural and dynamical properties. Further information on the conformational and dynamical features was obtained by photophysical experiments as a function of the viscosity and polarity of the medium. Taken together, the results revealed a transition from an elongated, helical conformation to a family of compact, folded structures mimicking a helix-turn-helix motif, which may represent a model of the early steps of the protein hydrophobic collapse.     

On the rationality of moduli spaces of pointed curves

Motivated by several recent results on the geometry of the modulispaces of stable curves of genus g with n marked points, we determine the birational structureof these spaces for small values of g and n by exploiting suitableplane models of a general curve. More precisely, _g,n is shownto be rational for g = 2 and 1 n 12, g = 3 and 1 n 14, g= 4 and 1 n 15, and g = 5 and 1 n 12     

The molecular structure of N-hydroxyurea

Ab initio calculations were performed on the tautomers and conformers of N-hydroxyurea using a 6-31G ** basis set. The minimum-energy structures have been found and the importance of the intramolecular hydrogen bond as the stabilizing factor was pointed out. © 1996 John Wiley & Sons, Inc.