湍流的相干结构:推演方法和结果

本文讨论壁面湍流发展的相干结构的观点.在简要的历史文献综述后,我们回顾一些基本观点, 并且介绍相干结构的思想.基于大量主要是由实验所得的结果,本文通过广泛运用的事件检 测技术,探讨湍流边界层内部和外部区域发生的现象.我们从边界层内部区域发生的现象、 边界层外部大尺度运动的发展和涡结构动力学的角度来描述流动的现象.在文章的 第2部分,介绍从背景流动中推演出湍流相干结构的各种方法以及在各种方法框架下所得到的结果, 讨论速度梯度张量不变量、压力的Hessian矩阵分析和本征正交分解等方法.每一个过程 都有``相干结构'的特定的定义,满足恰当的数学构架,并可以对湍流数据做相干结构动力 学分析.这一工作可能会对当前流体动力学家在湍流研究中用到的最新理论和技术的传播有 所贡献.     

Phenylhydrazine–borane adduct—characterized in the solid state and in solution

The 1:1 phenylhydrazine–borane adduct, obtained from phenylhydrazine and sodium borohydride in acidic solution, was investigated by IR, NMR spectroscopy, and MS spectrometry. Ab initio MO calculations indicated the isomer in which the boron center is attached to the primary amino group as the more stable. This forecast was confirmed by solution‐state ¹H, ¹¹B, ¹³C, and ¹⁵N NMR spectroscopy, in agreement with the molecular structure in the solid state determined by X‐ray analysis. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:366–372, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10049     

CFD modelling of a spray deposition process of paint

The paint deposition process by spraying has been studied by means of Computational Fluid Dynamics in order to predict the final thickness of the coating and to determine theoretically the overspraying phenomenon. The VOF model has been used to describe the impact phenomena onto the wall and the Euler-Lagrange approach to simulate droplet trajectories on their way to the surface. Particular attention has been devoted to the prediction of the maximum diameter reached by an impinging droplet at the end of the spreading phase. This diameter is very important in the study of the paint processes because the high viscosity and the small surface tension of paints reduce the impingement practically only to the spreading phase. Two different configurations of atomizers have been considered. The air flux provides a finer atomisation of the liquid, gives to the droplets the necessary velocity to reach the wall, but is also the main cause of overspray since the small droplets tend to follow its deviation near the wall.     

Efficient DNA Extraction and Amplification of Samples from the Archeological Site of Pompei (Italy)

Due to their growth and metabolism, microorganisms can cause severe damage to Cultural Heritage, through mechanical and chemical processes. In this paper we used molecular approaches to study bacterial communities on samples from the archeological site of Pompei (Italy). In particular four DNA extraction methods without prior cultivation of the microflora were compared. In terms of efficiency, the DNA extraction method based on the Tri-Reagent™ kit gave the best results. All extraction protocols coupled with 16S rDNA fragments PCR amplification were satisfactory; but the best results were obtained by Klentaq DNA LA Polymerase™; this enzyme can be considered an effective tool for amplification of DNA from Cultural Heritage and possibly other environmental samples.     

Alternating Diene Metathesis Polycondensation (ALTMET) – A Versatile Tool for the Preparation of Perfectly Alternating AB Copolymers

Perfectly alternating copolymers can be synthesised by reacting diacrylates with terminal dienes using alternating diene metathesis polycondensation (ALTMET). This novel method is very versatile and allows preparation of diverse structures of polymers, including main‐chain liquid crystalline polymers.

Main‐chain liquid crystalline polymer obtained by ALTMET.     

Synthesis and crystal structures of the triphenylstannyl esters of N-phthaloyl-glycine and -leucine

Triphenyltin N-phthaloylglycinate crystallizes from ethanol as a bridged, cyclic hexamer (rhombohedral R3 space group, a = 19.928(3) Å, α = 116.47(2)⁰; Z = 6) and triphenyltin N-phthaloylleucinate as a monomeric molecule (orthorhombic Pbca space group, a = 18.032(6), b = 26.992(7), c = 11.705(4) Å; Z = 8).