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31.
Giuseppa Di Bella Patrizia Licata Vito Pellizzeri Hedi Ben Mansour Giacomo Dugo 《Natural product research》2018,32(12):1402-1406
Two species of edible clams Venerupis aurea laeta and Cerastoderma edule glaucum from Ganzirri Lake (Sicily, Italy) were investigated to determine OCP and PCB residues by GC-MS. Thirty-five samples were examined for two years in order to perform: a) their actual contamination; b) the daily dietary exposure of seafood consumers to the pollutants in question. In all the clams analysed in this study, PCB and OCP (4,4′-DDE) residues are always below the limits fixed by law. It seems that there is some seasonality of concentrations observed. In fact the more high concentrations of residues are detected in the hot months, for both species and years. Given the consumption of clams and the values obtained in this study for the two species analysed, it is possible estimate that the average daily dietary intake of NDL-PCB and of 4,4′-DDE for adults is really low. 相似文献
32.
Nora Jannsen Dr. Stefano Diodati Nicola Dengo Francesca Tajoli Dr. Nicola Vicentini Dr. Giacomo Lucchini Prof. Adolfo Speghini Prof. Denis Badocco Prof. Paolo Pastore Prof. Silvia Gross 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(59):13624-13634
The aim of this work was i) to develop a hydrothermal, low-temperature synthesis protocol affording the upconverting hexagonal phase NaYF4 with suitable dopants while adhering to the “green chemistry” standards and ii) to explore the effect that different parameters have on the products. In optimizing the synthesis protocol, short reaction times and low temperatures (below 150 °C) were considered. Yb3+ and Er3+ ions were chosen as dopants for the NaYF4 material. Within the context of the second goal, parameters including nature of the precursors, treatment temperature, and treatment time were investigated to afford a pure hexagonal crystalline phase, both in the doped and undoped materials. To fully explore the synthesis results, the prepared materials were characterized from a structural (XRD), compositional (XPS, ICP-MS), and morphological (SEM) point of view. The upconverting properties of the compounds were confirmed by photoluminescence measurements. 相似文献
33.
Cristian Rosso Dr. Giacomo Filippini Prof. Maurizio Prato 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(70):16032-16036
The use of amine-rich N-doped carbon nanodots (NCNDs) for the photochemical radical perfluoroalkylation of organic compounds is reported. This operationally simple approach occurs under mild conditions producing valuable new C−C bonds. The chemistry is driven by the ability of NCNDs to directly reach an electronically excited state upon light absorption, thereby successively triggering the formation of reactive radical species from simple perfluoroalkyl iodides. Preliminary mechanistic studies are also reported. 相似文献
34.
In this paper we propose practical strategies for generating split cuts, by considering integer linear combinations of the
rows of the optimal simplex tableau, and deriving the corresponding Gomory mixed-integer cuts; potentially, we can generate
a huge number of cuts. A key idea is to select subsets of variables, and cut deeply in the space of these variables. We show
that variables with small reduced cost are good candidates for this purpose, yielding cuts that close a larger integrality
gap. An extensive computational evaluation of these cuts points to the following two conclusions. The first is that our rank-1
cuts improve significantly on existing split cut generators (Gomory cuts from single tableau rows, MIR, Reduce-and-Split,
Lift-and-Project, Flow and Knapsack cover): on MIPLIB instances, these generators close 24% of the integrality gap on average;
adding our cuts yields an additional 5%. The second conclusion is that, when incorporated in a Branch-and-Cut framework, these
new cuts can improve computing time on difficult instances. 相似文献
35.
Giacomo Aletti Caterina May Piercesare Secchi 《Journal of Theoretical Probability》2012,25(4):1207-1232
We study a functional equation whose unknown maps a Euclidean space into the space of probability distributions on [0,1]. We prove existence and uniqueness of its solution under suitable regularity and boundary conditions, we show that it depends continuously on the boundary datum, and we characterize solutions that are diffuse on [0,1]. A canonical solution is obtained by means of a Randomly Reinforced Urn with different reinforcement distributions having equal means. The general solution to the functional equation defines a new parametric collection of distributions on [0,1] generalizing the Beta family. 相似文献
36.
Luca Giacomo Bettini Maria Vittoria Diamanti Maurizio Sansotera Maria Pia Pedeferri Walter Navarrini Paolo Milani 《Journal of nanoparticle research》2016,18(8):238
Anatase/rutile mixed-phase titanium dioxide (TiO2) photocatalysts in the form of nanostructured powders with different primary particle size, specific surface area, and rutile content were produced from the gas-phase by flame spray pyrolysis (FSP) starting from an organic solution containing titanium (IV) isopropoxide as Ti precursor. Flame spray-produced TiO2 powders were characterized by means of X-ray diffraction, Raman spectroscopy, and BET measurements. As-prepared powders were mainly composed of anatase crystallites with size ranging from 7 to 15 nm according to the synthesis conditions. TiO2 powders were embedded in a multilayered fluoropolymeric matrix to immobilize the nanoparticles into freestanding photocatalytic membranes. The photocatalytic activity of the TiO2-embedded membranes toward the abatement of hydrosoluble organic pollutants was evaluated employing the photodegradation of rhodamine B in aqueous solution as test reaction. The photoabatement rate of best performing membranes significantly overcomes that of membranes produced by the same method and incorporating commercial P25-TiO2. 相似文献
37.
Comparison of two laser-induced breakdown spectroscopy techniques for total carbon measurement in soils 总被引:1,自引:0,他引:1
M.V. Belkov V.S. Burakov A. De Giacomo V.V. Kiris S.N. Raikov N.V. Tarasenko 《Spectrochimica Acta Part B: Atomic Spectroscopy》2009
The potentials of two advanced laser-induced breakdown spectroscopy (LIBS) techniques which are used to determine the total carbon content in soils have been examined. The first one is the combination of a single-pulse laser ablation with spark excitation of plasma plume triggering the gap between electrodes close to the target surface. The second one is a more conventional double-pulse LIBS. In both modes the calibration graphs have a nonlinear trend in the actual range of carbon contents and present a good R2 value (0.97). In the combined laser-spark approach, using low-cost and portable laser instrumentation is possible, as well as inducing a micro-damage on the target surface. Certain regularities in the spectral line intensities of soil nutritious elements have been detected and appear to be connected to the total carbon content and to the soil origin. 相似文献
38.
A study of the reduction of CuO in a ternary oxide system (Cu:Zn:Al, atomic ratio 62:14:24) demonstrated that at lower temperatures it occurred in two stages, whereas at higher temperatures it was no longer possible to display the formation of Cu2O. The rate of reduction of CuO was strongly reduced on decreasing the partial pressure of hydrogen, while the presence of CO2 stabilized the Cu2O, delaying the reduction to copper. On the basis of simpler systems it was possible to demonstrate the activating effect of Al2O3 and the delaying effect of ZnO on the reduction of CuO. 相似文献
39.
Rocco Angelone Dr. Francesco Ciardelli Prof. Arturo Colligiani Prof. Francesco Greco Dr. Paolo Masi Prof. Annalisa Romano Dr. Giacomo Ruggeri Prof. 《Chemphyschem》2010,11(2):460-465
A derivative of 2‐methylindole, 3‐[2‐(4‐nitrophenyl)ethenyl]‐1‐allyl‐2‐methylindole, NPEMI‐A, is studied for its photoconductivity and photorefractivity behaviour. Its blends with the organic polymer poly‐(2,3‐dimethyl‐N‐vinylindole), PVDMI, are also investigated. Due to the expected and devised mutual solubility of the two components of the blends, it is possible to carry out measurements with the weight percent of the chromophore NPEMI‐A changing from zero to 100. Films were produced by a squeezing process between two ITO‐covered glass sheets. No opacity phenomena, that are so common for many other organic blends due to the segregation of the dissolved chromophore, are observed. The photorefractive optical gain Γ2 is obtained as a function of the chromophore content. Differential scanning calorimetry measurements (DSC) are also carried out to obtain the whole change of the glass transition temperature Tg as a function of the amount of chromophore contained in the blends. From the experimental trend of Tg a meaningful quantitative estimate of the value of the electrostatic interactions acting in the studied blends, is obtained. The importance of the value of Tg, and of the electrostatic interactions, in determining the extent of the photorefractivity is clearly evident. The results are compared for NPEMI‐A (Γ2=210 cm?1) and for NPEMI‐E (Γ2 ≈ 2000 cm?1) that has a N‐2‐ethylhexyl group instead of a N‐allyl group. The Pockels and Kerr contributions and—for the first time—a “collaborative effect” of the photorefractivity of NPEMI‐A are distinguished and quantitatively evaluated. 相似文献
40.
Dr. Antonio Zucca Dr. Luca Maidich Laura Canu Dr. Giacomo L. Petretto Prof. Sergio Stoccoro Prof. Maria Agostina Cinellu Dr. Guy J. Clarkson Dr. Jonathan P. Rourke 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(18):5501-5510
Rollover cyclometalation involves bidentate heterocyclic donors, unusually acting as cyclometalated ligands. The resulting products, possessing a free donor atom, react differently from the classical cyclometalated complexes. Taking advantage of a “rollover”/“retro‐rollover” reaction sequence, a succession of oxidative addition and reductive elimination in a series of platinum(II) complexes [Pt(N,C)(Me)(PR3)] resulted in a rare C(sp2)?C(sp3) bond formation to give the bidentate nitrogen ligands 3‐methyl‐2,2′‐bipyridine, 3,6‐dimethyl‐2,2′‐bipyridine, and 3‐methyl‐2‐(2′‐pyridyl)‐quinoline, which were isolated and characterized. The nature of the phosphane PR3 is essential to the outcome of the reaction. This route constitutes a new method for the activation and functionalization of C?H bond in the C(3) position of bidentate heterocyclic compounds, a position usually difficult to functionalize. 相似文献