In the simplest case of a linearly degenerate mobility, we view the thin-film equation as a classical free boundary problem. Our focus is on the regularity of solutions and of their free boundary in the “complete wetting” regime, which prescribes zero slope at the free boundary. In order to rule out of the analysis possible changes in the topology of the positivity set, we zoom into the free boundary by looking at perturbations of the stationary solution. Our strategy is based on a priori energy-type estimates which provide “minimal” conditions on the initial datum under which a unique global solution exists. In fact, this solution turns out to be smooth for positive times and to converge to the stationary solution for large times. As a consequence, we obtain smoothness and large-time behavior of the free boundary. 相似文献
Fluorescent vesicles considered as a mimic of natural primitive cells are prepared from poly(3‐hexylthiophene)‐block‐poly(3‐O‐methacryloyl‐D‐galactopyranose) P3HT‐b‐PMAGP copolymers. The unique characteristic of such vesicular nanostructures is their architecture, which comprises a hydrophobic π‐conjugated P3HT wall stabilized by a hydrophilic PMAGP interface featuring glucose units. The results of this work offer a very efficient and straightforward method for engineering well‐controlled fluorescent nanoparticles (without the addition of dyes), which provide an excellent support to the study of carbohydrate‐protein interactions.
Total charge-changing cross sections and cross sections for the production of projectile-like fragments were determined for fragmentation reactions induced by 370 MeV/n 20Ne ions in water and lucite, and 490 MeV/n 24Mg ions in polyethylene, carbon and aluminum targets sandwiched with CR-39 plastic nuclear track detectors. An automated microscope system and a track-to-track matching algorithm were used to count and recognize the primary and secondary particles. The measured cross sections were then compared with published cross sections and predictions of different models. Two models and the three-dimensional Monte Carlo Particle Heavy Ion Transport Code System (PHITS) were used to calculate total charge-changing cross sections. Both models agreed within a few percent for the system 24Mg + CH2, however a deviation up to 20% was observed for the systems 20Ne + H2O and C5H8O2, when using one of the models. For all the studied systems, PHITS systematically underestimated the total charge-changing cross section. It was also found that the partial fragmentation cross sections for 24Mg + CH2 measured in present and earlier works deviated up to 20% for Z = 6–11. Measured cross sections for the production of fragments (Z = 4–9) for 20Ne + H2O and C5H8O2 were compared with predictions of three different semi-empirical models and JQMD which is used in the PHITS code. The calculated cross sections differed from the measured data by 10–90% depending on which fragment and charge was studied, and which model was used. 相似文献
The relative mean activity coefficients of the M3[Fe(CN)6]2 salts, M=Mg, Ca, Sr, Ba, are measured down to about 5×10–6 mol-kg–1 using the liquid membrane cell method. In the dilute region these salts display negative instead of positive deviations from the limiting law, contrary to Debye-Hückel's theory predictions. An indirect method based on auxiliary emf measurements in MCl2, K3Fe(CN)6 and KCl, rather than a theory-assisted direct extrapolation to zero of the relative activity coefficients, is used to identify the actual values of the activity coefficients. The data are compared with Mayer's theory, ion-pair theory and numerical integration of the Poisson-Boltzmann equation. Best-fit coefficients of Pitzer's equation which meet the activity coefficients of the M3[Fe(CN)6]2 salts to be reproduced, are reported. 相似文献
We present the preliminary results of the cosmic abundances below the knee energies (CAKE) experiment for the study of the primary cosmic-ray composition and for the search of exotic particles in the primary cosmic radiation. CAKE uses CR39® and Lexan nuclear track detectors, which were calibrated with beams of 158 AGeV Pb ions and 1 AGeV Fe ions at the CERN and BNL accelerators, respectively. Results based on the analysis of a first data sample are shown. 相似文献
We prove short-time existence and uniqueness of classical solutions in weighted Hölder spaces for the thin-film equation with linear mobility, zero contact angle, and compactly supported initial data. We furthermore show regularity of the free boundary and optimal regularity of the solution in terms of the regularity of the initial data. Our approach relies on Schauder estimates for the operator linearized at the free boundary, obtained through a variant of Safonov's method that is solely based on energy estimates. 相似文献