A New Cyanofluorene–Triphenylamine Copolymer: Synthesis and Photoinduced Intramolecular Electron Transfer Processes

A new π‐conjugated copolymer, namely, poly{cyanofluore‐alt‐[5‐(N,N′‐diphenylamino)phenylenevinylene]} ((CNF–TPA)_n), was synthesized by condensation polymerization of 2,2′‐(9,9‐dioctyl‐9H‐fluorene‐2,7‐diyl)diacetonitrile and 5‐(N,N′‐diphenylamino)benzene‐1,3‐dicarbaldehyde by using the Knoevenagel reaction. By design, diphenylamine, alkylfluorene and poly(p‐phenylenevinylene) linkages were combined to form a (CNF–TPA)_n copolymer which exhibits high thermal stability and glass‐transition temperature. Photodynamic measurements in polar benzonitrile indicate fast and efficient photoinduced electron transfer (≈10¹¹ s^?1) from triphenylamine (TPA) to cyanofluorene (CNF) to produce the long‐lived charge‐separated state (90 μs). The finding that the charge‐recombination process of (CNF^.?–TPA^.+)_n is much slower than the charge separation in polar benzonitrile suggests a potential application in molecular‐level electronic and optoelectronic devices.     

Synthesis and Characterization of α-Bromo Chalcone Derivatives

α-Bromo chalcones containing 2-thiene ring were prepared in good yields by the condensation of 1-(thien-3-yl)ethanone with aromatic aldehydes, followed by bromination with bromine and selective dehydrobromination with triethyl amine at room temperature.     

Heterocycles [<Emphasis Type="Italic">h</Emphasis>]-fused to 4-oxoquinoline-3-carboxylic acid. Part VII: synthesis of some 6-oxoimidazo[4,5-<Emphasis Type="Italic">h</Emphasis>]quinoline-7-carboxylic acids and esters

Abstract  A series of ethyl 2-(substituted)-9-cyclopropyl-4-fluoro-6-oxo-1H-imidazo[4,5-h]quinoline-7-carboxylates has been prepared from ethyl 7,8-diamino-1,4-dihydroquinoline-3-carboxylate via thermally induced reactions with model alkanoic acids or via microwave-assisted cyclocondensation with some arene carboxaldehydes. Acid-catalysed hydrolysis of the resulting ester derivatives furnished the corresponding imidazoquinoline-7-carboxylic acids. The structures of these new acid and ester derivatives are based on microanalytical and spectral (IR, MS, and NMR) data. Graphical abstract        

Arsenic speciation in natural water samples by coprecipitation-hydride generation atomic absorption spectrometry combination

A speciation procedure for As(III) and As(V) ions in environmental samples has been presented. As(V) was quantitatively recovered on aluminum hydroxide precipitate. After oxidation of As(III) by using dilute KMnO₄, the developed coprecipitation was applied to determination of total arsenic. Arsenic(III) was calculated as the difference between the total arsenic content and As(V) content. The determination of arsenic levels was performed by hydride generation atomic absorption spectrometry (HG-AAS). The analytical conditions for the quantitative recoveries of As(V) including pH, amount of aluminum as carrier element and sample volume, etc. on the presented coprecipitation system were investigated. The effects of some alkaline, earth alkaline, metal ions and also some anions were also examined. Preconcentration factor was calculated as 25. The detection limits (LOD) based on three times sigma of the blank (N: 21) for As(V) was 0.012 μg L⁻¹. The satisfactory results for the analysis of arsenic in NIST SRM 2711 Montana soil and LGC 6010 Hard drinking water certified reference materials for the validation of the method was obtained. The presented procedure was successfully applied to real samples including natural waters for arsenic speciation.     

Experimental studies on natural convection of water in a closed-loop vertical annulus

Experimental studies on heat transfer and fluid flow of water in a vertical annulus, circulating through a cold leg forming a closed loop thermo-siphon, have been carried out in this article. The annulus has a radius ratio (outer radius to inner radius) of 1.184 and aspect ratio (length to annular gap) equal to 352. The experiments were conducted for constant heat fluxes of 1, 2.5, 5, 7.5, 10, 12.5, and 15 kW/m². Transient behavior during the heat-up period of the system until the steady-state condition is attained and discussed. Variation in the heat transfer coefficient and Nusselt number along the annulus height represent the developing boundary layer at the entrance and fully developed flow in the remaining length. A large drop in the differential pressure is experienced when the liquid is circulated through the flow meters, which restrict the flow due to their very small passages. Flow restriction causes mass accumulation and rise of pressure at the exit of the annulus. It also causes a decrease in liquid head in the cooling leg. An increase in the heat flux leads to an increase in the heat transfer coefficient and Nusselt number. As a result of the data analysis correlations for the average Nusselt number, Reynolds number and circulation rate have been developed in terms of the heat flux.     

Bright,dark and singular optical solitons in a power law media with fourth order dispersion

This study focuses on exact solutions of nonlinear Schrödinger equation in a power law media with fourth order dispersion. Jacobi elliptic functions will be used to carry out the integration of this equation. Bright, dark and singular optical soliton solutions are obtained as well as Jacobi elliptic function solutions.     

Solitary wave solutions to the Tzitzeica type equations obtained by a new efficient approach

The properties of Tzitzeica equations in nonlinear optics have received a great attention of many recent studies. In this work, the so-called generalized exponential rational function method (GERFM) has been applied for finding the analytical solution of two nonlinear partial differential equations type of equations, namely Tzitzeica-Dodd-Bullough and Tzitzeica equation. The proposed method provides a wide range of closed-form travelling solutions leading to a very effective and simply-applied method by means of a symbolic computation system. The method not only provides a general form of solutions with some free parameters but also shows potential application to other types of nonlinear partial differential equations.     

General decay result for nonlinear viscoelastic equations

In this paper we consider a nonlinear viscoelastic equation with minimal conditions on the $L^1(0,\infty )$ relaxation function g namely $g^{\prime }(t)\le ?\xi (t)H(g(t))$, where H is an increasing and convex function near the origin and ξ is a nonincreasing function. With only these very general assumptions on the behavior of g at infinity, we establish optimal explicit and general energy decay results from which we can recover the optimal exponential and polynomial rates when $H(s)=s^p$ and p covers the full admissible range $[1,2)$. We get the best decay rates expected under this level of generality and our new results substantially improve several earlier related results in the literature.     

Real matrix representations of complex split quaternions with applications

In this paper, we introduce 8×8 real matrix representations of complex split quaternions. Then, the relations between real matrix representations of split and complex split quaternions are stated. Moreover, we investigate some linear split and complex split quaternionic equations with split Fibonacci and complex split Fibonacci quaternion coefficients. Finally, we also give some numerical examples as applications of real matrix representation of complex split quaternions.     

Partial order relations on family of sets and scalarizations for set optimization

In this study, some new order relations on family of sets are introduced by using Minkowski difference. The relations between these orders and the ordering cone of the vector space are obtained. It is shown that depending on the corresponding cone, these order relations are partial orders on the family of nonempty bounded sets. Some relationships between these order relations and upper and lower set less order relations are investigated. Also, two scalarizing functions are introduced in order to replace set optimization problems with respect to these partial order relations with scalar optimization problems. Moreover, necessary and sufficient optimality conditions are presented.