Effects of annealing temperature on shape transformation and optical properties of germanium quantum dots

The influences of thermal annealing on the structural and optical features of radio frequency(rf) magnetron sputtered self-assembled Ge quantum dots(QDs) on Si(100) are investigated.Preferentially oriented structures of Ge along the(220) and(111) directions together with peak shift and reduced strain(4.9%to 2.7%) due to post-annealing at 650 ℃ are discerned from x-ray differaction(XRD) measurement.Atomic force microscopy(AFM) images for both pre-annealed and post-annealed(650 ℃) samples reveal pyramidal-shaped QDs(density ~ 0.26×10~(11) cm~(-2)) and dome-shape morphologies with relatively high density ~ 0.92×10~(11) cm~(-2),respectively.This shape transformation is attributed to the mechanism of inter-diffusion of Si in Ge interfacial intermixing and strain non-uniformity.The annealing temperature assisted QDs structural evolution is explained using the theory of nucleation and growth kinetics where free energy minimization plays a pivotal role.The observed red-shift ~ 0.05 eV in addition to the narrowing of the photoluminescence peaks results from thermal annealing,and is related to the effect of quantum confinement.Furthermore,the appearance of a blue-violet emission peak is ascribed to the recombination of the localized electrons in the Ge-QDs/SiO_2 or GeO_x and holes in the ground state of Ge dots.Raman spectra of both samples exhibit an intense Ge-Ge optical phonon mode which shifts towards higher frequency compared with those of the bulk counterpart.An experimental Raman profile is fitted to the models of phonon confinement and size distribution combined with phonon confinement to estimate the mean dot sizes.A correlation between thermal annealing and modifications of the structural and optical behavior of Ge QDs is established.Tunable growth of Ge QDs with superior properties suitable for optoelectronic applications is demonstrated.     

A Triphenyl Amine‐Based Solvatofluorochromic Dye for the Selective and Ratiometric Sensing of OCl− in Human Blood Cells

A new visible‐light‐excitable fluorescence ratiometric probe for OCl^? has been developed based on a triphenylamine‐diamiomaleonitrile (TAM) moiety. The structure of the dye was confirmed by single‐crystal X‐ray analysis. It behaves as a highly selective and sensitive probe for OCl^? over other analytes with a fast response time (～100 s). OCl^? reacts with the probe leading to the formation of the corresponding aldehyde in a mixed‐aqueous system. The detection limit of the probe is in the 10^?8 M range. The probe (TAM) also exhibits solvatofluorochromism. Changing the solvent from non‐polar to polar, the emission band of TAM largely red‐shifted. Moreover, the probe shows an excellent performance in real‐life application in detecting OCl^? in human blood cells. The experimentally observed changes in the structure and electronic properties of the probe after reaction with OCl^? were studied by DFT and TDDFT computational calculations.     

Dynamics of networking agents competing for high centrality and low degree

We model a system of networking agents that seek to optimize their centrality in the network while keeping their cost, the number of connections they are participating in, low. Unlike other game-theory based models for network evolution, the success of the agents is related only to their position in the network. The agents use strategies based on local information to improve their chance of success. Both the evolution of strategies and network structure are investigated. We find a dramatic time evolution with cascades of strategy change accompanied by a change in network structure. On average the network self-organizes to a state close to the transition between a fragmented state and a state with a giant component. Furthermore, with increasing system size both the average degree and the level of fragmentation decreases.     

p-adic string theories provide lattice Discretization to the ordinary string worldsheet

A class of models called p-adic strings is useful in understanding the tachyonic instability of string theory. These are found to be empirically related to the ordinary strings in the p-->1 limit. We propose that these models provide discretization for the string worldsheet and argue that the limit is naturally thought of as a continuum limit in the sense of the renormalization group.     

Structural transition in alcohol-water binary mixtures: A spectroscopic study

The strengthening of the hydrogen bonding (H-bond) network as well as transition from the tetrahedral-like water network to the zigzag chain structure of alcohol upon increasing the alcohol concentration in ethanol-water and tertiary butanol (TBA) — water mixtures have been studied by using both steady state and time resolved spectroscopy. Absorption and emission characteristics of coumarin 153 (C153), a widely used non-reactive solvation probe, have been monitored to investigate the structural transition in these binary mixtures. The effects of the hydrogen bond (H-bond) network with alcohol concentration are revealed by a minimum in the peak frequency of the absorption spectrum of C153 which occur at alcohol mole fraction ∼0·10 for water-ethanol and at ∼0·04 for water-TBA mixtures. These are the mole fractions around which several thermodynamic properties of these mixtures show anomalous change due to the enhancement of H-bonding network. While the strengthening of H-bond network is revealed by the absorption spectra, the emission characteristics show the typical non-ideal alcohol mole fraction dependence at all concentrations. The time resolved anisotropy decay of C153 has been found to be bi-exponential at all alcohol mole fractions. The sharp change in slopes of average rotational correlation time with alcohol mole fraction indicates the structural transition in the environment around the rotating solute. The changes in slopes occur at mole fraction ∼0·10 for TBA-water and at ∼0·2 for ethanol-water mixtures, which are believed to reflect alcohol mole fraction induced structural changes in these alcohol-water binary mixtures.     

Velocity and concentration profiles in uniform sediment-laden flow

This paper presents a theoretical model for computing the velocity and sediment concentration profiles in a uniform sediment-laden flow carrying all fine, medium and coarse sediments. The proposed model essentially includes the effect of sediment concentration in total turbulent shear stress and eddy diffusivity in addition to the modified mixing length derived by Umeyama and Gerritsen [J. Hydr. Engng., ASCE, 118 (2) (1992) 229–245] applied to Hunt’s diffusion equation. Numerical solution of coupled differential equations for velocity and sediment concentration is carried out. The theoretical results show quite good agreement with the experimental data.     

Exponential correlated basis in Schwinger variational principle for positronium formation in hydrogen

An exponential correlated basis set is tested within the framework of multi-channel Schwinger variational principle in the momentum space. It is found that inclusion of only the positron-electron correlation in the basis set is enough to obtain accurate results for all significant partial waves for ground state positronium formation in positron-hydrogen collisions at low and intermediate energies (6.856–75 eV). Results are in conformity with other accurate variational and non-variational calculations as well as observed data available in the literature.     

Synthesis of nano and micro crystals of Cd(OH)2 and CdO in the shape of hexagonal sheets and rods

Cd(OH)₂ and CdO nano/micro crystals were synthesized in ethanol-water medium using cadmium foil as a source under solvothermal condition. The experimental parameters such as ratio of ethanol to water, concentration of NaOH and synthesis temperature all play important role in determining the size, shape and crystalline phase of the products. The products were characterized by X-ray diffraction and scanning electron microscopy. Nano/micro crystals of CdO were also achieved by thermal treatment of Cd(OH)₂ crystals in air at different temperatures.     

Preservation of network degree distributions from non-uniform failures

There has been a considerable amount of interest in recent years on the robustness of networks to failures. Many previous studies have concentrated on the effects of node and edge removals on the connectivity structure of a static network; the networks are considered to be static in the sense that no compensatory measures are allowed for recovery of the original structure. Real world networks such as the world wide web, however, are not static and experience a considerable amount of turnover, where nodes and edges are both added and deleted. Considering degree-based node removals, we examine the possibility of preserving networks from these types of disruptions. We recover the original degree distribution by allowing the network to react to the attack by introducing new nodes and attaching their edges via specially tailored schemes. We focus particularly on the case of non-uniform failures, a subject that has received little attention in the context of evolving networks. Using a combination of analytical techniques and numerical simulations, we demonstrate how to preserve the exact degree distribution of the studied networks from various forms of attack.