Experimental study and nuclear model calculation for 65Zn production

Excitation functions and theoretical yields via charge particle induced reactions were evaluated using EMPIRE-3.2.2 and ALICE/ASH codes and the obtained results have been discussed and compared with the available reported experimental data. It has been verified that ^natCu(p,n)⁶⁵Zn reaction is the optimum ⁶⁵Zn production route. The ⁶⁵Zn was produced using ^natCu(p,xn) ⁶⁵Zn reaction in the energy range of 16.8 → 12.2 MeV with the thick target yield of 0.15 ± 0.005 MBq/μA h. The ⁶⁵Zn radionuclide was purified by anion exchange chromatography.

     

A simple and efficient approach to the synthesis of endo and exo bicyclo[6.1.0]nona-3,5-diene-9-carboxaldehyde

Monobromination of 1,5-cyclooctadiene, followed by cyclopropanation with ethyl diazoacetate, led to the formation of endo and exo ethyl 4,5-dibromobicyclo[6.1.0]nonane-9-carboxylates 3a and 3b. Bis-dehydrobromination of 3a and 3b using 1,8-diazabicyclo[5,4,0]undec-7-ene (DBU) afforded the endo and exo ethyl bicyclo[6.1.0]nona-3,5-diene-9-carboxylates 4a and 4b. Reduction of these compounds to the corresponding alcohols 5a and 5b and subsequent oxidation with pyridinium chlorochromate (PCC) resulted in the formation of the target compounds endo and exo bicyclo[6.1.0]nona-3,5-diene-9-carboxaldehydes 6a and 6b.     

Dual-wavelength CW diode-end-pumped a-cut Nd:YVO4 laser at 1064.5 and 1085.5 nm

A simple and compact dual-wavelength continuous wave (CW) laser-diode end-pumped laser operating simultaneously at 1,064.5 and 1,085.5 nm in a single a-cut Nd:YVO₄ has been demonstrated. We have used two Nd:YVO₄ crystals with different Nd⁺³ concentrations and lengths; 0.1 %-14 mm and 0.25 %-12 mm. The maximum total output power of 5 and 6.18 W, including 1,064.5 and 1,085.5 nm, is achieved at the incident pump power of 22 and 18 W, with a slope efficiency 23.3 and 32.9 %, respectively, for the crystals of 0.1 %-14 mm and 0.25 %-12 mm. The calculations show both wavelengths lasing at 1,064.5 and 1,085.5 nm can possess the same threshold when reflectivity of the output coupler at 1,064.5 nm is less than 87.5 % and, at this condition, the reflectivity of the output coupler at 1,085.5 nm increases nearly linearly with that of 1,064.5 nm.     

A continuous covering location model with risk consideration

This paper proposes a continuous covering location model with risk consideration. The investigated model is an extension of the discrete covering location models in continuous space. The objective function consists of installation and risk costs. Because of uncertain covering radius, customer satisfaction degree of covering radius is introduced by fuzzy concept. Since, the uncertainty may cause risk of uncovering customers; the risk cost is added to the objective function. The installation cost is assigned to a zone with a predetermined radius from its center. The model is solved by a fuzzy method named α$\alpha$-cut. After solving the model based on different α$\alpha$-values, the zones with the largest possibilities are determined for locating new facilities and the best locations are calculated based on the obtained possibilities. Then, the model is solved to determine the best covering values. This paper, also introduces a risk analysis method based on Response Surface Methodology (RSM) to consider risk management in the location models. Finally, a numerical example is expressed to illustrate the proposed model.     

Economic production quantity model with repair failure and limited capacity

We develop an economic production quantity (EPQ) model with random defective items and failure in repair. The existence of only one machine results with limited production capacity and shortages. The aim of this research is to derive the optimal cycle length, the optimal production quantity and the optimal back ordered quantity for each product so as to minimize the total expected cost (holding, shortage, production, setup, defective items and repair costs). The convexity of the model is derived and the objective function is proved convex. Two numerical examples illustrate the practical usage of the proposed method.     

Polynomial numerical hulls of matrix polynomials,II

In this article, we study some algebraic and geometrical properties of polynomial numerical hulls of matrix polynomials and joint polynomial numerical hulls of a finite family of matrices (possibly the coefficients of a matrix polynomial). Also, we study polynomial numerical hulls of basic A-factor block circulant matrices. These are block companion matrices of particular simple monic matrix polynomials. By studying the polynomial numerical hulls of the Kronecker product of two matrices, we characterize the polynomial numerical hulls of unitary basic A-factor block circulant matrices.     

New aluminum‐based ionic liquids: Synthesis,characterization, and theoretical study

Synthesis, characterization, spectral and molecular parameters of some new room‐temperature ionic liquids (tetraalkylammonium bromotrichloro aluminum [R₄N]⁺[AlCl₃Br]⁻) have been studied in the present study. All synthesized ionic liquids were characterized by IR, ¹H, ¹³C, and ⁸¹Br‐NMR. In addition, synthesized structures were optimized at the B3LYP/LANL2DZ level of theory and then the structures, molecular specifications, and infrared spectra of these were extracted using Gaussian 03 program. Theoretical data show good agreement with the experimental results. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 20:398–404, 2009; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20564     

Investigation of isothermal and dynamic cure kinetics of epoxy resin/nadic methyl anhydride/dicyandiamide by differential scanning calorimetry (DSC)

Isothermal and dynamic differential scanning calorimetry (DSC) was exploited to study the curing behavior of diglycidyl ether bisphenol-A epoxy resin with various combining ratios of dicyandiamide (DICY) and nadic methyl anhydride (NMA). Curves of prepared samples indicated that the enthalpy of the reaction decreased with increasing the molar ratios (NMA/DICY) up to 40% after which an exothermic peak peculiar to the effect of anhydride appeared at a higher temperature. The curing behavior examination of the samples containing the aforementioned molar ratio of NMA/DICY (= 40%) was carried out using isothermal condition at different temperatures (130–145 °C) and dynamic condition DSC at various heating rates (2.5–20 °C min⁻¹). Under the isothermal condition, by constructing a master curve, the values of activation energy (E_a) and pre-exponential factor (A) were calculated 89.3 kJ mol⁻¹ and 1.2 × 10⁺⁹ s⁻¹, respectively. The activation energy of the curing reactions in a dynamic mode was obtained 85.32 kJ mol⁻¹ and 88.02 kJ mol⁻¹ using Kissinger and Ozawa methods, respectively. Likewise, pre-exponential factors were also calculated 3.35 × 10⁺⁸ and 7.4 × 10 ⁺⁸ s⁻¹, respectively. The overall order of reaction for both conditions was found to be a value around 3.

     

Lattice Boltzmann Pore Scale Simulation of Natural Convection in a Differentially Heated Enclosure Filled with a Detached or Attached Bidisperse Porous Medium

In this research, pore scale simulation of natural convection in a differentially heated enclosure filled with a conducting bidisperse porous medium is investigated using the thermal lattice Boltzmann method. For the first time, the effect of connection of the bidisperse porous medium to the enclosure walls is studied by considering the attached geometry in addition to the detached one. Effect of most relevant parameters on the streamlines and isotherms as well as hot wall average Nusselt number is studied for two of the bidisperse porous medium configurations. It is observed that effect of geometrical and thermo-physical parameters of the bidisperse porous medium on the heat transfer characteristics is more complicated for the attached configuration. To assess the validity of the local thermal equilibrium condition in the micro-porous media, the pore scale results are used to compute the percentage of the local thermal non-equilibrium for two of the bidisperse porous medium configurations. It is concluded that for the detached configuration, the local thermal equilibrium condition is confirmed in the entire micro-porous media for the ranges of the parameters studied here. However, for the attached geometry, it is shown that departure from the local thermal equilibrium condition is observed for the higher values of the Rayleigh number, micro-porous porosity, solid–fluid thermal conductivity ratio, and the smaller values of the macro-pores volume fraction.