Action du fluorure de potassium sur les tosylates α-fluores: Synthese et proprietes de derives 1,2-difluores.

Fluorinated alcohols, synthesised from epoxides by action of trimethylamine fluorhydrate, can be transformed to 1,2-fluorotosylates when they are treated with tosyl chloride in pyridine. The physico-chemical propreties of these fluorotosylates are studied. The action of KF, in diethylen glycol, on these α-fluorinated tosylates gives the corresponding 1,2-difluorinated compounds in good yield. The stereochemical course of the last reaction can be elucidated from an analysis of the ¹⁹F NMR of the 1,2-difluorocyclohexane.     

Crystal structure,thermal analysis and IR spectrometric investigation of bis (2‐amino‐6‐methyl) pyridinium sulfate

The synthesis method, crystal structure determination, phase transitions studied by thermal analysis and IR spectrometric investigation of 2C₆H₉N₂⁺.SO₄^2– are reported. The compound crystallizes in the monoclinic space group C2/c (no. 15) with a = 10.5068(4) Å, b = 10.2225(5) Å, c = 14.0422(7) Å, and β = 104.489(3)°. The atomic arrangement can be described by layers built by all the components of the structure and centered by planes z = 1/4 and 3/4. The organic molecules form channels parallel to the c direction with dimensions of 4.163(1)Å and 5.148(4)Å. Thermal analysis shows that the anhydrous compound presents an irreversible weak phase transition. The IR study, based on theoretical analyses and on the literature data allows the interpretation of the IR spectrum. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Quantum field induced strains in nanostructures and prospects for optical actuation

We develop the mechanics theory of a phenomenon in which strain is induced in nanoscale structures in the absence of applied stress, due solely to the presence of quantum mechanical confinement of charge carriers. The direct effect of strain on electronic structure has been widely studied in recent years, but the “reverse coupling” effect that we investigate, which is only appreciable in the smallest structures, has been largely ignored even though its effects are present in first principles atomistic calculations. We develop a simple effective mass approach that can be used to model this universal physical phenomenon allowing a transparent scheme to identify its occurrence. We relate quantum field induced strain to acoustic polarons and identify the presence of this effect in density functional theory calculations of strain and quantum confinement in free-standing Si and GaAs quantum dots. Finally, we discuss the use of this quantum confinement induced strain as a mechanism for universal optical actuation in nanowire structures in the context of recent experimental results on carbon nanotubes.     

Numerical modeling of the generation of internal waves by uniform stratified flow over a thin vertical barrier

Numerical simulations of two‐dimensional stratified flow past an obstacle (thin vertical strip) were performed at relatively low Reynolds numbers. A finite differences solver was adopted to simultaneously solve Navier–Stokes equations together with transport equations for salinity (stratifying agent), and the standard Smagorinsky turbulent closure scheme was called in whenever necessary to account for turbulence. The emphases were on the evaluation of code for unsteady stratified flow applications as well as identification of transient and steady internal‐wave processes during flow past obstacles. Simulations were compared with laboratory experiments, where observations were made using a high resolution Schlieren technique and conductivity probes. Blocking was observed upstream of the obstacle, surrounded by near‐zero frequency internal waves, the phase lines of which joined those of lee waves through a transition zone in the proximity of the obstacle. This pattern was preceded by initial transients of the starting flow in which propagating internal waves played a dominant role. Confluence of isopycnals passing over/under the obstacle in the wake led to interesting flow phenomena, including the radiation of internal waves. The numerical simulations were in good agreement with observations, except that some phenomena could not be captured due to resolution issues of either numerical or experimental techniques. The efficacy of the code in point for stratified flow calculations with relevance to the atmosphere and oceans was confirmed. Copyright © 2011 John Wiley & Sons, Ltd.     

Effet d'un champ magnétique transversal sur la stabilité de l'écoulement de Hartmann : les modes tridimensionnels

A numerical study is conducted in order to determine the influence of a transverse magnetic field on the three-dimensional instabilities of the Hartmann flow. We prove that the Squire transformation currently used to characterize such instabilities give satisfactory results only in the case where Ha is weak and 3D modes are slightly deviated from the 2D modes. Such a study is justified by the fact that the two-dimensional instabilities could not always explain successfully the experimental observations relating to the transition phenomenon. To cite this article: M. Jédidi et al., C. R. Mecanique 333 (2005).     

Local electrochemical impedance spectroscopy: A window into heterogeneous interfaces

The ability to probe surface reactivity on a local scale has led to a new insight into the comprehension of the electrochemical reactivity in relation with the microstructure of the surface. Among the different techniques developed in recent years, local electrochemical impedance spectroscopy has the advantage of using a transient approach to locally characterize a stationary electrochemical system without the need to add any redox mediator in solution, which is a great advantage for the study of different systems.In this review, particular attention is paid to the different ways of measuring the local impedance, and the technique implementing a local current measurement in solution is deeply discussed. This local electrochemical impedance spectroscopy journey also encompasses a discussion about technical and experimental limitations.     

Highly Selective and Sensitive Aggregation-Induced Emission of Fluorescein-Coated Metal Oxide Nanoparticles

We report the synthesis, characterization, and photophysical properties of novel metal oxide nanoparticles (NPs) coated with specially designed fluorescein substituents which are capped with electron-withdrawing groups. The fluorescein-coated nanoparticles were synthesized in excellent yields, and their structures were confirmed using various advanced spectroscopic, instrumental, and surface analysis techniques, revealing the formation of the target functionalized nanoparticles (FNPs) which show superior chemical and thermal stabilities. In addition, the photophysical properties of the FNPs were examined using UV-visible absorption and fluorescence spectroscopy. These latter techniques disclosed aggregation-induced emission (AIE) properties for most of the target FNPs, namely those which are soluble in common organic solvents at selective concentration ranges of water fractions in the solvent mixture.     

Concentration and solvent induced micellization of F68 tri-block copolymer

The Fourier transform infrared spectroscopy is used to study the binary mixtures of F68/water and F68/p-xylene. The results show that in aqueous solution the wavenumbers of the two bands associated to the O-H and C-O-C vibrations are inversely proportional. This can be explained by the fact that the dehydrated methylene groups approach by the hydrophobic interaction to form hydrophobic cores, which lead to a breakdown of the hydrogen bond between water and C-O-C. The spectrum associated to the binary mixture F68/p-xylene show that F68 exists as nonassociated molecules (unimers) at room temperature. The results of the ternary mixtures of the F68/p-xylene/water show a change in the spectra on the level of the vibrations of the O-H and C-O-C groups which is attributed to the change of structure following the variation of the concentration from unimers to large aggregates.