全文获取类型
收费全文 | 150篇 |
免费 | 5篇 |
专业分类
化学 | 97篇 |
晶体学 | 5篇 |
力学 | 11篇 |
数学 | 21篇 |
物理学 | 21篇 |
出版年
2022年 | 1篇 |
2021年 | 3篇 |
2020年 | 3篇 |
2019年 | 3篇 |
2018年 | 5篇 |
2017年 | 6篇 |
2016年 | 6篇 |
2015年 | 6篇 |
2014年 | 3篇 |
2013年 | 23篇 |
2012年 | 9篇 |
2011年 | 6篇 |
2010年 | 5篇 |
2009年 | 7篇 |
2008年 | 5篇 |
2007年 | 5篇 |
2006年 | 6篇 |
2005年 | 10篇 |
2004年 | 7篇 |
2003年 | 5篇 |
2002年 | 8篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1995年 | 5篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1988年 | 1篇 |
1981年 | 1篇 |
1979年 | 2篇 |
1978年 | 1篇 |
排序方式: 共有155条查询结果,搜索用时 15 毫秒
31.
Moez Guettari Riadh Gomati Abdelhafidh Gharbi 《Journal of Macromolecular Science: Physics》2013,52(3):552-562
The behavior of polyvinylpyrrolidone in mixed water/methanol solvents was studied by rheoviscosimetry over a temperature range of 20°C–40°C. For the lower temperatures of this range, the intrinsic viscosity variation of the polymer vs. methanol molar fraction shows structural transitions (coil–globule–coil). This transition, which is usually attributed to the cononsolvency phenomenon, agrees with our previously published results obtained by dynamic light scattering. For higher temperatures, near 40°C, the intrinsic viscosity increase shows an expansion of the polymer over the alcohol molar fraction range 0.2 < X A < 0.5. This last result can be attributed to the water/alcohol complex destruction under temperature increase. The “excess viscosity” of the polymer-mixed solvents vanishes with increasing temperature and becomes positive at 40°C. So, the polymer chain tends to transit from a globular to an ideal chain in the middle composition range of the mixed solvents. 相似文献
32.
Tijani Pakhrou 《Mathematische Nachrichten》2008,281(3):396-401
Let Y be a reflexive subspace of the Banach space X, let (Ω, Σ, μ) be a finite measure space, and let L∞(μ, X) be the Banach space of all essentially bounded μ ‐Bochner integrable functions on Ω with values in X, endowed with its usual norm. Let us suppose that Σ0 is a sub‐σ ‐algebra of Σ, and let μ0 be the restriction of μ to Σ0. Given a natural number n, let N be a monotonous norm in ?n . We prove that L∞(μ, Y) is N ‐simultaneously proximinal in L∞(μ,X), and that if X is reflexive then L∞(μ0, X) is N ‐simultaneously proximinal in L∞(μ, X) in the sense of Fathi, Hussein, and Khalil [3]. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
33.
Claire André Teddy Bagnost Samuel Limat Tijani Gharbi Yves Claude Guillaume 《Chromatographia》2008,68(9-10):807-810
In a previous paper (Bagnost et al., J Chromatogr B Analyt Technol Biomed Life Sci 853:38–46, 2007), an arginase chromatographic support was developed to study the association mechanism of arginase (an enzyme which can reduce endothelial dysfunction and blood pressure rising in spontaneously hypertensive rats) with nor-NOHA a potential inhibitor of its activity. In this report mutagenesis experiments associated with this biochromatographic approach confirmed that the active-site residue Hist 141 is protonated as imidazolium cation. Hist 141 could function as a general acid to protonate the leaving amino group of l-ornithine during catalysis. 相似文献
34.
The molecular structures, conformational stabilities, and infrared vibrational wavenumbers of 2-thiophenecarboxaldehyde and 3-thiophenecarboxaldehyde are computed using Becke-3–Lee–Yang–Parr (B3LYP) with the 6-311++G** basis set. From the computations, cis-2-thiophenecarboxaldehyde is found to be more stable than the transfer conformer with an energy difference of 1.22 kcal/mol, while trans-3-thiophenecarboxaldehyde is found to be more stable than the cis conformer by 0.89 kcal/mol. The computed dipole moments, structural parameters, relative stabilities of the conformers and infrared vibrational wavenumbers of the two molecules coherently support the experimental data in the literature. The normal vibrational wavenumbers are characterized in terms of the potential energy distribution using the VEDA4 program. The effect of solvents on the conformational stability of the molecules in nine different solvents is investigated using the polarizable continuum model. 相似文献
35.
Tijani A. Apalara Salim A. Messaoudi Ahmed A. Keddi 《Mathematical Methods in the Applied Sciences》2016,39(10):2671-2684
In this work, we study the well‐posedness and the asymptotic stability of a one‐dimensional linear thermoelastic Timoshenko system, where the heat conduction is given by Cattaneo's law and the coupling is via the displacement equation. We prove that the system is exponentially stable provided that the stability number χτ=0. Otherwise, we show that the system lacks exponential stability. Furthermore, in the latter case, we show that the solution decays polynomially. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
36.
Mehdi Zeghal Loïc Auvray Mondher Jebbari Abdelhafidh Gharbi 《Macromolecular Symposia》2005,222(1):149-156
We study by SANS the structure of intermolecular complexes formed through hydrogen bonding and hydrophobic interactions between poly(methacrylic acid) (PMA) and a neutral copolymer surfactant (PEO-PPO-PEO). The contrast variation method enables us to probe the structure factor of each polymer in the complex and their cross structure factor. The number of copolymer chains, which results from the cooperative action of hydrogen bonding and hydrophobic interactions increases as the charge of the polyacid decreases. The aggregation preserves the micellar core-corona organization of the copolymer and shrinks the polyacid chains which adopt a similar compact structure. Finally, the structure of the aggregates is compared to that of PEO-PMA homopolymer complex observed by SANS. 相似文献
37.
38.
Anouar Rich Youssef Mandri Denis Mangin Alain Rivoire Souad Abderafi Christine Bebon Naoual Semlali Jean-Paul Klein Tijani Bounahmidi Ahmed Bouhaouss Stéphane Veesler 《Journal of Crystal Growth》2012,342(1):110-116
This work aims at developing a dynamic layer crystallizer operated batchwise, for freezing desalination of sea water. The experiments were performed with water/NaCl solutions and with samples of sea water from Nice, Rabat and Marseille. The pilot crystallizer consists of a cooled tube immersed in a cylindrical double jacketed tank. The solution is poured into the tank and the crystallization takes place on the external surface of the tube, by applying a cooling ramp in the tube. The solution is agitated by air bubbling. The whole process involves the freezing step, leading to the crystallization of the ice layer and the sweating step, which consists of purifying in depth the ice layer by melting the impure zones. A parametric study on the effect of the operating parameters has allowed quantifying the role of the different key parameters of the freezing and sweating steps. Three experiments allowed reaching salinities lower than 0.5 g/kg, satisfying the standards of drinking water. The duration of the whole process dropped to only 8 h (5 h for freezing and 3 h for sweating), with a yield of sweating equal to about 50%, provided severe conditions were applied for sweating. Higher yields required longer times. Overall, the results show the feasibility of the technique. 相似文献
39.
Houcine Ammar Fatma Abdelkafi Souhir Abid Bouchra Benjelloum-Mlayah Rachid El Gharbi Michel Delmas 《Chemistry of Natural Compounds》2012,48(1):99-102
Alfa grass pulping was successfully performed in hydro-organic acid medium under mild conditions (107°C, atmospheric pressure, cooking
time: 3 h). Use of an acetic acid/formic acid/water mixture as pulping liquor was perfectly suitable for selective isolation
of pulp, lignin, and hemicelluloses. The unbleached pulp obtained in good yield was first delignified by peroxyacids in organic
acid medium and then bleached with hydrogen peroxide in a basic medium to give pulp offering good physico-chemical and mechanical
characteristics. 相似文献
40.
We have investigated the viscoelastic behaviour exhibited by chiral smectic C* phases in homeotropic orientation. For an appropriate scattering geometry and using the light scattering technique, the orientational diffusivities associated with the Goldsone mode in ferro- and antiferroelectric phases of C11thiobenzoate and C8tolane compounds have been measured. (SmCA*) is about 100 times weaker than (SmC*). This divergence may be largely attributed to the mode of the molecular arrangement in ferro- and antiferroelectric phases, in spite of the same helical structure observed in the two phases. 相似文献