Biodegradable hyperbranched polyesters derived from 1,1,1‐tris(hydroxymethyl)ethane

Low molar mass hyperbranched polyesters were prepared by polycondensation of 1,1,1‐tris(hydroxymethyl)ethane and various dimethyl esters of aliphatic dicarboxylic acids in bulk. The usefulness of nontoxic bismuth salts as transesterification catalysts for these polycondensations was studied. The maximum conversion increased, and the reaction time decreased in the following sequence of increasing reactivity: dimethyl sebacate < adipate < glutarate < succinate. Regardless of the monomer combination, gelation occurred at conversions > 91.5%. The hyperbranched structure was proven by ¹H NMR spectroscopy and the absence of cyclic elements by MALDI‐TOF mass spectrometry. Quantitative acylation of all CH₂OH groups was achieved with an excess of acetic anhydride or methycrylic anhydride. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 231–238, 2009     

Trennung von Proteinen und Protein-Untereinheiten

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Eine Methode zur quantitativen Bestimmung von freiem und peptidgebundenem Tryptophan

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Die quantitative gas-chromatographische Bestimmung von Fentanyl in L?sungen

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Die gasehromatographische Bestimmung der Bleialkyle in Ottokraftstoffen mit dem Elektroneneinfangdetektor

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Die spektralphotometrische Bestimmung von Mikrogramm-Mengen Vanadium in Solen

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Untersuchungen über die Energieabhängigkeit von Kernreaktionen mit Neutronen im Energiebereich zwischen 12 und 19 MeV

Continuing earlier investigations we studied the energy dependence of the cross sections of the following nuclear reactions produced by neutrons in the energy range from 12 to 19 MeV: P³¹(n, 2n)P³², P³¹(n,α)Al²⁸, Cu⁶⁵(n, 2n)Cu⁶⁴, Cu⁶⁵(n, p)Ni⁶⁵, Zn⁶⁴(n, 2n)Zn⁶³, Zn⁶⁴(n, p)Cu⁶⁴, V⁵¹(n, p)Ti⁵¹, Br⁷⁹(n, α)As⁷⁶, O¹⁶(n, α)C¹³. The results were compared with cross sections calculated according to the statistical theory, considering the competition ofγ-ray emission and particle (predominantly neutron) emission from the excited residual nucleus.