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151.
152.
With the emergence of an information society, the idea of protecting sensitive data is steadily gaining importance. Conventional encryption methods may not be sufficient to guarantee data protection in the future. Quantum key distribution (QKD) is an emerging technology that exploits fundamental physical properties to guarantee perfect security in theory. However, it is not easy to ensure in practice that the implementations of QKD systems are exactly in line with the theoretical specifications. Such theory–practice deviations can open loopholes and compromise security. Several such loopholes have been discovered and investigated in the last decade. These activities have motivated the proposal and implementation of appropriate countermeasures, thereby preventing future attacks and enhancing the practical security of QKD. This article introduces the so-called field of quantum hacking by summarising a variety of attacks and their prevention mechanisms.  相似文献   
153.
Luminescence from TIBr single crystals at low temperature has been investigated using continuous X-ray and UV excitation as well as pulsed-electron-beam excitation. Four emission bands were observed consistently at 495, 504, 560 and 650 nm, with relative intensities dependent on sample preparation, mode of excitation and measurement temperature. The 560 nm band is shown to be associated with excess thallium at the sample surface. Deformation of the crystal at low temperature (e.g. 9°K) produces recombination centers giving rise to the 504 nm and 650 nm luminescence. Subsequent annealing at temperatures of the order of 120°K causes a decrease in the 504 nm luminescence and the simultaneous appearance of the 495 nm band. These observations are interpreted in terms of the thermal release of recombination centers from the vicinities of the dislocations where they are generated.  相似文献   
154.
155.
Denecke MA  Dardenne K  Marquardt CM 《Talanta》2005,65(4):1008-1014
X-ray absorption near edge structure (XANES) spectroscopy for in situ metal valence determination has become a powerful analytical tool in heterogeneous systems. This is in part because it is applicable without prior separation procedures. For some systems, however, determining the oxidation state from XANES spectra is not straightforward and caution must be used. We show that the analysis of L3,2 edge EXAFS (extended X-ray absorption fine structure) spectra is better suited to distinguish between Np(IV) and Np(V) than from their XANES spectra. Whereas evidence for the oxidation of Np(IV) in solution samples from their Np L3 XANES is unclear, their EXAFS data unequivocally reveals Np(V) formation in the solutions.  相似文献   
156.
BACKGROUND: Human beta-tryptase is a mast cell specific trypsin-like serine protease that is thought to play a key role in the pathogenesis of diverse allergic and inflammatory disorders like asthma and psoriasis. The recently resolved crystal structure revealed that the enzymatically active tetramer consists of four quasi-identical monomers. The spatial display of the four identical active sites represents an ideal basis for the rational design of bivalent inhibitors. RESULTS: Based on modeling experiments homobivalent inhibitors were constructed using (i) 6A,6D-dideoxy-6A,6D-diamino-beta-cyclodextrin as a rigid template to bridge the space between the two pairs of identical active sites and (ii) 3-(aminomethyl)benzene as a headgroup to occupy the arginine/lysine specific S1 subsites. A comparative analysis of the inhibitory potencies of synthetic constructs that differ in size and type of the spacer between headgroup and template revealed that the construct contained two 3-(aminomethyl)benzenesulfonyl-glycine groups linked to the 6A,6D-diamino groups of beta-cyclodextrin as an almost ideal bivalent inhibitor with a cooperativity factor of 1.9 vs. the ideal value of 2. The bivalent binding mode is supported by the inhibitor/tetramer ratio of 2:1 required for inactivation of tryptase and by X-ray analysis of the inhibitor/tryptase complex. CONCLUSION: The results obtained with the rigid cyclodextrin template underlined the importance of a minimal loss of conformational entropy in bivalent binding, but also showed the limitations imposed by such rigid core molecules in terms of optimal occupancy of binding sites and thus of enthalpic strains in bidentate binding modes. The main advantage of bivalent inhibitors is their high selectivity for the target enzyme that can be achieved utilizing the principle of multivalency.  相似文献   
157.
Nanocrystal networks, especially mixtures of chemically different components or gradient materials, may turn out to be absorbers, sensors, detectors, or converters, designed for a variety of specific purposes with high sensitivity and flexibility. Received: 27 March 1998  相似文献   
158.
A multivariate analogue of the fractionally integrated continuous time autoregressive moving average (FICARMA) process defined by Brockwell [Representations of continuous-time ARMA processes, J. Appl. Probab. 41 (A) (2004) 375-382] is introduced. We show that the multivariate FICARMA process has two kernel representations: as an integral over the fractionally integrated CARMA kernel with respect to a Lévy process and as an integral over the original (not fractionally integrated) CARMA kernel with respect to the corresponding fractional Lévy process (FLP). In order to obtain the latter representation we extend FLPs to the multivariate setting. In particular we give a spectral representation of FLPs and consequently, derive a spectral representation for FICARMA processes. Moreover, various probabilistic properties of the multivariate FICARMA process are discussed. As an example we consider multivariate fractionally integrated Ornstein-Uhlenbeck processes.  相似文献   
159.
Guided acoustic wave Brillouin scattering (GAWBS) generates phase and polarization noise of light propagating in glass fibers. This excess noise affects the performance of various experiments operating at the quantum noise limit. We experimentally demonstrate the reduction of GAWBS noise in a photonic crystal fiber in a broad frequency range by tailoring the acoustic modes using the photonic also as a phononic crystal. We compare the noise spectrum to the one of a standard fiber and observe a tenfold noise reduction in the frequency range up to 200 MHz. Based on our measurement results as well as on numerical simulations, we establish a model for the reduction of GAWBS noise in photonic crystal fibers.  相似文献   
160.
We report on the generation of polarization squeezing by employing intense, ultrashort light pulses in a single pass method in photonic crystal fibers. We investigated the squeezing behavior near the zero-dispersion wavelength and in the anomalous dispersion regime by using two distinct fibers. We observed a maximal squeezing at 810 nm of −3.3 ± 0.3 dB with an excess noise of +16.8 ± 0.3 dB in the anomalous regime. Correcting for linear and interference losses between the polarization modes, this corresponds to −6 ± 1 dB. The ratio of squeezing to excess noise indicates the creation of a much purer state; this ratio indeed lies an order of magnitude below those squeezing experiments that exploit traditional fibers [1]. We attribute this increased state of purity to increased effective nonlinearity and to the reduction of scattering on acoustic modes in the fiber. Original Text ? Astro, Ltd., 2007.  相似文献   
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