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991.
Khayat S Hötzl H Geyer S Ali W Knöller K Strauch G 《Isotopes in environmental and health studies》2006,42(3):289-302
Sulphate and chloride concentrations in the shallow Pleistocene aquifer systems in the lower Jordan valley area indicate a general trend of increasing salinity eastward and southward. This study was conducted in one of the important sub-basins feeding the Pleo-Pleistocene aquifer in the Jericho area in the southern part of the valley using S and O isotopes of dissolved sulphate. The results show that sulphate has mainly two contributions to the groundwater. One is the surface seepage, which is present as a salty leachate form with the positive delta34Ssulphate values of primary gypsum in Lisan and Samara formations, and the second is the upwelling saline water which was in contact with a deep secondary gypsum, aragonites and salty rocks and rose up under heavy abstraction with depleted 34S in sulphate and relatively high sulphate and chloride content. The latest was clearly shown in the Arab Project wells to the east that is undergoing a continuous heavy abstraction. The isotopic signatures of S and O in these wells to the east show that this depleted 34S and highly concentrated sulphate might also indicate a dissolved sulphate originating from pyrite oxidation that results from the interaction with a pyrite-rich aquifer, which can well up with salty water under heavy abstraction and is oxidised in the upper aerobic shallow aquifer. 相似文献
992.
The response of a tunnel structure under a moving and oscillating dynamic load can be calculated by means of a hybrid Integral–Transformation–Method–FEM approach. In the ITM approach analytical solutions of ideal geometries of the infinite continuum are superposed such that the wave–number impedance and transfer–function at the interior of a circular tunnel can be calculated efficiently. By this means the infinite continuum can be coupled to an arbitrary tunnel structure which is modelled by the FEM with corresponding form–functions. In order to reduce the effort for the coupling, the characteristics of the analytically given transfer–functions which can be split into near– and far–fields is taken into account. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
993.
994.
Debdutta Lahiri Surinder M. Sharma Ashok K. Verma B. Vishwanadh G. K. Dey Gerhard Schumacher Tobias Scherb Heinrich Riesemeier Uwe Reinholz Martin Radtke S. Banerjee 《Journal of synchrotron radiation》2014,21(6):1296-1304
Short‐range order has been investigated in Zr69.5Cu12Ni11Al7.5 and Zr41.5Ti41.5Ni17 metallic glasses using X‐ray absorption spectroscopy and ab initio molecular dynamics simulations. While both of these alloys are good glass formers, there is a difference in their glass‐forming abilities (Zr41.5Ti41.5Ni17 > Zr69.5Cu12Ni11Al7.5). This difference is explained by inciting the relative importance of strong chemical order, icosahedral content, cluster symmetry and configuration diversity. 相似文献
995.
Novel carotenoids genetically engineered in a heterologous host 总被引:2,自引:0,他引:2
Sandmann G 《Chemistry & biology》2003,10(6):478-479
Carotenoids are commercially important pigments that are essential for human health. Diverse carotenoids have been identified, but availability has impeded evaluation of their pharmaceutical potential. Molecular techniques have been developed to produce specific and novel carotenoids with improved biological activities. 相似文献
996.
G Höfle K Gerth H Reichenbach B Kunze F Sasse E Forche EV Prusov 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(36):11362-11370
Eliamid is a secondary metabolite isolated from two bacterial strains. This molecule features a linear polyketide backbone terminated by a tetramic acid amide moiety. Among other biological activities, eliamid shows a high and specific cytostatic action on human lymphoma and cervix carcinoma cell lines. The 2,4-anti relative configuration of the C-2,C-4-dimethyl substituted amide fragment was assigned by means of Breit's rule. The absolute configuration of all stereocenters was determined by a combination of degradation methods, structural similarity analysis and total synthesis. The stereogenic centers were introduced by vinylogous Mukaiyama aldol reaction and two consecutive Myers alkylations. The use of pentafluorophenyl ester as acylation agent allowed the efficient formation of tetramic acid amide. The longest linear sequence in the synthesis consist of 13?steps and proceeds with 12?% overall yield. Differential spectroscopy experiments with beef heart submitochondrial particles established that eliamid is a potent inhibitor of the NADH-ubiquinone oxidoreductase complex. Additionally, biosynthesis of eliamid was investigated by feeding experiments with (13) C-labeled precursors. 相似文献
997.
C Wang X Yang CC Loh G Raabe D Enders 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(37):11531-11535
Sulfenylated oxindoles: The first asymmetric sulfenylation of N-Boc-protected oxindoles has been developed to provide products containing a tetrasubstituted stereogenic center in high to excellent yields (86-98?%) and, in most cases, excellent enantioselectivities (up to 96?%?ee; see scheme). 相似文献
998.
999.
Rafael Martí Gerhard Reinelt Abraham Duarte 《Computational Optimization and Applications》2012,51(3):1297-1317
The linear ordering problem consists of finding an acyclic tournament in a complete weighted digraph of maximum weight. It
is one of the classical NP-hard combinatorial optimization problems. This paper surveys a collection of heuristics and metaheuristic
algorithms for finding near-optimal solutions and reports about extensive computational experiments with them. We also present
the new benchmark library LOLIB which includes all instances previously used for this problem as well as new ones. 相似文献
1000.
Messi BB Ndjoko-Ioset K Hertlein-Amslinger B Lannang AM Nkengfack AE Wolfender JL Hostettmann K Bringmann G 《Molecules (Basel, Switzerland)》2012,17(5):6114-6125
A new flavanone-chromone biflavonoid, preussianone (1), has been isolated from the leaves of Garcinia preussii, along with four known biflavonoids. The absolute stereostructures were elucidated by chemical, spectroscopic, and chiroptical methods. The biological properties of the new biflavonoid against several bacterial strains were evaluated. 相似文献