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991.
Meiyappan Muthuraman Jean‐Franois Nicoud Muriel Bagieu‐Beucher 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(9):1077-1078
The title compound, alternatively sodium pyridin‐2‐olate trihydrate, Na+·C5H3N2O3?·3H2O, crystallizes in the P space group. It is made up of edge‐shared chains of NaO6 octahedra with five water molecules and one 5‐nitro‐2‐pyridonate anion. Four of these water molecules are bicoordinating, involved in connecting the adjacent octahedra, and the fifth is coordinated to only one octahedron. The crystal structure is stabilized by a network of strong O—H?O and O—H?N interactions. The organic moieties occupy the space between the chains with an antiparallel alignment. 相似文献
992.
Manuel Cano Beatriz Palenzuela J. Luis Ávila Rafael Rodríguez‐Amaro 《Electroanalysis》2007,19(9):973-977
A PVC/TTF‐TCNQ composite electrode has been employed as detector in a flow injection system. The proposed method allows the simultaneous detection of ascorbic acid (AA) and uric acid (UA) in mixtures by using a FIA system in a simple manner, without pre‐treatment or modified electrode. This method is based on the amperometric determination of (a) ascorbic acid at 0.15 V and (b) both analytes at 0.35 V, being the response linear in the range 1×10?2–4×10?4 M for both analytes with detection limits (S/N=3) of 1.2×10?4 M and 8.1×10?5 M for AA and UA, respectively. 相似文献
993.
Two new uncommon nitrogenous sesquiterpenes, 11‐ethoxy‐3‐formamidotheonellin ( 1 ) and 7‐ethoxy‐3‐formamidobisabolane‐8,10‐diene ( 2 ), together with two known related sesquiterpenes, 3‐formamidotheonellin (=theonellin formamide; 3 ) and theonellin isothiocyanate ( 4 ), were isolated from the Hainan sponge Axinyssa aff. variabilis. Their structures were determined on the basis of extensive spectroscopic analysis and by comparison of their NMR data with those of known compounds. 相似文献
994.
Zhan‐Xin Zhang Wei‐Dong Xie Ping‐Lin Li Yan‐Ping Shi Zhong‐Jian Jia 《Helvetica chimica acta》2006,89(12):2927-2933
Six new compounds were isolated from the whole plant of Sonchus uliginosus, including three eudesmane‐type sesquiterpenoids (1β,6α)‐1,6,14‐trihydroxyeudesm‐3‐en‐12‐oic acid γ‐lactone ( 1 ), (1β,6α)‐1,6,14‐trihydroxyeudesma‐3,11(13)‐dien‐12‐oic acid γ‐lactone ( 2 ), and (1β,6α)‐1,6‐dihydroxy‐14‐O‐[(4‐hydroxyphenyl)acetyl]eudesma‐3,11(13)‐dien‐12‐oic acid γ‐lactone ( 3 ), and three phenylpropane derivatives, 4‐hydroxy‐γ,3,5‐trimethoxybenzenepropanol ( 6 ), γ,3,4,5‐tetramethoxybenzenepropanol ( 7 ), and γ,3,4,5‐tetramethoxybenzenepropanol acetate ( 8 ), together with the two known compounds 4 and 5 . The new structures were elucidated by means of spectroscopic methods, such as IR, EI‐MS, HR‐ESI‐MS, 1D‐ and 2D‐NMR, and by comparison of the spectroscopic data with those reported for structurally related compounds. 相似文献
995.
The isolation and identification of twenty‐one components (including four new triterpenoid saponins and one new triterpenoid acid) from the root of Rhaponticum uniflorum (L.) DC. (Compositae) are described. Their structures were determined on the basis of spectral analysis and chemical trans formation. The new compounds were identified as 3‐O‐α‐L‐arabinopyranosyl‐urs‐12,18(19)‐dien‐28‐oic acid β‐D‐glucopyranosyl ester, 3β‐ hydroxyurs‐12,18(19)‐dien‐28‐oic acid β‐D‐glucopyranosyl ester, 3β‐hydroxyurs‐12,19(29)‐dien‐28‐oic acid β‐D‐glucopyranosylester, 3‐O‐α‐L‐arabinopyranosyl‐urs‐9(11),12‐dien‐28‐oic acid β‐D‐glucopyranosyl ester and 2 α,3 α, 19α,25‐tetrahydroxyurs‐12‐en‐23,28‐dioic acid. 相似文献
996.
Ju‐Yeon Lee Eun‐Ju Park 《Journal of polymer science. Part A, Polymer chemistry》2002,40(11):1742-1748
Methyl 3,4‐di‐(2′‐hydroxyethoxy)benzylidenecyanoacetate ( 3 ) was prepared by hydrolysis of methyl 3,4‐di‐(2′‐vinyloxyethoxy)benzylidenecyanoacetate ( 2 ). Diol 3 was condensed with 2,4‐toluenediisocyanate, 3,3′‐dimethoxy‐4,4′‐biphenylenediisocyanate, and 1,6‐hexamethylenediisocyanate to yield polyurethanes 4 – 6 containing the nonlinear optical chromophore 3,4‐dioxybenzylidenecyanoacetate. The resulting polyurethanes 4 – 6 were soluble in common organic solvents such as acetone and dimethylformamide. Polymers 4 – 6 indicated thermal stability up to 300 °C in thermogravimetric thermograms with glass‐transition temperature values obtained from differential scanning calorimetric thermograms in the range of 78–102 °C. The second‐harmonic generation coefficients (d33) of the poled polymer films were around 6.9 × 10?9 esu. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 1742–1748, 2002 相似文献
997.
A. Jeyabharathi M. N. Ponnuswamy S. Nanjundan Hoong‐Kun Fun Suchada Chantrapromma Anwar Usman Ibrahim Abdul Razak 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(1):o26-o28
Chalcones (α,β‐unsaturated ketones) are effective antitumour agents. It has been proved that having halogen or methoxy groups substituted in various positions of the phenyl ring enhances the activity of chalcones many times. The title compounds, C21H20O5 and C19H15BrO3, respectively, were chosen for crystallographic study in order to determine their structures and conformations. In both compounds, the keto group is in the s‐cis conformation and is almost planar. There are weak intramolecular interactions in both structures. 相似文献
998.
Solutions of the perfluoro anion-exchange membrane TosHex® in a solvent mixture composed of methanol + isopropanol + water (1:1:1) were prepared and applied in coating glassy carbon electrodes. The evaporated films were used to accumulate the Fe(CN)
6 redox couple on the electrode surface. The magnitude of the electrochemical response of the loaded films is comparable with that for Nafion® incorporated cationic redox species. The multicharged Fe(CN)
6 couple accumulated in Tosflex® film causes an ion cross-linking of the polymeric backbone, thus decreasing ion transport in the film substantially. 相似文献
999.
Prem Paul Singh Jan Spitzer Robert M. McKay Keith G. McCurdy Loren G. Hepler 《Thermochimica Acta》1978,24(1):111-115
We have made calorimetric and density measurements leading to apparent molar heat capacities and volumes of dilute aqueous solutions of silver nitrate and silver perchlorate at 298 K. Resulting apparent molar properties at infinite dilution are the following: φoc(AgNO3) = ? 36.8 J K?1 mol?1, φov(AgNO3) = 29.1 cm3 mol?1, φoc(AgClO4) = 11.0 J K?1 mol?1, and φov(AgClO4) = 43.5 cm3 mol?1. 相似文献
1000.
Bożena Tutaj Anna Kasprzyk Jan Czapkiewicz 《Journal of inclusion phenomena and macrocyclic chemistry》2003,47(3-4):133-136
A survey of the literature reveals that the spectroscopic displacement method, in which phenolphthalein is used as a competitive chromophore to determine binding constants of β-cyclodextrin with surfactants was successful in the case of homologous hydrocarbon and fluorocarbon anionic surfactants. We show here that this method can be applied also for homologous alkyltrimethylammonium bromides (with alkyl varying from octyl- to hexadecyl) under the condition that the concentration of the cationic surfactant is distinctly lower than the value of itscritical micelle concentration. 相似文献