Potassium thiocyanate argentates: K3[Ag(SCN)4], K4[Ag2(SCN)6] and K[Ag(SCN)2]

The anions of the title compounds contain [Ag(SCN)₄] units, with the S atoms coordinating to Ag⁺ in a tetrahedral arrangement. Whereas in the isolated anions of tripotassium tetra­thio­cyanatoargentate(I), K₃[Ag(SCN)₄], (I), all SCN^? groups are bonded as terminal ligands, in tetrapotassium di‐μ‐thio­cyanato‐S:S‐bis­[dithio­cyanato­argentate(I)], K₄[Ag₂(SCN)₆], (II), two AgS₄ tetrahedra share one common edge. In poly[potassium [argentate(I)‐di‐μ‐thio­cyanato‐S:S]], K[Ag(SCN)₂], (III), edge‐ and vertex‐sharing of AgS₄ tetrahedra results in infinite [Ag(SCN)₂]^? layers.     

Feedback-controlled optimization of amplified femtosecond laser pulses

Received: 17 December 1998     

Femtosecond nonresonant degenerate four-wave mixing at atmospheric pressure and in a free jet

2 , N₂, and CO₂. For CO₂ additional experiments have been performed at reduced pressure and in a molecular beam. By delaying the probe pulse a periodic recovery of the DFWM signal is observed. The period of these transients can be assigned unambiguously to rotational Raman transitions of the ground state within the laser bandwidth. The decay of the transients yields the collisional dephasing of the Raman-induced polarization. At zero delay also optical-field-induced birefringence of electronic nature contributes to the signal. The different time scales of the Raman and electronic effects allow us to estimate their relative strength. Received: 3 August 1998 / Revised version: 21 October 1998 / Published online: 24 February 1999     

Time-resolved two-photon photoemission spectroscopy of HOPG and Ag nanoparticles on HOPG

Received: 6 November 1998     

Lattice site occupation and precipitate dissolution of implanted and irradiated Al(Rh) and Al(Ir)

Abstract

The apparent substitutional fraction, f_s , of Rh and Ir implanted into Al single crystals at 293 K with peak concentrations of 0.17±0.01 at.% is 0.57 ± 0.02 and 0.47±0.02, respectively. Upon annealing to 593 K f_s decreases and the critical angles of the impurities narrow due to partially coherent precipitate formation. Irradiation with 300 keV Ar ions at 77 K with deposited energy densities up to 20 dpa leads to precipitate dissolution accompanied by an increase of f_s up to 0.70±0.02 for Al(Rh) and 0.82±0.02 for Al(Ir). The relatively high f_s values do not decrease during annealing from 77 K to 293 K, indicating that vacancy trapping is not a dominant process. Precipitate formation seems therefore to limit the maximum obtainable f_s values during implantation at 293 K for these systems.     

Nachweis und Bestimmung von Nitraten in der Milch

Ohne Zusammenfassung     

Optimal dividends in the dual model

The optimal dividend problem proposed by de Finetti [de Finetti, B., 1957. Su un’impostazione alternativa della teoria collettiva del rischio. In: Transactions of the XVth International Congress of Actuaries, vol. 2. pp. 433-443] is to find the dividend-payment strategy that maximizes the expected discounted value of dividends which are paid to the shareholders until the company is ruined or bankrupt. In this paper, it is assumed that the surplus or shareholders’ equity is a Lévy process which is skip-free downwards; such a model might be appropriate for a company that specializes in inventions and discoveries. In this model, the optimal strategy is a barrier strategy. Hence the problem is to determine b^∗, the optimal level of the dividend barrier. A key tool is the method of Laplace transforms. A variety of numerical examples are provided. It is also shown that if the initial surplus is b^∗, the expectation of the discounted dividends until ruin is the present value of a perpetuity with the payment rate being the drift of the surplus process.     

Searching for evolutions from pure states into mixed states with entangled neutral kaons

Entangled two-quantum states may be a sensitive probe for a loss of quantum coherence due to apparent violations of quantum mechanics, e.g. as caused by gravitation. We show that there exists a modest experiment sensitive to any one of the nine phenomenological parameters which describe decoherence in the neutral kaon system.Received: 14 March 2003, Published online: 26 November 2003     

The adhesion molecule Necl-3/SynCAM-2 localizes to myelinated axons,binds to oligodendrocytes and promotes cell adhesion

Background  

Cell adhesion molecules are plasma membrane proteins specialized in cell-cell recognition and adhesion. Two related adhesion molecules, Necl-1 and Necl-2/SynCAM, were recently described and shown to fulfill important functions in the central nervous system. The purpose of the work was to investigate the distribution, and the properties of Necl-3/SynCAM-2, a previously uncharacterized member of the Necl family with which it shares a conserved modular organization and extensive sequence homology.     

Quantum control by ultrafast polarization shaping

We demonstrate that the use of time-dependent light polarization opens a new level of control over quantum systems. With potassium dimer molecules from a supersonic molecular beam, we show that a polarization-shaped laser pulse increases the ionization yield beyond that obtained with an optimally shaped linearly polarized laser pulse. This is due to the different multiphoton ionization pathways in K2 involving dipole transitions which favor different polarization directions of the exciting laser field. This experiment is a qualitative extension of quantum control mechanisms which opens up new directions giving access to the three-dimensional temporal response of molecular systems.