全文获取类型
收费全文 | 2647篇 |
免费 | 71篇 |
国内免费 | 15篇 |
专业分类
化学 | 1899篇 |
晶体学 | 7篇 |
力学 | 48篇 |
数学 | 388篇 |
物理学 | 391篇 |
出版年
2020年 | 28篇 |
2019年 | 29篇 |
2016年 | 54篇 |
2015年 | 51篇 |
2014年 | 46篇 |
2013年 | 102篇 |
2012年 | 134篇 |
2011年 | 155篇 |
2010年 | 79篇 |
2009年 | 74篇 |
2008年 | 162篇 |
2007年 | 122篇 |
2006年 | 129篇 |
2005年 | 110篇 |
2004年 | 98篇 |
2003年 | 81篇 |
2002年 | 92篇 |
2001年 | 40篇 |
2000年 | 38篇 |
1999年 | 41篇 |
1998年 | 35篇 |
1997年 | 41篇 |
1996年 | 41篇 |
1995年 | 35篇 |
1994年 | 25篇 |
1993年 | 39篇 |
1992年 | 34篇 |
1991年 | 29篇 |
1990年 | 21篇 |
1989年 | 33篇 |
1988年 | 30篇 |
1987年 | 23篇 |
1985年 | 42篇 |
1984年 | 43篇 |
1983年 | 28篇 |
1982年 | 39篇 |
1981年 | 32篇 |
1980年 | 50篇 |
1979年 | 41篇 |
1978年 | 44篇 |
1977年 | 24篇 |
1976年 | 27篇 |
1975年 | 32篇 |
1974年 | 20篇 |
1973年 | 28篇 |
1971年 | 19篇 |
1968年 | 14篇 |
1966年 | 16篇 |
1960年 | 14篇 |
1959年 | 15篇 |
排序方式: 共有2733条查询结果,搜索用时 15 毫秒
111.
Walter MJ Lupton JM Becker K Feldmann J Gaefke G Höger S 《Physical review letters》2007,98(13):137401
Simultaneous surface enhanced Raman scattering (SERS) and fluorescence is demonstrated from single conjugated polymer chains. As resonance enhancement of SERS depends on the spectral overlap of the polymer's absorption and the incident laser, resonance Raman and fluorescence effectively probe the absorbing and emitting part of the polymer, respectively. The optical phonon energies change along the polymer chain, providing a window to spatially track excited state relaxation. Whereas a mean spatial redistribution of the excitation is witnessed by a change in vibronic fingerprint following interchromophoric energy transfer, intrachromophoric exciton self-trapping leaves the vibrations unchanged. 相似文献
112.
Warburton RE McCarthy A Wallace AM Hernandez-Marin S Hadfield RH Nam SW Buller GS 《Optics letters》2007,32(15):2266-2268
We demonstrate subcentimeter depth profiling at a stand off distance of 330 m using a time-of-flight approach based on time-correlated single-photon counting. For the first time to our knowledge, the photon-counting time-of-flight technique was demonstrated at a wavelength of 1550 nm using a superconducting nanowire single-photon detector. The performance achieved suggests that a system using superconducting detectors has the potential for low-light-level and eye-safe operation. The system's instrumental response was 70 ps full width at half-maximum, which meant that 1 cm surface-to-surface resolution could be achieved by locating the centroids of each return signal. A depth resolution of 4 mm was achieved by employing an optimized signal-processing algorithm based on a reversible jump Markov chain Monte Carlo method. 相似文献
113.
Petrus Zwart John Taylor Simon Morton Randall Cayford Gerald Fontenay Marc Allaire 《Synchrotron Radiation News》2015,28(2):22-27
The Berkeley Center for Structural Biology (BCSB) operates and develops a suite of protein crystallography beamlines at the Advanced Light Source (ALS) located at Lawrence Berkeley National Laboratory (LBNL). Although the ALS was conceived as a low-energy (1.9-GeV), third-generation synchrotron source of vacuum ultraviolet (VUV) and soft X-ray radiation, it was realized during the development of the facility in the mid-1990s that a multipole wiggler coupled with brightness-preserving optics would result in a beamline whose performance in the energy range of 5 to 15 keV would be sufficient for most protein crystallographic experiments. Later, the hard X-ray capabilities of the ALS were expanded by the addition of three superconducting bending magnets, resulting in additional protein crystallography facilities at the ALS [1]. 相似文献
114.
M.Sc. Johannes E. M. N. Klein Dr. Burkhard Miehlich Dr. Michael S. Holzwarth Prof. Dr. Matthias Bauer Dipl.‐Chem. Magdalena Milek Dr. Marat M. Khusniyarov Dr. Gerald Knizia Prof. Dr. Hans‐Joachim Werner Prof. Dr. Bernd Plietker 《Angewandte Chemie (International ed. in English)》2014,53(7):1790-1794
During the past 10 years iron‐catalyzed reactions have become established in the field of organic synthesis. For example, the complex anion [Fe(CO)3(NO)]?, which was originally described by Hogsed and Hieber, shows catalytic activity in various organic reactions. This anion is commonly regarded as being isoelectronic with [Fe(CO)4]2?, which, however, shows poor catalytic activity. The spectroscopic and quantum chemical investigations presented herein reveal that the complex ferrate [Fe(CO)3(NO)]? cannot be regarded as a Fe?II species, but rather is predominantly a Fe0 species, in which the metal is covalently bonded to NO? by two π‐bonds. A metal–N σ‐bond is not observed. 相似文献
115.
Fe or FeNO Catalysis? A Quantum Chemical Investigation of the [Fe(CO)3(NO)]−‐Catalyzed Cloke–Wilson Rearrangement 下载免费PDF全文
Johannes E. M. N. Klein Dr. Gerald Knizia Dr. Burkhard Miehlich Prof. Dr. Johannes Kästner Prof. Dr. Bernd Plietker 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(24):7254-7257
A quantum chemical investigation of the Bu4N[Fe(CO)3(NO)]‐catalyzed Cloke–Wilson rearrangement of vinyl cyclopropanes is reported. It was found that allylic C?C bond activation can proceed through a SN2′ or SN2‐type mechanism. The application of the recently reported intrinsic bond orbital (IBO) method for all structures indicated that one Fe?N π bond is directly involved. Further analysis showed that during the reaction oxidation occurs at the NO ligand exclusively. 相似文献
116.
Dr. Chaohuang Chen Dr. Jun Li Dr. Constantin G. Daniliuc Dr. Christian Mück-Lichtenfeld Dr. Gerald Kehr Prof. Dr. Gerhard Erker 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(48):21644-21648
Hydride abstraction from the heterocyclic carbene borane adducts (NHC)BH2C6F5 (NHC: IMes or IMe4) gave the B−H containing [(NHC)B(H)C6F5]+ borenium cations. They added carbon monoxide to give the respective [(NHC)B(H)(C6F5)CO]+ boron carbonyl cations. Carbon nucleophiles add to the boron carbonyl to give [B](H) acyls. Hydride reduced the [B]CO cation to hydroxymethylborane derivatives. 相似文献
117.
118.
Teresa Ksel Gran Schulz Gerald Drger Andreas Kirschning 《Angewandte Chemie (International ed. in English)》2020,59(30):12376-12380
This report discloses the photochemical homolytic cleavage of iodine azide after its formation following release from polymer‐bound bisazido iodate(I) anions. A series of radical reactions are reported including the 1,2‐functionlization of alkenes and the unprecedented chemoselective oxidation of secondary alcohols in the presence of primary alcohols. 相似文献
119.
At temperatures above the brittle-to-ductile transition (490 °C) in Te-doped GaAs three types of predominant defect configurations have been observed after uniaxial compression along a [001] direction: (i) twins and stacking faults (500 … 520 °C), (ii) slip zones of dislocations (≈ 550 °C) and (iii) dislocation cells (580 … 590 °C). In Part I quantitative details of the appearance of twins and stacking faults are given. Most frequently found were 30° partials in twins and stacking faults. 相似文献
120.
At temperatures above the brittle-to-ductile transition (490 °C) in Te-doped GaAs three types of predominant defect configurations have been observed after uniaxial compression along a [001] direction: (i) twins and stacking faults (500 … 520 °C), (ii) slip zones of dislocations (≈550 °C) and (iii) dislocation cells (580 … 590 °C). In Part II quantitative details of the appearance of slip and cell formation are given. Leading segments of gliding half loops are mainly of 60° type. Cell walls were formed by multiple slip of perfect dislocations. 相似文献