Camphane-based aminophosphine ligands for Pd-catalyzed asymmetric allylic alkylation

A practical synthesis of new chiral aminophosphine ligands based on the camphane scaffold bearing alkoxy groups was accomplished. The application of these ligands in the Pd-catalyzed allylic alkylation of (E)-1,3-diphenyl-2-propenyl acetate proceeded with excellent conversions and ee’s of up to 91%. Variation of the alkoxy substituents did not substantially influence the catalytic performance.     

Electrostatic interaction between two conducting spheres

In the paper we consider the problem of the electrostatic interaction between two charged conducting spheres with arbitrary electrical charges and radiuses. Using the image charges method we determine exact analytical formulas for the force F and for the potential energy W of the interaction between these two spheres as well as for the potential V of the electromagnetic field in an arbitrary point created by them. Our formulas lead to Coulomb’s law for point charges.We theoretically prove the experimentally shown fact that two spheres with the same type (positive or negative) of charges can also attract each other.     

Weak Exponential Stability for Time-Periodic Differential Inclusions via First Approximation Averaging

In this work we propose a method to study a weak exponential stability for time-varying differential inclusions applying an averaging procedure to a first approximation. Namely, we show that a weak exponential stability of the averaged first approximation to the differential inclusion implies the weak exponential stability of the original time-varying inclusion. The result is illustrated by an example.     

Timelike surfaces with zero mean curvature in Minkowski 4-space

On any timelike surface with zero mean curvature in the four-dimensional Minkowski space we introduce special geometric (canonical) parameters and prove that the Gauss curvature and the normal curvature of the surface satisfy a system of two natural partial differential equations. Conversely, any two solutions to this system determine a unique (up to a motion) timelike surface with zero mean curvature so that the given parameters are canonical. We find all timelike surfaces with zero mean curvature in the class of rotational surfaces of Moore type. These examples give rise to a one-parameter family of solutions to the system of natural partial differential equations describing timelike surfaces with zero mean curvature.     

The Poincaré Map of Randomly Perturbed Periodic Motion

A system of autonomous differential equations with a stable limit cycle and perturbed by small white noise is analyzed in this work. In the vicinity of the limit cycle of the unperturbed deterministic system, we define, construct, and analyze the Poincaré map of the randomly perturbed periodic motion. We show that the time of the first exit from a small neighborhood of the fixed point of the map, which corresponds to the unperturbed periodic orbit, is well approximated by the geometric distribution. The parameter of the geometric distribution tends to zero together with the noise intensity. Therefore, our result can be interpreted as an estimate of the stability of periodic motion to random perturbations. In addition, we show that the geometric distribution of the first exit times translates into statistical properties of solutions of important differential equation models in applications. To this end, we demonstrate three distinct examples from mathematical neuroscience featuring complex oscillatory patterns characterized by the geometric distribution. We show that in each of these models the statistical properties of emerging oscillations are fully explained by the general properties of randomly perturbed periodic motions identified in this paper.     

Comparison theorems forL-monosplines of minimal norm

Summary LetLM _N be the set of allL-monosplines withN free knots, prescribed by a pair (x;E) of pointsx = {x _i } ₁ ⁿ ,a <x ₁ < ... <x _n <b and an incidence matrixE = (e _ij ) _i=1 ⁿ , _r-1 ^j=0 with Denote byLM _N ^O the subset ofLM _N consisting of theL-monosplines withN simple knots (n=N). We prove that theL-monosplines of minimalL _p-norms inLM _N belong toLM _N ^O .The results are reformulated as comparison theorems for quadrature formulae.     

Kähler manifolds of quasi-constant holomorphic sectional curvatures

The Kähler manifolds of quasi-constant holomorphic sectional curvatures are introduced as Kähler manifolds with complex distribution of codimension two, whose holomorphic sectional curvature only depends on the corresponding point and the geometric angle, associated with the section. A curvature identity characterizing such manifolds is found. The biconformal group of transformations whose elements transform Kähler metrics into Kähler ones is introduced and biconformal tensor invariants are obtained. This makes it possible to classify the manifolds under consideration locally. The class of locally biconformal flat Kähler metrics is shown to be exactly the class of Kähler metrics whose potential function is only a function of the distance from the origin in ? ⁿ . Finally we show that any rotational even dimensional hypersurface carries locally a natural Kähler structure which is of quasi-constant holomorphic sectional curvatures.     

Assemblies from metallic and semiconducting nanocrystals

Optical properties of nanomaterials such as semiconductor and metal quantum dots are important for sensors and photovoltaic applications. We report on optical, microscopic, and AFM investigations on bulk and single nanoobjects such as metal and semiconducting nanoparticles. Firstly, of special interest is the investigation of Ag metal nanoaggregates formed in zeolites. Here, the defined structure of the zeolite serves both as size directing and a stabilizing agent. The size selected Ag aggregates fluoresce in the zeolite cages even after storage under ambient conditions for almost one year. In addition, single Ag particles escape the cages and can be investigated by fluorescence microscopy also with respect to sensor applications. Secondly, with respect to photovoltaic applications, energy transfer among organic dye molecules and semiconductor quantum dots is of great importance. We report on the extension of the optical absorption of ZnSe quantum dots into the UV regime and investigate excitation energy transfer within self-assembled nanoaggregates of surface functionalized QDs and fluorescent styrylpyridine dyes.