全文获取类型
收费全文 | 9251篇 |
免费 | 163篇 |
国内免费 | 46篇 |
专业分类
化学 | 5973篇 |
晶体学 | 84篇 |
力学 | 292篇 |
数学 | 1677篇 |
物理学 | 1434篇 |
出版年
2021年 | 97篇 |
2020年 | 94篇 |
2019年 | 79篇 |
2018年 | 70篇 |
2017年 | 63篇 |
2016年 | 143篇 |
2015年 | 134篇 |
2014年 | 154篇 |
2013年 | 519篇 |
2012年 | 371篇 |
2011年 | 478篇 |
2010年 | 265篇 |
2009年 | 239篇 |
2008年 | 480篇 |
2007年 | 445篇 |
2006年 | 441篇 |
2005年 | 433篇 |
2004年 | 341篇 |
2003年 | 326篇 |
2002年 | 354篇 |
2001年 | 148篇 |
2000年 | 134篇 |
1999年 | 102篇 |
1998年 | 95篇 |
1997年 | 118篇 |
1996年 | 147篇 |
1995年 | 87篇 |
1994年 | 106篇 |
1993年 | 109篇 |
1992年 | 111篇 |
1991年 | 105篇 |
1990年 | 101篇 |
1989年 | 83篇 |
1988年 | 94篇 |
1987年 | 95篇 |
1986年 | 72篇 |
1985年 | 153篇 |
1984年 | 147篇 |
1983年 | 121篇 |
1982年 | 136篇 |
1981年 | 152篇 |
1980年 | 149篇 |
1979年 | 125篇 |
1978年 | 132篇 |
1977年 | 127篇 |
1976年 | 117篇 |
1975年 | 104篇 |
1974年 | 106篇 |
1973年 | 105篇 |
1972年 | 65篇 |
排序方式: 共有9460条查询结果,搜索用时 15 毫秒
991.
Lindenberg AM Engemann S Gaffney KJ Sokolowski-Tinten K Larsson J Hillyard PB Reis DA Fritz DM Arthur J Akre RA George MJ Deb A Bucksbaum PH Hajdu J Meyer DA Nicoul M Blome C Tschentscher T Cavalieri AL Falcone RW Lee SH Pahl R Rudati J Fuoss PH Nelson AJ Krejcik P Siddons DP Lorazo P Hastings JB 《Physical review letters》2008,100(13):135502
Femtosecond time-resolved small and wide angle x-ray diffuse scattering techniques are applied to investigate the ultrafast nucleation processes that occur during the ablation process in semiconducting materials. Following intense optical excitation, a transient liquid state of high compressibility characterized by large-amplitude density fluctuations is observed and the buildup of these fluctuations is measured in real time. Small-angle scattering measurements reveal snapshots of the spontaneous nucleation of nanoscale voids within a metastable liquid and support theoretical predictions of the ablation process. 相似文献
992.
High‐performance liquid chromatography separation of unsaturated organic compounds by a monolithic silica column embedded with silver nanoparticles 下载免费PDF全文
Yang Zhu Kei Morisato George Hasegawa Nirmalya Moitra Tsutomu Kiyomura Hiroki Kurata Kazuyoshi Kanamori Kazuki Nakanishi 《Journal of separation science》2015,38(16):2841-2847
The optimization of a porous structure to ensure good separation performances is always a significant issue in high‐performance liquid chromatography column design. Recently we reported the homogeneous embedment of Ag nanoparticles in periodic mesoporous silica monolith and the application of such Ag nanoparticles embedded silica monolith for the high‐performance liquid chromatography separation of polyaromatic hydrocarbons. However, the separation performance remains to be improved and the retention mechanism as compared with the Ag ion high‐performance liquid chromatography technique still needs to be clarified. In this research, Ag nanoparticles were introduced into a macro/mesoporous silica monolith with optimized pore parameters for high‐performance liquid chromatography separations. Baseline separation of benzene, naphthalene, anthracene, and pyrene was achieved with the theoretical plate number for analyte naphthalene as 36 000 m?1. Its separation function was further extended to cis/trans isomers of aromatic compounds where cis/trans stilbenes were chosen as a benchmark. Good separation of cis/trans‐stilbene with separation factor as 7 and theoretical plate number as 76 000 m?1 for cis‐stilbene was obtained. The trans isomer, however, is retained more strongly, which contradicts the long‐ established retention rule of Ag ion chromatography. Such behavior of Ag nanoparticles embedded in a silica column can be attributed to the differences in the molecular geometric configuration of cis/trans stilbenes. 相似文献
993.
We analyze a supply chain with a Resale Price Maintenance (RPM) contract in which the manufacturer sets the retail price with a general multiplicative price–demand function and prove the existence/uniqueness of an equilibrium. We also compare the equilibrium prices and quantities, consumer surplus and total system welfare for the RPM and wholesale price contracts. We conclude that a manufacturer may capture a smaller share of the total supply chain profit despite her ability to set the retail price. 相似文献
994.
Factors that determine the chirality of supramolecular helical tapes formed by a backbone-modified amylin(20-29) depsipeptide and inverso-depsipeptide, were studied by Fourier transform infrared spectroscopy, circular dichroism and transmission electron microscopy. Although β-sheet propensity was absent in both peptides, it was found that the l-depsipeptide formed left-handed and the enantiomeric d-depsipeptide right-handed helical tapes. Moreover, the backbone-modified depsipeptides, showed a certain degree of cross-recognition between both enantiomers, which might have implications in designing amyloid formation inhibitors. 相似文献
995.
996.
George E. Andrews 《Advances in Mathematics》2005,191(2):393-407
In the Lost Notebook, Ramanujan presents a truly enigmatic infinite product expansion for the two variable Rogers-Ramanujan series. In this paper, we prove this formula by a careful analysis of the Stieltjes-Wigert polynomials. 相似文献
997.
J. R. Pai A. M. George V. K. Rohatgi 《Applied Physics A: Materials Science & Processing》1980,22(3):283-285
The work function was measured in a vacuum of 10−5 Torr for magnesia incorporated lanthanum chromite based ceramic designated LC2OM. The results obtained are φ
R
=2.75eV andA
R
=0.11 A/cm2 K2 which ensure that LC2OM has favourable electron emission characteristics for MHD hot electrode material. The measurements
have been carried out in the temperature range from ambient to 1700 K.
Chemistry Division 相似文献
998.
Evangelos I. Tolis Dikaia E. Saraga George Z. Ammari Evangelos I. Gkanas Theofilos Gougoulas Christina C. Papaioannou Anastasios K. Sarioglou Eleftherios Kougioumtzidis Athina Skemperi John G. Bartzis 《Central European Journal of Chemistry》2014,12(6):643-651
Eordaia basin located in northwest of Greece, comprises an area which is characterized by intense energy related activities, including coal burning at four power plants and the associated mining operations. Air samples of inhalable (PM10) and respirable particles (PM2.5) were collected in cold and warm periods in 2010 at an urban background site of Kozani, the major city and capital of the region which is located close to the power plants. Particulate matter concentration, particle-bound polycyclic aromatic hydrocarbons and anionic species concentrations were determined using gravimetric, GC-MS in SIM mode and Ion Chromatography analysis, respectively. For the cold period, the mean PM10 and PM2.5 mass concentration was found to be 19.62 and 14.68 µg m?3, respectively. Correspondingly, for the warm period, the mean PM10 and PM2.5 values were 35.29 and 25.75 µg m?3, respectively. In general, the results indicated that the major sources of air pollution in Kozani are traffic, combustion from agricultural activities and lignite power plants emissions, contributing by different percentages to each particle fraction. 相似文献
999.
Oprea Simona-Vasilica Bâra Adela Ifrim George Adrian 《Journal of Optimization Theory and Applications》2021,190(1):151-182
Journal of Optimization Theory and Applications - Recent advancements in the sensor industry, smart metering systems and communication technology have led to interesting electricity consumption... 相似文献
1000.
Parworth CL Tucker MK Holmes BE Heard GL 《The journal of physical chemistry. A》2011,115(45):13133-13138
The 1,2-HX elimination reaction (where X = F, Cl, Br, OH) has been established as an important reaction in the degradation of compounds introduced into the upper atmosphere, including common CFC replacement compounds. By analyzing the electron densities of the transition state geometries of these reactions using QTAIM, we see that we can divide these reactions into two types. For HF and HOH elimination, the transition state is a complete ring of bonds, and neither the C-H nor the C-X bonds have been broken at the maximum of energy. There is very little accumulation of electron density on the X atom, with the majority of charge being lost by the hydrogen atom undergoing elimination, being transferred on to the two carbon atoms. In HCl and HBr elimination, a similar loss of electron density of the hydrogen atom is accompanied by significant accumulation of electron density on the X atom and a smaller change in electron density on the carbon atoms. The C-X bond is broken in the transition state geometry, with no ring critical point being present. This may explain the relative stabilities of halohydrocarbons and haloalcohols with respect to loss of H-X. 相似文献