全文获取类型
收费全文 | 7558篇 |
免费 | 1214篇 |
国内免费 | 956篇 |
专业分类
化学 | 5496篇 |
晶体学 | 45篇 |
力学 | 495篇 |
综合类 | 65篇 |
数学 | 844篇 |
物理学 | 2783篇 |
出版年
2024年 | 46篇 |
2023年 | 140篇 |
2022年 | 240篇 |
2021年 | 293篇 |
2020年 | 313篇 |
2019年 | 292篇 |
2018年 | 210篇 |
2017年 | 199篇 |
2016年 | 311篇 |
2015年 | 354篇 |
2014年 | 368篇 |
2013年 | 495篇 |
2012年 | 583篇 |
2011年 | 684篇 |
2010年 | 434篇 |
2009年 | 427篇 |
2008年 | 490篇 |
2007年 | 428篇 |
2006年 | 421篇 |
2005年 | 406篇 |
2004年 | 290篇 |
2003年 | 253篇 |
2002年 | 252篇 |
2001年 | 219篇 |
2000年 | 167篇 |
1999年 | 158篇 |
1998年 | 151篇 |
1997年 | 132篇 |
1996年 | 139篇 |
1995年 | 150篇 |
1994年 | 117篇 |
1993年 | 106篇 |
1992年 | 74篇 |
1991年 | 97篇 |
1990年 | 61篇 |
1989年 | 60篇 |
1988年 | 48篇 |
1987年 | 31篇 |
1986年 | 23篇 |
1985年 | 19篇 |
1984年 | 12篇 |
1983年 | 11篇 |
1982年 | 13篇 |
1981年 | 5篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1976年 | 1篇 |
1966年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有9728条查询结果,搜索用时 15 毫秒
61.
AbstractIn this paper, we introduce white noise, telegraph noise and time delay to the two-dimensional foraging arena population system describing the prey and predator abundance. The aim is to find out how the interactions between white noise, telegraph noise and time delay affect the dynamics of the population system. Firstly, the existence of a global positive solution is verified. Then the long-time properties including the stochastically ultimate boundedness, extinction and some other asymptotic pathwise estimation of this population system are studied. Finally, the main results are illustrated by two examples. 相似文献
62.
X. Y. Lai Q. Y. Cai M. S. Zhan 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2009,53(3):393-396
Many nonlinear quantum phenomena of intense laser-atom
physics can be intuitively explained with the concept of trajectory.
In this paper, Bohmian mechanics (BM) is introduced to study a
multiphoton process of atoms interacting with the intense laser
field: above-threshold ionization (ATI). Quantum trajectory of an
atomic electron in intense laser field is obtained from the
Bohm-Newton equation first and then the energy of the photoelectron
is gained from its trajectory. With energies of an ensemble of
photoelectrons, we obtain the ATI spectrum which is consistent with
the previous theoretical and experimental results. Comparing BM with
the classical trajectory Monte-Carlo method, we conclude that
quantum potential may play a key role to reproduce the spectrum of
ATI. Our work may present a new approach to understanding quantum
phenomena in intense laser-atom physics with the image of
trajectory. 相似文献
63.
64.
In this paper, we synthesized rutile TiO2 nanorods by hydrolysis of TiCl4 ethanolic solution in water at 50?°C. Scanning electron microscopy and transmission electron microscopy images show that the as-prepared sample was consisted of nanoflowers of about 500?nm in sizes, and each petal of nanoflowers was assembled by several nanorods. We tested the electrochemical properties of the rutile TiO2 nanorods as an anode material for lithium-ion batteries. The rutile TiO2 nanorods exhibited a large initial discharge capacity of 223?mA?h?g?1, and the stabilized capacity was as high as 170?mA?h?g?1 after 100 cycles. These improved electrochemical performances may be attributed to the shorter diffusion length for both the electron and Li+, and the large electrode?Celectrolyte contact area offered by the nanorods with a large specific surface area, which facilitated the lithium ions insertion and extraction. 相似文献
65.
Propagation properties of a decentered general astigmatic partially coherent beam (i.e., decentered twisted anisotropic Gaussian Schell-model beam) in a turbulent atmosphere are investigated. Analytical formulas for the cross-spectral density and decentered parameter of a decentered astigmatic partially coherent beam propagating in a turbulent atmosphere are derived. Irradiance properties of a decentered astigmatic partially coherent beam in a turbulent atmosphere are studied graphically, and are found to be quite different from its properties in free space. 相似文献
66.
In this Letter, exponential synchronization of a complex network with nonidentical time-delayed dynamical nodes is considered. Two effective control schemes are proposed to drive the network to synchronize globally exponentially onto any smooth goal dynamics. By applying open-loop control to all nodes and adding some intermittent controllers to partial nodes, some simple criteria for exponential synchronization of such network are established. Meanwhile, a pinning scheme deciding which nodes need to be pinned and a simply approximate formula for estimating the least number of pinned nodes are also provided. By introducing impulsive effects to the open-loop controlled network, another synchronization scheme is developed for the network with nonidentical time-delayed dynamical nodes, and an estimate of the upper bound of impulsive intervals ensuring global exponential stability of the synchronization process is also given. Numerical simulations are presented finally to demonstrate the effectiveness of the theoretical results. 相似文献
67.
Superhydrophobic surfaces fabricated by microstructuring of stainless steel using a femtosecond laser 总被引:1,自引:0,他引:1
Fabrication of superhydrophobic surfaces induced by femtosecond laser is a research hotspot of superhydrophobic surface studies nowadays. We present a simple and easily-controlled method for fabricating stainless steel-based superhydrophobic surfaces. The method consists of microstructuring stainless steel surfaces by irradiating samples with femtosecond laser pulses and silanizing the surfaces. By low laser fluence, we fabricated typical laser-induced periodic surface structures (LIPSS) on the submicron level. The apparent contact angle (CA) on the surface is 150.3°. With laser fluence increasing, we fabricated periodic ripples and periodic cone-shaped spikes on the micron scale, both covered with LIPSS. The stainless steel-based surfaces with micro- and submicron double-scale structure have higher apparent CAs. On the surface of double-scale structure, the maximal apparent CA is 166.3° and at the same time, the sliding angle (SA) is 4.2°. 相似文献
68.
A new method of online concentration capillary electrochromatography using a lauryl methacrylate-based monolithic column was developed for determination of three β(2)-agonists including salbutamol, procaterol, and formoterol. The separation parameters including acetonitrile concentration, running buffer pH, and concentration were evaluated. To improve the sensitivity, an online concentration method with combination of the chromatographic zone-sharpening effect and field-enhanced sample-stacking effect has been developed in which the concentration parameters including injection voltage, injection time, as well as sample matrix were systematically studied. Under the optimized conditions, baseline separation of three β(2)-agonists was achieved within 4 min. When compared to the conventional sample injection, this online concentration technique increased their corresponding sensitivities up to 45-, 36-, and 320-fold, respectively. Furthermore, good repeatability was obtained with relative standard deviations (RSDs) for migration times within 0.84% and those for peak areas less than 6.35% (n = 5) in the experiment. The proposed method was successfully applied to the determination of above-mentioned β(2)-agonists in urine sample. The recoveries of spiked urine samples were between 82.4% and 109.1% with RSDs less than 9.97%. 相似文献
69.
A unified picture is presented of water interacting with pyridine, pyridazine, pyrimidine, and pyrazine on the S(1) manifold in both gas-phase dimers and in aqueous solution. As (n,π*) excitation to the S(1) state removes electrons from the ground-state hydrogen bond, this analysis provides fundamental understanding of excited-state hydrogen bonding. Traditional interpretations view the excitation as simply breaking hydrogen bonds to form dissociated molecular products, but reactive processes such as photohydrolysis and excited-state proton coupled electron transfer (PCET) are also possible. Here we review studies performed using equations-of-motion coupled-cluster theory (EOM-CCSD), multireference perturbation theory (CASPT2), time-dependent density-functional theory (TD-DFT), and excited-state Monte Carlo liquid simulations, adding new results from symmetry-adapted-cluster configuration interaction (SAC-CI) and TD-DFT calculations. Invariably, gas-phase molecular dimers are identified as stable local minima on the S(1) surface with energies less than those for dissociated molecular products. Lower-energy biradical PCET minima are also identified that could lead to ground-state recombination and hence molecular dissociation, dissociation into radicals or ions, or hydration reactions leading to ring cleavage. For pyridine.water, the calculated barriers to PCET are low, suggesting that this mechanism is responsible for fluorescence quenching of pyridine.water at low energies rather than accepted higher-energy Dewar-benzene based "channel three" process. Owing to (n,π*) excitation localization, much higher reaction barriers are predicted for the diazines, facilitating fluorescence in aqueous solution and predicting that the as yet unobserved fluorescence from pyridazine.water and pyrimidine.water should be observable. Liquid simulations based on the assumption that the solvent equilibrates on the fluorescence timescale quantitatively reproduce the observed spectral properties, with the degree of (n,π*) delocalization providing a critical controlling factor. 相似文献
70.
A facile method for the activation of hydroxy-substituted carboxylic acids using benzotriazole chemistry without prior protection of the hydroxy substituents is presented. The N-acylbenzotriazole intermediates 2a-g, 6a-d, and 9a-c have been used for high-yielding synthesis of both aliphatic (3a-l) and aromatic (7a-h, 10a-f) hydroxy carboxamides. High yields of aromatic hydroxy esters 12a-h and 13a-i were obtained using either neat alcohols in neutral microwave conditions or nucleophilic alkoxides and the intermediate N-(arylacyl)benzotriazoles. Moderate yields were obtained in the case of aliphatic hydroxy esters 11a,b and thiolesters 11e-g from the intermediates 2a-c. 相似文献