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Tobias Str?mgren Geert Brethouwer Gustav Amberg Arne V. Johansson 《Flow, Turbulence and Combustion》2011,86(3-4):477-495
An Eulerian turbulent two phase flow model using kinetic theory of granular flows for the particle phase was developed in order to study evolving upward turbulent gas particle flows in a pipe. The model takes the feedback of the particles into account and its results agree well with experiments. Simulations show that the pipe length required for particle laden turbulent flow to become fully developed is up to five times longer than an unladen flow. To increase the understanding of the dependence of the development length on particle diameter a simple model for the expected development length was derived. It shows that the development length becomes shorter for increasing particle diameters, which agrees with simulations up to a particle diameter of 100 ??m. Thereafter the development length becomes longer again for increasing particle diameters because larger particles need a longer time to adjust to the velocity of the carrier phase. 相似文献
223.
Geert Janssens Dirk Courtheyn Sven Mangelinckx Stéphanie Prévost Emmanuelle Bichon Fabrice Monteau Geert De Poorter Norbert De Kimpe Bruno Le Bizec 《Analytica chimica acta》2013
Although substantial technical advances have been achieved during the past decades to extend and facilitate the analysis of growth promoters in cattle, the detection of abuse of synthetic analogs of naturally occurring hormones has remained a challenging issue. When it became clear that the exogenous origin of steroid hormones could be traced based on the 13C/12C isotope ratio of the substances, GC/C/IRMS has been successfully implemented to this aim since the end of the past century. However, due to the costly character of the instrumental setup, the susceptibility of the equipment to errors and the complex and time consuming sample preparation, this method is up until now only applied by a limited number of laboratories. In this review, the general principles as well as the practical application of GC/C/IRMS to differentiate between endogenous steroids and exogenously synthesized homologous compounds in cattle will be discussed in detail, and will be placed next to other existing and to be developed methods based on isotope ratio mass spectrometry. Finally, the link will be made with the field of sports doping, where GC/C/IRMS has been established within the World Anti-Doping Agency (WADA) approved methods as the official technique to differentiate between exogenous and endogenous steroids over the past few years. 相似文献
224.
Dr. Qiuhua Liang Prof. Dr. Geert Brocks Dr. Anja Bieberle-Hütter 《Chemphyschem》2023,24(5):e202200429
Magnetic exchange force microscopy (MExFM) is an important experimental technique for mapping the magnetic structure of surfaces with atomic resolution relying on the spin-dependent short-range exchange interaction between a magnetic tip and a magnetic surface. RuO2 is a significant compound with applications in heterogeneous catalysis and electrocatalysis. It has been characterized recently as an antiferromagnetic (AFM) material, and its magnetism has been predicted somewhat surprisingly to play an important role in its catalytic properties. In the current study, we explore theoretically whether MExFM can visualize the magnetic surface structure of RuO2. We use density functional theory (DFT) calculations to extract the exchange interactions between a ferromagnetic Fe tip interacting with an AFM RuO2(110) surface, as a function of tip-surface distance and the position of the tip over the surface. Mimicking the MExFM experiment, these data are then used to calculate the normalized frequency shift of an oscillating cantilever tip versus the minimum tip-surface distance, and construct corrugation height line profiles. It is found that the exchange interaction between tip and surface is strongest for a parallel configuration of the spins of the tip and of the surface; it is weakest for an anti-parallel orientation. In a corrugation profile, this gives rise to a sizable height difference of 25 pm between the spin-up and spin-down Ru atoms in the RuO2(110) surface at a normalized frequency shift =−10.12 fNm1/2. The O atoms in the surface are not or hardly visible in the corrugation profile. 相似文献
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