Effects of reactor type and mass transfer on the morphology of CuS and ZnS crystals

For the precipitation of CuS and ZnS, the effects of the reactor/precipitator type, mass transfer and process conditions on crystal morphology were studied. Either H₂S gas or a S^2– solution were applied. Three different types of reactors have been tested, namely a laminar jet, a bubble column and an MSMPR reactor. The choice of reactor type as well as mass transfer and metal concentration all have a considerable influence on the morphology of the produced crystals. A well mixed bubble column with H₂S containing gas as feed yields the coarsest crystals. Use is then made of the surface active properties of CuS‐particles, which induce agglomeration at the gas‐liquid interface, where as the low metal concentrations inside the reactor also contribute to the formation of coarser particles (especially for ZnS). (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Numerical Modelling of Traffic Induced Vibrations

A solution procedure is presented to compute free field vibrations induced by train or road traffic, the excitation being either deterministic or stochastic. The full interaction between the vehicle, the track or road and the soil is accounted for, using a substructure approach that takes advantage of the fact that the properties of the track or road and the soil do not change along the longitudinal direction. A time-frequency approach is proposed to characterize the free field radiated in the soil. The examples show the importance of guided waves along the track for understanding the dynamic behavior of the track or the road.     

Direct Numerical Simulation of Turbulent Pipe Flow at Moderately High Reynolds Numbers

Fully resolved direct numerical simulations (DNSs) have been performed with a high-order spectral element method to study the flow of an incompressible viscous fluid in a smooth circular pipe of radius R and axial length 25R in the turbulent flow regime at four different friction Reynolds numbers Re _τ ?=?180, 360, 550 and $1\text{,}000$ . The new set of data is put into perspective with other simulation data sets, obtained in pipe, channel and boundary layer geometry. In particular, differences between different pipe DNS are highlighted. It turns out that the pressure is the variable which differs the most between pipes, channels and boundary layers, leading to significantly different mean and pressure fluctuations, potentially linked to a stronger wake region. In the buffer layer, the variation with Reynolds number of the inner peak of axial velocity fluctuation intensity is similar between channel and boundary layer flows, but lower for the pipe, while the inner peak of the pressure fluctuations show negligible differences between pipe and channel flows but is clearly lower than that for the boundary layer, which is the same behaviour as for the fluctuating wall shear stress. Finally, turbulent kinetic energy budgets are almost indistinguishable between the canonical flows close to the wall (up to y ^?+??≈?100), while substantial differences are observed in production and dissipation in the outer layer. A clear Reynolds number dependency is documented for the three flow configurations.     

Ionotrope Gele von Polyuronsäuren

Ohne Zusammenfassung vgl. I. Bildung und Verhalten. Kolloid-Z.140, 76, ff (1955) Diese Arbeit wurde zum Teil mit Mitteln der Deutschen Forschungsgemeinschaft und des Fonds zur F?rderung der Chemie durchgeführt.     

Simultaneous in situ profiling of DNA lesion endpoints based on image cytometry and a single cell database approach

Analyzing the integrity of DNA is one of the most frequent used endpoints for risk assessment of chemical and physical agents. In the framework of a radiobiological space experiment, this work aimed at having (1) a histochemical tool for the in situ assessment of DNA damage in as long as 20 days old fixed cell cultures, (2) a comprehensive tool for the quantification of different types of DNA lesions, and (3) a methodology of sampling thousands of nuclei based on confocal microscopy, automated stage scanning and digital image processing. For this purpose several fixatives and permeabilization techniques were tested together with the combinatorial use of terminal dUTP transferase-mediated nick end-labeling (TUNEL) and the DNA polymerase I mediated in situ nick translation. These biochemical tools are useful for scoring DNA single and double breaks, and oxidative lesions. Ltk(-) cells were exposed either to hydrogen peroxide or heavy ion beam irradiation. Combination of paraformaldehyde fixation, sodium citrate permeabilization and heat gave the best staining results. A three-channel fluorescence methodology was established including a DNA counter stain for nucleus identification and normalization of DNA content. Communication between confocal imaging software, image analysis software and a relational database proved to be pivotal for a semi-automated high-end single cell analysis and storage of images. In this way, DNA damage data per nucleus can be traced back to the original image. As much as 2500 cells could be analyzed in situ within a day and correlations drawn between different DNA lesion endpoints.     

Ab initio rovibrational spectrum of LiNC and LiCN

Rovibrational calculations are performed on an ab initio potential energy surface for lithium cyanide. Vibrational states localized about both the isocyanide structure and the metastable cyanide structure are found. Calculated fundamental frequencies are LiNC 126.6 cm^?1 (bend) and 754.3 cm^?1 (stretch); LiCN 165.8 cm^?1 (bend) and 688.8 cm^?1 (stretch). Many states are found in the region of the barrier to isomerization, some of which are delocalized (polytopic).     

A Modelling Study of Evolving Particle-laden Turbulent Pipe-flow

An Eulerian turbulent two phase flow model using kinetic theory of granular flows for the particle phase was developed in order to study evolving upward turbulent gas particle flows in a pipe. The model takes the feedback of the particles into account and its results agree well with experiments. Simulations show that the pipe length required for particle laden turbulent flow to become fully developed is up to five times longer than an unladen flow. To increase the understanding of the dependence of the development length on particle diameter a simple model for the expected development length was derived. It shows that the development length becomes shorter for increasing particle diameters, which agrees with simulations up to a particle diameter of 100 ??m. Thereafter the development length becomes longer again for increasing particle diameters because larger particles need a longer time to adjust to the velocity of the carrier phase.