排序方式: 共有28条查询结果,搜索用时 15 毫秒
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An arsine-mediated Wittig reaction for the synthesis of olefins is described. After heating triphenylarsine in the presence of an activated alkyl bromide for 30 min, the resulting arsonium salt condensed with aldehydes in as little as 5 min at room temperature, yielding the olefins in high yields. Aromatic, heteroaromatic, and alkyl aldehydes were all suitable substrates for this process. 相似文献
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Robert D. Vaughan Elaine Geary Mila Pravda George G. Guilbault 《International journal of environmental analytical chemistry》2013,93(7-8):555-571
This article is a tutorial review of piezoelectric immunosensors and their application to environmental monitoring. The basic theory and historical developments of piezoelectricity are introduced. The development of piezoelectric sensors and eventually immunosensors for the specific detection of analytes of environmental importance are mentioned. The various assay formats and their advantages as well as examples of the different approaches taken by different analysers are also mentioned. Current developments within this laboratory on the development of piezoelectric immunosensors for the detection of okadaic acid and microcystin-LR are briefly introduced. The major drawbacks of piezoelectric immunosensors and their potential future are also discussed. 相似文献
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The adaptation of a standard minicomputer to the processing of infrared spectroscopic data is described. The computer is interfaced to one of three high-performance infrared spectrophotometers and is supported by a flexible software package designed for the spectroscopist. The development of these computerized dispersive spectroscopy systems is discussed in terms of hardware and software. An indication of performance is included by reference to specific analytical applications. 相似文献
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The visible, spectra of the highly sensitive colorimetric reagent 4-(2-pyridylazo)-resorcinol (I), and of the coloured cpmplexes formed with copper(II), nickel(II), cobalt(II), lead(II), and uranium(VI) were obtained in water and in aqueous dioxan. The structures of these complexes were determined by spectrophotometric methods, and chelation by (I) established as essentially terdentate. Comparison is made with the visible spectra of salicylidene-2-aminopyridine (II), 2-(o-hydroxy-phenyl-imino-methyl)-pyridine (III), and benzeneazoresorcinol (IV), and of the metal complexes of (II) (III) and (IV). The red coloration obtained with 4-(2-pyridylazo)-resorcinol is explained by the presence of a pseudo-phenanthroline system and an o-o'-disubstituted azo system, the active groups in chelation being the pyridine nitrogen atom, the azo nitrogen farthest from the heterocycle, and the o-hydroxyl group. 相似文献
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Geary EA Yellowlees LJ Jack LA Oswald ID Parsons S Hirata N Durrant JR Robertson N 《Inorganic chemistry》2005,44(2):242-250
A family of [Pt(II)(diimine)(dithiolate)] complexes of general formula [Pt{X,X'(CO(2)R)(2)-2,2'-bipyridyl}(maleonitriledithiolate)] (where X = 3, 4, or 5 and R = H or Et) have been synthesized, spectroscopically and electrochemically characterized, and attached to a TiO(2) substrate to be tested as solar cell sensitizers. A single-crystal X-ray structure showing a large torsion angle between the bipyridyl rings was determined for [Pt{3,3'(CO(2)Et)(2)-2,2'-bipyridyl}(maleonitriledithiolate)].MeCN. The effect of changing the position of the bipyridyl substituents from 3,3' to 4,4' and 5,5' is discussed with reference to structural and electronic changes seen within the different members of the family of molecules. The first UV/vis/NIR spectroelectrochemical study of complexes of this general formula is discussed. All three complexes (where R = H) were tested as solar cell sensitizers, with the 3,3'-disubstituted bipyridyl complex giving an intermediate dye loading value but superior photovoltaic performance to those of the other two. The performance of this sensitizer is then compared with that of a well-known Ru polypyridyl sensitizer, the ditetrabutylammonium salt of [RuL(2)(NCS)(2)] (L = 2,2'-bipyridyl-4,4'-dicarboxylato), commonly called N719. 相似文献
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Willem de Haan Yolande AL Pijnenburg Rob LM Strijers Yolande van der Made Wiesje M van der Flier Philip Scheltens Cornelis J Stam 《BMC neuroscience》2009,10(1):101-12