Delicate crystal structure changes govern the magnetic properties of 1D coordination polymers based on 3d metal carboxylates

Homo- and heterometallic 1D coordination polymers of transition metals (Co II, Mn II, Zn II) have been synthesized by an in-situ ligand generation route. Carboxylato-based complexes [Co(PhCOO)2]n (1 a, 1 b), [Co(p-MePhCOO)2]n (2), [ZnMn(PhCOO)4]n (3), and [CoZn(PhCOO)4]n (4) (PhCOOH=benzoic acid, p-MePhCOOH=p-methylbenzoic acid) have been characterized by chemical analysis, single-crystal X-ray diffraction, and magnetization measurements. The new complexes 2 and 3 crystallize in orthorhombic space groups Pnab and Pcab respectively. Their crystal structures consist of zigzag chains, with alternating M(II) centers in octahedral and tetrahedral positions, which are similar to those of 1 a and 1 b. Compound 4 crystallizes in monoclinic space group P2 1/c and comprises zigzag chains of M II ions in a tetrahedral coordination environment. Magnetic investigations reveal the existence of antiferromagnetic interactions between magnetic centers in the heterometallic complexes 3 and 4, while ferromagnetic interactions operate in homometallic compounds (1 a, 1 b, and 2). Compound 1 b orders ferromagnetically at TC=3.7 K whereas 1 a does not show any magnetic ordering down to 330 mK and displays typical single-chain magnet (SCM) behavior with slowing down of magnetization relaxation below 0.6 K. Single-crystal measurements reveal that the system is easily magnetized in the chain direction for 1 a whereas the chain direction coincides with the hard magnetic axis in 1 b. Despite important similarities, small differences in the molecular and crystal structures of these two compounds lead to this dramatic change in properties.     

The evolution of the chaotic dynamics of collective modes as a method for the behavioral description of living systems

Human-scaled (in complexity) systems possess a unique feature, viz., the continuous random motion of many components of the state vector x = x(t) of such living systems. Taking this property into consideration causes the rejection of any of the known types of stationary modes (e.g., dx/dt = 0) and requires revision of the concept of chaos. A new approach to the understanding of living systems (as a third paradigm of the natural sciences) and new methods for the study of living systems (as a theory of chaos and self-organization) are proposed. Common grounds of physics and theory of chaos and self-organization are revealed as a generalized uncertainty principle and a limit on the parameters of quasi-attractors.     

Dynamics of the cascade capture of electrons by charged donors in GaAs and InP

The times for the cascade capture of an electron by a charged impurity have been calculated for pulsed and stationary excitations of impurity photoconductivity in GaAs and InP. The characteristic capture times under pulsed and continuous excitations are shown to differ noticeably both from each other and from the value given by the Abakumov–Perel–Yassievich formula for a charged impurity concentration greater than 10¹⁰ cm^–3. The cause of this difference has been established. The Abakumov–Perel–Yassievich formula for the cascade capture cross section in the case of stationary excitation has been generalized. The dependences of the cascade capture rate on the charged impurity concentration in GaAs and InP have been found for three temperatures in the case of pulsed excitation.     

Some peculiarities of wave multiple scattering in a statistically anisotropic medium

This paper investigates the evolution of the angular distribution of the intensity of an electromagnetic wave incident on a thick layer of a random statistically anisotropic medium. The anisotropy of the medium is caused by the presence of prolate random inhomogeneities of the refractive index oriented along the normal to the medium boundary. Oblique and normal illumination of the layer are considered. A characteristic gap in the angular distribution is detected and investigations are made using Monte Carlo simulations.     

Study of sensitization of Cr4+ ions by Yb3+ ions in yttrium-aluminum garnet crystals

The possibility of using ytterbium ions as sensitizers of luminescence of tetravalent chromium in yttrium-aluminum garnet single crystals is studied. It is found that average values of the microparameters of electronic energy transfer between ytterbium and chromium ions are C _DA=7.05×10^?36 cm⁶/s and C _DD=4.55×10^?43 cm⁶/s.     

Magnetospectroscopy of double HgTe/CdHgTe QWs with inverted band structure in high magnetic fields up to 30 T

Magnetoabsorption in far and mid IR ranges in double HgTe/CdHgTe quantum wells with inverted band structure has been studied in high magnetic fields up to 30 T. Numerous intraband and interband transitions have been revealed in the spectra and interpreted within axial 8 × 8 k·p model. Splitting of dominant magnetoabsorption lines resulting from optical transitions from hole-like zero-mode Landau level has been discovered and discussed in terms of a built-in electric field and collective phenomena.     

Terahertz Spectroscopy of Two-Dimensional Semimetal in Three-Layer InAs/GaSb/InAs Quantum Well

JETP Letters - The features of terahertz photoluminescence and magnetoabsorption in magnetic fields up to 16 T in threelayer InAs/GaSb/InAs quantum wells with a band structure corresponding to a...     

Features of Photoluminescence of Double Acceptors in HgTe/CdHgTe Heterostructures with Quantum Wells in a Terahertz Range

JETP Letters - The terahertz photoluminescence spectra of HgTe/CdHgTe heterostructure with quantum wells under interband optical excitation with a power of 3 to 300 mW have been studied in the...     

Ab initio study of optical properties of rhodamine 6G molecular dimers

Equilibrium atomic geometries of rhodamine 6G (R6G) dye molecule dimers are studied using density-functional theory. Electron-energy structure and optical properties of R6G H and J dimers are calculated using the generalized gradient approximation method with ab initio pseudopotentials. Our theory predicts substantial redshifts or blueshifts of the optical absorption spectra of R6G dye molecules after aggregation in J or H dimers, respectively. Predicted optical properties of R6G dimers are interpreted in terms of interatomic and intermolecular interactions. Results of the calculations are discussed in comparison with experimental data.     

Exchange interaction effects in electron spin resonance: Larmor theorem violation in narrow-gap quantum well heterostructures

We report a theoretical study of the exchange interaction effects in the electron spin resonance (ESR) in n-type narrow-gap quantum well (QW) heterostructures. Using the Hartree-Fock approximation, based on the eight-band k?p Hamiltonian, the many-body correction to the ESR energy is found to be nonzero, providing theoretical evidence of Larmor theorem violation in symmetric narrow-gap QWs. We predict the exchange enhancement of the ESR g-factor and its divergence in low magnetic fields. The 'enhanced' ESR g-factor and quasiparticle g-factor, measured in magnetotransport, coincide at even-valued filling factors of the Landau levels in moderate and quantizing magnetic fields.