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481.
Gediminas Galinis Gauthier Torricelli Atea Akraiam Klaus von Haeften 《Journal of nanoparticle research》2012,14(8):1-6
Experimental studies have been performed on unisize tungsten clusters constructed on a graphite surface by means of the scanning tunneling microscopy. It was found that the geometry of the clusters changes instantaneously from a monatomic-layer tungsten disk to a diatomic-layer structure between the cluster size of 10 and 11. We concluded that this transition is driven by a change in the dominant interaction from the attractive electrostatic interaction between the cluster and the surface to intracluster cohesive metallic interaction. 相似文献
482.
Lucie Blondeau Suzy Surble Eddy Foy Hicham Khodja Magali Gauthier 《Journal of Energy Chemistry》2021,(4):124-128
A composite In-Pb:carbon was successfully synthetized by a two-step mechanochemical synthesis in order to obtain an adequate particles size and structure to investigate the electrochemical reactivity of the In-Pb solid solution towards Mg.A potential synergetic coupling of electroactive elements In and Pb was examined using electrochemical and ex situ X-ray diffraction analyses.The potential profile of the solid solution indicates the formation of Mg2Pb and Mg In.However,the diffraction study suggests a peculiar electrochemically-driven amorphization of Mg In during the magnesiation,in strong contrast to Mg In crystallization in In-based and In Bi-based electrodes reported in the literature.Combining In and Pb favors the amorphization of Mg In and a high first magnesiation capacity of about 550 m Ah g-1,but is thereafter detrimental to the material’s reversibility.These results emphasize the possible influence of electrochemically-driven amorphization and crystallization processes on electrochemical performance of battery materials. 相似文献
483.
Xiaoxuan Yang Shreya Mukherjee Thomas O'Carroll Prof. Yang Hou Prof. Meenesh R. Singh Prof. Joseph A. Gauthier Prof. Gang Wu 《Angewandte Chemie (International ed. in English)》2023,62(10):e202215938
Unrestrained anthropogenic activities have severely disrupted the global natural nitrogen cycle, causing numerous energy and environmental issues. Electrocatalytic nitrogen transformation is a feasible and promising strategy for achieving a sustainable nitrogen economy. Synergistically combining multiple nitrogen reactions can realize efficient renewable energy storage and conversion, restore the global nitrogen balance, and remediate environmental crises. Here, we provide a unique aspect to discuss the intriguing nitrogen electrochemistry by linking three essential nitrogen-containing compounds (i.e., N2, NH3, and NO3−) and integrating four essential electrochemical reactions, i.e., the nitrogen reduction reaction (N2RR), nitrogen oxidation reaction (N2OR), nitrate reduction reaction (NO3RR), and ammonia oxidation reaction (NH3OR). This minireview also summarizes the acquired knowledge of rational catalyst design and underlying reaction mechanisms for these interlinked nitrogen reactions. We further underscore the associated clean energy technologies and a sustainable nitrogen-based economy. 相似文献
484.
A.M.C. Dawes D.J. Gauthier S. Schumacher N.H. Kwong R. Binder A.L. Smirl 《Laser \u0026amp; Photonics Reviews》2010,4(2):221-243
We review recent theoretical and experimental efforts toward developing an all‐optical switch based on transverse optical patterns. Transverse optical patterns are formed when counterpropagating laser beams interact with a nonlinear medium. A perturbation, in the form of a weak switch beam injected into the nonlinear medium, controls the orientation of the generated patterns. Each state of the pattern orientation is associated with a state of the switch. That is, information is stored in the orientation state. A realization of this switch using a warm rubidium vapor shows that it can be actuated by as few as 600 ± 40 photons with a response time of 5 µs. Models of nonlinear optical interactions in semiconductor quantum wells and microresonators suggest these systems are also suitable for use as fast all‐optical switches using this same conceptual design, albeit at higher switching powers. 相似文献