全文获取类型
收费全文 | 680篇 |
免费 | 27篇 |
专业分类
化学 | 505篇 |
晶体学 | 17篇 |
力学 | 11篇 |
数学 | 43篇 |
物理学 | 131篇 |
出版年
2024年 | 4篇 |
2023年 | 14篇 |
2022年 | 23篇 |
2021年 | 23篇 |
2020年 | 32篇 |
2019年 | 24篇 |
2018年 | 27篇 |
2017年 | 21篇 |
2016年 | 35篇 |
2015年 | 20篇 |
2014年 | 37篇 |
2013年 | 59篇 |
2012年 | 48篇 |
2011年 | 52篇 |
2010年 | 35篇 |
2009年 | 23篇 |
2008年 | 32篇 |
2007年 | 30篇 |
2006年 | 23篇 |
2005年 | 28篇 |
2004年 | 14篇 |
2003年 | 12篇 |
2002年 | 9篇 |
2001年 | 5篇 |
2000年 | 6篇 |
1999年 | 3篇 |
1997年 | 4篇 |
1996年 | 4篇 |
1994年 | 4篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1988年 | 2篇 |
1986年 | 5篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 1篇 |
1981年 | 9篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1973年 | 2篇 |
1972年 | 1篇 |
1971年 | 2篇 |
1967年 | 1篇 |
1963年 | 1篇 |
排序方式: 共有707条查询结果,搜索用时 62 毫秒
651.
Shyamprasad Karagadde Anirban Bhattacharya Gaurav Tomar Pradip Dutta 《Journal of computational physics》2012,231(10):3987-4000
A coupled methodology for simulating the simultaneous growth and motion of equiaxed dendrites in solidifying melts is presented. The model uses the volume-averaging principles and combines the features of the enthalpy method for modeling growth, immersed boundary method for handling the rigid solid–liquid interfaces, and the volume of fluid method for tracking the advection of the dendrite. The algorithm also performs explicit–implicit coupling between the techniques used. A two-dimensional framework with incompressible and Newtonian fluid is considered. Validation with available literature is performed and dendrite growth in the presence of rotational and buoyancy driven flow fields is studied. It is seen that the flow fields significantly alter the position and morphology of the dendrites. 相似文献
652.
653.
654.
A.K. Chauhan D.K. Aswal S.P. Koiry S.K. Gupta J.V. Yakhmi C. Sürgers D. Guerin S. Lenfant D. Vuillaume 《Applied Physics A: Materials Science & Processing》2008,90(3):581-589
We report the deposition of 3-aminopropyltrimethoxysilane (APTMS) multilayers on SiOx/Si(p++) substrates by a layer-by-layer self-assembly process. The multilayers were grafted in a glove box having nitrogen ambient
with both humidity and oxygen contents <1 ppm using APTMS solutions prepared in an anhydrous toluene. Deposition of the multilayers
has been carried out as a function of solution concentration and grafting time. Characterization of the multilayers using
static de-ionized water contact angle, ellipsometry, X-rayphotoelectron spectroscopy and atomic force microscope measurements
revealed that self-assembling of the multilayers takes place in two distinct stages: (i) the first APTMS monolayer chemisorbs
on a hydroxylated oxide surface by a silanization process and, (ii) the surface amino group of the first monolayer chemisorbs
the hydrolyzed silane group of other APTMS molecules present in the solution, leading to the formation of a bilayer. The second
stage is a self-replicating process that results in the layer-by-layer self-assembly of the multilayers with trapped NH3
+ ions. The current–voltage characteristics of the multilayers exhibit a hysteresis effect along with a negative differential
resistance, suggesting their potential application in the molecular memory devices. A possible mechanism for the observed
hysteresis effect based on filling and de-filling of the NH3
+ acting as traps is presented.
PACS 73.30.+y 相似文献
655.
Bis(N, N′‐dialkyldithiocarbamato)antimony(III) alkylenedithiophosphates of the type [R2NCS2]2 SbS(S)POGO [where NR2 = N(CH3)2, N(C2H5)2 and N(CH2)4; G = ? CH2? C(C2H5)2? CH2? , ? CH2? C(CH3)2? CH2? , ? CH(CH3)? CH(CH3)? and ? C(CH3)2? C(CH3)2? ] were synthesized and characterized by physico‐chemical, spectral [UV, IR and NMR (1H, 13C and 31P)] and thermal (TG, DTA and DSC) analysis. The TG decomposition analysis step of the complex indicated the formation of Sb2S3 as the final product. The first endothermic peak in DSC indicated the melting point of the complexes. These complexes were screened for their antimicrobial activities using the disk diffusion method. All the complexes showed good activity as antibacterial and antifungal agents on some selected bacterial and fungal strains, which increased on increasing the concentration. Chloroamphenicol and terbinafin were used as standards for comparison. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
656.
Activated polystyrene cuvet is used for the determination of oxalate in urine sample and immunoglobulin in human sera. Polystyrene cuvet was activated by introducing active functional group onto its surface by coating the surface with a heterobifunctional photolinker, 1-fluoro-2-nitro-4-azidobenzene and exposing to UV light at 365 nm. Modified cuvet was active enough to covalently link oxalate oxidase in just 45 min at 50 °C without any additional catalyst or reagent. Remarkable reduction of time was achieved when immobilization was carried out by microwave irradiation. It took only 50 s to immobilize oxalate oxidase in the activated cuvet when exposed to microwaves in a domestic microwave oven. Immobilized-oxalate oxidase was stable, reusable and conveniently used for determination of urinary oxalate for diagnosis of primary hyperoxaluria and calcium oxalate nephrolithaiasis. Detection of human IgG involving ELISA in antihuman IgG-immobilized cuvet showed the feasibility of the cuvet in other immunoassays. 相似文献
657.
A. K. Narula S. K. Goyal Savita Saini R. P. Chauhan S. K. Chakarvarti 《Indian Journal of Physics》2009,83(8):1171-1175
The diffusion of radon in dwellings is a process determined by the radon concentration gradient across the building material
structure between the radon source and the surrounding air, and can be a significant contributor to indoor radon inflow. Radon
can originate from the deeply buried deposit beneath homes and can migrate to the surface of earth. Radon emanates to the
surfaces mainly by diffusion processes from the point of origin following α-decay of 226Ra in underground soil and building materials used, in the construction of floors, walls, and ceilings. In the present study
radon diffusion through some building materials viz. coarse sand and stone dust of different grain size has been carried out using LR-115 type II solid-state nuclear track detectors
(SSNTDs). The radon diffusion coefficients and diffusion lengths through these building construction materials have been calculated.
The effect of grain size on radon diffusion through these building materials shows the decrease in radon diffusion with decrease
in grain size. 相似文献
658.
In this paper, we report on the pulsed laser deposition of epitaxial (0002) oriented Zn1−x
Mg
x
O thin films onto (0001) sapphire substrate in O2 ambient at different deposition temperatures. Pulsed laser deposited Zn1−x
Mg
x
O films showed (0002) oriented hexagonal wurtzite structure up to 34% of Mg concentration. The bandgap of Zn1−x
Mg
x
O thin films is successfully tuned from 3.3 to 4.2 eV by adjusting the Mg concentration x=0.0 to x=0.34. Pulsed laser deposited Zn1−x
Mg
x
O thin films were characterized by XRD, AFM, SEM, PL and UV–VIS spectrometer. We have also studied the effect of deposition
temperature on to the structure, surface morphology and optical properties of Zn1−x
Mg
x
O thin films. 相似文献
659.
Fatemeh Jahanzad Gini Chauhan Sherif Mustafa Basu Saha Shahriar Sajjadi Brian W. Brooks 《Macromolecular Symposia》2007,259(1):145-150
Summary: A new route was employed to produce composite polymer nanoparticles. First, a model polymer (a low molecular-weight polyisobutene) was dissolved in a model monomer (styrene) and then the solution was emulsified in water containing a pair of nonionic surfactants via a transitional phase inversion route. After phase inversion, which produced an oil-in-water miniemulsion, polymerisation of the vinyl monomer gave composite polymer particles. Low temperature emulsification was not practical because the inverted oil-in-water emulsions reinverted to water-in-oil emulsions upon raising the temperature to the reaction temperature. Miniemulsions prepared at the reaction temperature with low monomer content in the oil phase showed good stabilty in the course of polymerisation and produced latexes with a particle size similar to the size of drops in the initial miniemulsions. 相似文献
660.
The potentiality of a phoxonic crystal for sensing of biodiesel in a binary mixture of diesel and biodiesel is theoretically investigated. Using the transfer matrix method, the transmission of acoustic and optical waves through a periodic one-dimensional crystal of Si–SiO2 layers is studied. A pass band is created in the band gap region by introducing a cavity in the considered one-dimensional crystal structure. This pass band can also be considered as a defect mode, and it is found that its position is highly dependent on mole concentration of binary mixture of biodiesel and diesel present in the cavity. The sensitivity of the sensor for a binary mixture of biodiesel and diesel in the cavity with various mole concentrations is estimated. Simulated results provide a valuable guidance for designing a phoxonic crystal sensor consisting of a defect layer. 相似文献