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11.
Zixin Huang Josie E. Auckett Peter E. R. Blanchard Brendan J. Kennedy Wojciech Miiller Qingdi Zhou Maxim Avdeev Mark R. Johnson Mohamed Zbiri Gaston Garbarino William G. Marshall Qinfen Gu Chris D. Ling 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(13):3482-3485
Pressure‐induced charge transfer from Bi to Ir/Ru is observed in the hexagonal perovskites Ba3+nBiM2+nO9+3n (n=0,1; M=Ir,Ru). These compounds show first‐order, circa 1 % volume contractions at room temperature above 5 GPa, which are due to the large reduction in the effective ionic radius of Bi when the 6s shell is emptied on oxidation, compared to the relatively negligible effect of reduction on the radii of Ir or Ru. They are the first such transitions involving 4d and 5d compounds, and they double the total number of cases known. Ab initio calculations suggest that magnetic interactions through very short (ca. 2.6 Å) M M bonds contribute to the finely balanced nature of their electronic states. 相似文献
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Toka Diagana Gaston Nguerekata Nguyen Van Minh 《Proceedings of the American Mathematical Society》2004,132(11):3289-3298
This paper is concerned with the existence of almost automorphic mild solutions to equations of the form
where generates a holomorphic semigroup and is an almost automorphic function. Since almost automorphic functions may not be uniformly continuous, we introduce the notion of the uniform spectrum of a function. By modifying the method of sums of commuting operators used in previous works for the case of bounded uniformly continuous solutions, we obtain sufficient conditions for the existence of almost automorphic mild solutions to in terms of the imaginary spectrum of and the uniform spectrum of .
where generates a holomorphic semigroup and is an almost automorphic function. Since almost automorphic functions may not be uniformly continuous, we introduce the notion of the uniform spectrum of a function. By modifying the method of sums of commuting operators used in previous works for the case of bounded uniformly continuous solutions, we obtain sufficient conditions for the existence of almost automorphic mild solutions to in terms of the imaginary spectrum of and the uniform spectrum of .
15.
Rafael de la Madrid Gaston Garcia-Calderon Juan Gonzalo Muga 《Czechoslovak Journal of Physics》2005,55(9):1141-1150
The goal of this contribution is to discuss various resonance expansions that have been proposed in the literature.
Presented at the 3rd International Workshop “Pseudo-Hermitian Hamiltonians in Quantum Physics”, Istanbul, Turkey, June 20–22,
2005. 相似文献
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We report a pressure-dependent investigation of KMnF(3) by x-ray diffraction up to 30 GPa. The results are discussed in the framework of Landau theory and in relation to the isostructural phase transition in SrTiO(3). The phase transition temperature near 186 K in KMnF(3) shifts to room temperature at a critical pressure of P(c) = 3.4 GPa; the pressure dependence of the transition point follows ΔP(c)/ΔT(c) = 0.0315 GPa K(-1). The transition becomes second order under high pressure, close to the tricritical point. The phase transition is determined by the rotation of MnF(6) octahedra with their simultaneous expansion along the rotation axis. The rotation angle was found to increase to 10.5° at 24 GPa. An additional anomaly was observed at higher pressure around 25 GPa, suggesting a further phase transition. 相似文献
18.
This article presents the first application of gold nanoparticles deposited capillaries as pre-concentration devices for in-capillary microextraction CZE and their use for the analysis of monohydroxy-polycyclic aromatic hydrocarbons in synthetic urine samples. The successful separation of 1-hydroxypyrene, 9-hydroxyphenanthrene, 3-hydroxybenzo[a]pyrene (3-OHbap), 4-hydroxybenzo[a]pyrene and 5-hydroxybenzo[a]pyrene under a single set of electrophoretic conditions is demonstrated as well as the feasibility to obtain competitive ultraviolet absorption LOD with commercial instrumentation. Enrichment factors ranging from 87 (9-OHphe) to 100 (3-OHbap) made it possible to obtain LOD ranging from 9 ng/mL (9-OHphe and 3-OHbap) to 14 ng/mL (4-hydroxybenzo[a]pyrene). 相似文献
19.
Stéphanie Delbaere Gaston Vermeersch Jean-Claude MicheauAuthor vitae 《Journal of Photochemistry and Photobiology, C: Photochemistry Reviews》2011,12(2):74-105
The good understanding of a photochromic reaction mechanism requires the establishment of the list of all the transient species and the definition of their connecting processes. The purpose of kinetic studies is the determination of the main photochromic parameters, such as the quantum yields of photoisomerization, rate constants of thermal relaxation and spectra of transient species. These data allow the establishment of structure properties relationships in order to select the best substituents to improve photochromic performances within a given series. In this review, we describe the dynamic behaviour of various photochromic systems during thermal relaxation after irradiation, from the simplest mono-exponential decay to the more complicated multi-exponential dynamics. Then, we analyse the evolution of the long-lived isomers under continuous irradiation. Several pedagogical examples and tricks to perform easy kinetic analysis are given in the appendices. 相似文献
20.
Henri J. M. Dou Parina Hassanaly Jacky Kister Gaston Vernin Jacques Metzger 《Helvetica chimica acta》1978,61(8):3143-3148
S-Alkylation in heterocyclic serie by phase transfer catalysis: 2-alkylthiothiazoles, 2-alkylthio-Δ-4-thiazolines and 2-alkylthiobenzothiazoles Some Δ-4-thiazoline-, thiazolidine-, and benzothiazoline-2-thiones have been S-alkylated by phase transfer catalysis; yields averaged 80 to 90%. With halogenated heterocyclic compounds of poor reactivity, the main reaction consisted in a dequaternization of the catalyst by the thiones acting as nucleophiles. 相似文献