Cryostat attachment for IR spectrometers

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 50, No. 1, pp. 158–162, January, 1989.     

A two-fraction model for the calculation of the resonance spectra of the complex permittivity of ice in the far infrared

A two-fraction model that makes it possible to calculate analytically the complex dielectric permittivity of ice in the far infrared and submillimeter wavelength ranges is proposed. The librational and vibrational fractions are considered. The first fraction, consisting of rigid dipoles executing anharmonic reorientations in defects of the structure, gives rise to the librational band of ice at 800 cm^?1. The second fraction consists of elastically vibrating oppositely charged H-bonded molecules. This fraction describes two bands of ice in the range 100–300 cm^?1, and the nonresonant background of dielectric losses in the submillimeter wavelength range. The dielectric permittivity spectra of ice calculated for the temperature of ?7°C are consistent with the experimental spectra. The spectra of ice at the temperature ?30°C are predicted.     

On the model of divacancies in germanium

A model of a divacancy which explains a number of experimental facts for Ge exposed to a flow of accelerated electrons at temperature T=77 K is proposed. The model explains the absence of photoconduction associated with photoexcitation of infrared absorption bands at 0.44 and 0.52 eV corresponding to divacancies; the difference in the values of activation energy for divacancy energy levels determined by optical and electrical methods; and the existence of the limiting position of the Fermi level in the forbidden gap in the case of irradiation with large radiation fluxes.     

Polarization experiments with the SPIN setup at the ITEP synchrotron

New experimental data on the spin-rotation parameters A and R measured for elastic π ^± p scattering in the resonance region and on the asymmetry in pC scattering at primary momenta in the range 1.35–2.02 GeV/c, as well as in quasielastic proton scattering on nuclei in the same momentum range, are summarized. All these data were recently obtained by using the proton synchrotron installed at the Institute of Theoretical and Experimental Physics (ITEP, Moscow). The spectrum and features of seven isospin-3/2 baryon resonances that form a peak in the total cross section at a c.m. energy of 1.9 GeV are analyzed on the basis of new data on the parameters A and R, and the results of this analysis are presented. The experiments surveyed in this article were performed by a collaboration of researchers from ITEP and the Petersburg Nuclear Physics Institute (PNPI, Gatchina), the ITEP-PNPI collaboration.     

Modelling for the planning and management of bed capacities in hospitals

The internal dynamics of a hospital represent a complex non-linear structure. Planning and management of bed capacities must be evaluated within an environment of uncertainty, variability and limited resources. A common approach is to plan and manage capacities based on simple deterministic spreadsheet calculations. This paper demonstrates that these calculations typically do not provide the appropriate information and result in underestimating true bed requirements. More sophisticated, flexible and necessarily detailed capacity models are needed. The development and use of such a simulation model is presented in this paper. The modelling work, in conjunction with a major UK NHS Trust, considers various types of patient flows, at the individual patient level, and resulting bed needs over time. The consequence of changes in capacity planning policies and management of existing capacities can be readily examined. The work has highlighted the need for evaluating hospital bed capacities in light of both bed occupancies and refused admission rates. The relationship between occupancy and refusals is complex and often overlooked by hospital managers.     

Account of Thermal Flow Through Metal-Semimetal BiSb Contact Boundary for Determination of EHF Detector Volt-Watt Sensitivity

Bismuth, antimony and its alloys are the typical representatives of a class of semimetals, which electric conductance is lower in 10²-10³ times, than of usual well conducting an electrical current metals. The alloys bismuth with antimony have semi-conductor properties in wide area of compositions at temperatures below 77 °K. The semimetals are rather perspective materials from the point of view of their probable application in various devices [1,2,3].In present time the semimetal alloys BiSb have wide application in thermoelectric generators and refrigerators. In work [3] the opportunity of use of semimetals BiSb with percentage content of Bi and Sb from 8 % up to 25 % was shown as high-sensitivity and of small inertion indicators of the mm range radiation where thermoelectric effect is used. The principle of action of such indicators is based on occurrence of temperature gradient in a semimetal crystal BiSb that has two contacts of the various area with flowing electrical current. Basic element of such device is the dot contact metal - semimetal. One of the main characteristics is volt-watt sensitivity of metal-semimetal BiSb contact which calculating is shown in present work.     

The first total synthesis of (R)-convolutamydine A

The first total synthesis of (R)-convolutamydine A has been achieved by the organocatalytic addition of acetone to 4,6-dibromoisatin. The absolute configuration was determined by single crystal X-ray diffraction. DFT studies were used to model the transition states for the aldol reaction and equilibrium geometries of the post-aldol reaction intermediates. The DFT study revealed that the aldol bond forming reaction was considerably endothermic.     

An expansion in the exponent for compound binomial approximations

The purpose of this paper is two-fold. First, we introduce a new asymptotic expansion in the exponent for the compound binomial approximation of the generalized Poisson binomial distribution. The dependence of its accuracy on the symmetry and shifting of distributions is investigated. Second, for compound binomial and compound Poisson distributions, we present new smoothness estimates, some of which contain explicit constants. Finally, the ideas used in this paper enable us to prove new precise bounds in the compound Poisson approximation. Published in Lietuvos Matematikos Rinkinys, Vol. 46, No. 1, pp. 67–110, January–March, 2006.