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11.
Garguilo J Hong L Edwards GS Nemanich RJ Simon JD 《Photochemistry and photobiology》2007,83(3):692-697
A technique for measuring the photoionization spectrum and the photoelectron emission threshold of a microscopic structured material is presented. The theoretical underpinning of the experiment and the accuracy of the measurements are discussed. The technique is applied to titanium silicide nanostructures and melanosomes isolated from human hair, human and bovine retinal pigment epithelium cells, and the ink sac of Sepia officinalis. A common photothreshold of 4.5 +/- 0.2 eV is found for this set of melanosomes and is attributed to the photoionization of the eumelanin pigment. The relationship between the photoionization threshold and the electrochemical potential referenced to the normal hydrogen electrode is used to quantify the surface oxidation potential of the melanosome. The developed technique is used to examine the effect of iron chelation on the surface oxidation potential of Sepia melanosomes. The surface oxidation potential is insensitive to bound Fe(III) up to saturation, suggesting that the metal is bound to the interior of the granule. This result is discussed in relation to the age-dependent accumulation of iron in human melanosomes in both the eye and brain. 相似文献
12.
A De A Mitra A Ray SR Banerjee M Sengupta A Chatterjee S Kailas HS Patel MG Betigiri SK Dutta 《Pramana》1999,53(3):549-552
In this paper, we report our measurements of back-angle oxygen and carbon particle yields from 16O+89Y, 12C+93Nb reactions forming the same compound nucleus 105Ag at the same excitation energy and spin distribution. We find anomalously large oxygen yield and entrance channel dependence
at high excitation energies from 16O+89Y reaction implying formation of a dinuclear orbiting complex. Possible connection between nuclear orbiting and fast fission
is also discussed. 相似文献
13.
Helane?MS?Costa Augusto?CV?Freitas Júnior Ian?PG?Amaral Izaura?Y?Hirata Patrícia?MG?Paiva Luiz?B?CarvalhoJr Vitor?Oliveira Ranilson?S?BezerraEmail author 《Chemistry Central journal》2013,7(1):166