Wind tunnel simulation of air pollution dispersion in a street canyon

Physical simulation was used to study pollution dispersion in a street canyon. The street canyon model was designed to study the effect of measuring flow and concentration fields. A method of C02-laser photoacoustic spectrometry was applied for detection of trace concentration of gas pollution. The advantage of this method is its high sensitivity and broad dynamic range, permitting monitoring of concentrations from trace to saturation values. Application of this method enabled us to propose a simple model based on line permeation pollutant source, developed on the principle of concentration standards, to ensure high precision and homogeneity of the concentration flow. Spatial measurement of the concentration distribution inside the street canyon was performed on the model with reference velocity of 1.5 m/s.     

Cylindricity of tangent bundles of strongly parabolic metrics and strongly parabolic surfaces

It is proved that if the intrinsic zero-index of the Sasaki metric of a tangent bundleTM ⁿ isk, thenk is even andM ⁿ is the metric product of a Riemannian manifoldM ^n–k/2 by a Euclidean spaceE ^k/2, whileTM ⁿ is the metric product ofTM ^n–k/2 byE ^k . An expression is obtained for the second fundamental forms of the imbeddingTF ^l TM ⁿ in terms of the second fundamental forms of the imbeddingF ^l M ⁿ and the curvature tensor ofM ⁿ . It is proved thatTF ^l is totally geodesic inTM ⁿ if and only ifF ^l is totally geodesic inM ⁿ .Translated from Ukrainskií Geometricheskií Sbornik, Issue 28, 1985, pp. 12–32.     

Yttrium aluminate crystals for slabs

The methods of growing YAG:Nd crystals with a flat interface and YAP:Nd crystals with a sharp conical interface are described. The form of the interface was controlled by the He and H₂O content in the reducing atmosphere composed mainly of Ar and H₂ as well as by axial temperature gradient above the melt level. The crystals of 120–180 mm in length were machined to the high-quality slabs.     

Non-steady state homogeneous nucleation in glass-forming systems: Dimensionless kinetic equation

The kinetic equation of the classical homogeneous nucleation theory is rewritten in dimensionless form and it is shown that the numerical computation of the dimensionless kinetic equation is approximately 20 times faster in comparison with the original kinetic equation. The results are compared with known analytical results and with previous numerical results in the case of the constant and variable temperature for the model Li₂O.2 SiO₂ melt. It is shown, e.g., that under non-isothermal conditions the nucleation rate is greater than the quasistationary nucleation rate and the cluster distribution function is greater than the corresponding quasiequilibrium cluster distribution function.     

XPS investigation of LPE garnet films

XPS spectra of YIG, YIG:Bi, YIG:Ca and YIG:Co(Ge, Ca) epitaxial garnet films were measured at room temperature. The positions of the main iron, yttrium, oxygen, bismuth, cobalt and lead spectral lines were determined and their changes with the surface treatments were investigated. It was found that divalent and trivalent states of iron and cobalt ions can be resolved, the chemical shifts being in oposite directions.The authors would like to thank Dr. J. imová for careful EPMA analysis of the samples.     

Mössbauer and infrared spectroscopic studies of novel mixed valence states in cobaltous ferrocyanides and ferricyanides

Novel mixed valence states have been obtained by the treatment of cobaltous ferrocyanides (Co⁺²Fe^II) and ferricyanides (Co⁺²Fe^III) in an ozone flow. The CN stretching bands occur at 2085 cm^–1 for Co⁺²Fe^II and at 2160 cm^–1 for Co⁺²Fe^III. After the ozonization process of Co⁺²Fe^II, an intense band approximately at 2125 cm^–1 is detected. This intermediate band must correspond to a mixed valence state of the type: Fe^II–CN–Co²⁺–NC–Fe^III Mössbauer spectra recorded in situ during the ozonization of Co⁺²Fe^II show the presence of two components: a doublet with isomer shift and quadrupole splitting values close to the cobalti ferricyanide and a very broad line for the mixed valence state. From the Mössbauer and infrared spectra of the aged samples of the Co⁺²Fe^II after ozonization, a relaxation process to the initial state of the samples is observed but the mixed valence state is stable.     

Rigidity of codimension two indefinite spheres

We describe all isometric immersions f:S _n ^s S _s ⁿ +2/S _s ⁿ n–s4, whenever the set of totally geodesic points does not disconnect S _s ⁿ , where S _n ^s denotes the complete n-dimensional indefinite Riemannian space form of constant positive curvature 1 and signature s.     

Sensitivity of hydrodynamic system of the Obukhov type

The paper deals with the regime of advanced Bénard instabilities (described usually by the Lorenz system) in a more general system formulated firstly by Obukhov. It has been shown that triplet co-operation leads to characteristic courses where some new regularities occur.     

Influence of metastable-metastable collisions on electron distribution function in afterglow

The time dependence of the electron distribution function in helium afterglow, for pressures of 60–260 Pa, is calculated for the case in which metastable-metastable reactions are present. The time variation of the shape of the distribution function shows that careful consideration must be made of the time derivative of the distribution function in the Boltzmann equation for the calculation of the rate constant of such reactions from experimentally determined distribution function.