Effect of local structure on electron paramagnetic resonance spectra for trigonal [Cr(H2O)6]3+coordination complex in the sulfate alums series: a ligand field theory study

A simple theoretical method is introduced for studying the interrelation between electronic and molecular structures.By diagonalizing the 120 × 120 complete energy matrices,the relationships between zero-field splitting(ZFS) parameter D and local distortion parameter △θ for Cr 3+ ions doped,separately,in α-and β-alums are investigated.Our results indicate that there exists an approximately linear relationship between D and △θ in a temperature range 4.2-297 K and the signs of D and △θ are opposite to each other.Moreover,in order to understand the contribution of spin-orbit coupling coefficient ζ to ZFS parameter D,the relation between D and ζ is also discussed.     

Numerical simulation and experiment of TA2 sheet forming under laser shock

The effects of laser energy and different shock spaces and shock times on the TA2 titanium sheet deformation are investigated experimentally and simulated numerically by ABAQUS software. The results indicate that the amount of TA2 sheet deformation increases with the increase of laser energy, varies with shock order and shock path, and is the greatest when the shocks are along the length of sheet and symmetrical.The numerically simulative results are consistent with the experimental data.     

The circular and elliptic white-light dark spatial solitons in a photovoltaic self-defocusing nonlinear medium

We observed circular white-light dark spatial solitons in photovoltaic self-defocusing LiNbO₃:Fe crystal using an ordinary incandescent lamp as light source (a line source) with the filament of the bulb parallel to the crystalline c axis. Besides the above condition, the formation of the elliptic soliton needs an additive condition that the crystalline c axis is parallel to the minor axis of dark elliptic spot.     

2.0μm附近模拟呼吸气体中~(13)CO_2/~(12)CO_2同位素丰度的高精度实时在线测量

采用可调谐二极管激光吸收光谱技术,结合一新型多通池搭建了一套模拟呼吸气体中CO_2同位素丰度的测量装置.气体的压强、温度和流速被很好地控制且均能保持长期的稳定性;采用三次多项式拟合光谱基线,对光谱进行归一化,很好地消除了功率变化对测量结果的影响;利用移窗-回归技术消除频率漂移对同位素丰度测量的影响.实验结果表明:移窗-回归法的引入不仅延长了系统的稳定时间,还提高了系统的测量精度;小波去噪的应用获得了比多光谱平均法高2倍的信噪比;系统的稳定时间为100 s;Kalman滤波后系统测量精度为0.067‰.     

导弹目标单、双基地雷达散射截面对比分析

目标单、双基地雷达散射截面(RCS)反映了目标是否容易被单、双基地雷达检测到。目前缺乏单、双基地RCS对比的量化指标。首先定义了双基地RCS相对于单基地RCS的RCS增强因子和RCS增强率,然后应用该定义统计分析了某隐身目标和非隐身目标双基地RCS计算结果。结果显示：对隐身目标,RCS增强因子大,RCS增强率高,对于非隐身目标,其RCS增强因子显著下降,RCS增强率不高。结合指标含义,应用双基地RCS有助于隐身目标检测,而对非隐身目标效果并不明显,这与雷达界认识相一致。这也说明,应用上述两个指标进行单、双基地RCS对比分析是有效的。此外根据隐身目标在较窄双基地角范围内的双基地RCS分析结果,应用双基地角20°~40°范围内的双基地RCS即可提高对隐身目标的检测效果。     

General solutions of plane elasticity of one-dimensional orthorhombic quasicrystals with piezoelectric effect

By introducing four potential functions, the governing equations of plane problems in 1D orthorhombic quasicrystals with piezoelectric effect are composed of four second-order partial differential equations, in which the quasi-harmonic functions are the essential unknowns. The general solution of these equations is further established, and all expressions are expressed in terms of the potential functions. As an application of the general solution, the closed-form solutions are obtained for wedge problems or half-plane problems of 1D orthorhombic piezoelectric quasicrystals.     

Search for exclusive multibody non- decays at the resonance

Using data collected at the psi(3770) resonance with the CLEO-c detector at the Cornell e+e- storage ring, we present searches for 25 charmless decay modes of the psi(3770), mostly multibody final states. No evidence for charmless decays is found.     

Effect of γ-ray irradiation on the magnetic properties of NdFeB and Fe–Cr–Co permanent magnets

The effect of γ-ray irradiation on the magnetic properties of NdFeB and Fe–Cr–Co permanent magnets has been investigated. The magnetic flux loss of two kinds of magnets before and after irradiation was measured. Results show that the effect of γ-ray irradiation on the magnetic properties of sintered NdFeB is not so obvious as that on Fe–Cr–Co magnet. Irradiation-induced damage from γ-ray for the Fe–Cr–Co magnets was characterized for the first time. The decline of permanent magnetic properties of Fe–Cr–Co magnet induced by γ-ray irradiation is reversible except for the maximum energy product (BH)_max. The difference of coercivity mechanism between these two kinds of permanent magnets is responsible for the different dependence of magnetic properties loss induced by γ-ray irradiation.     

Microstructure and optical properties of nitrogen-doped ZnO film

The nitrogen doping of ZnO film deposited by the magnetron sputtering method is subsequently realized by the hydrothermal synthesis method.The nitrogen-doped ZnO film is preferably(002) oriented.With the increase of hexamethylenetetramine(HMT) solution concentration,the average grain size of the film along the 002 direction almost immediately decreases and then monotonously increases,conversely,the lattice strain first increases and then decreases.The structural evolution of the film surface from compact and even to sparse and rough is attributed to the enhanced nitrogen doping content in the hydrothermal process.The transmission and photoluminescence properties of the film are closely related to grain size,lattice strain,and nitrogen-related defect arising from the enhanced nitrogen doping content with HMT concentration increasing.     

A Note on Resistance of NPT to Mixture of Separable States

We study the stability of NPT property of an arbitrary pure entangled state under the mixture of arbitrary pure separable states. For bipartite pure states with Schmidt number n (n>1) which is NPT, we show that this state is still NPT when it is mixed with no more than $\frac {n(n-1)}{2}-1$ arbitrary pure separable states. This result is generalized to multipartite case.