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11.
Metal-acteylacetonates are important sublimable metal-organic precursors for metal-oxide thin film formation over solid preforms by MOCVD (Metal Organic Chemical Vapour Deposition) technique. Mixed-metal-acetylacetonates (MMAA) are suitable starting materials for mixed metal nano-oxidic thin film formation through such facile routes. Layered Double Hydroxides (LDH) of suitable metal ion combination can perform as appropriate starting base for neutralisation by enol form of 2,4-pentanedione or acteylacetonate tautomer ligands to obtain such MMAA. In this paper synthesis of composite crystals of Cu(II)/Cr(III) acetylacetonates (CCAA) is reported by the reaction of Cu–Cr-LDH with acetylacetone. The products were characterized by various different techniques. The surface area and pore volume analysis of the crystals showed the formation of nanopores in the compound. TEM analysis confirmed that the inner core of the nanoporous crystals of Cu(acac)2 was covered by coating of poorly crystallised Cr(acac)3 and they together form the composite crystals, and they together form the composite crystals. Due to eutectic mixture formation the melting point of CCAA lies in between the melting points of individual components Cu(acac)2 and Cr(acac)3 and shows sublimability, a property important for the formation of MOCVD films. The composite was used for CuCr2O4 spinel mixed oxide films formation over solid ceramic honeycomb monolithic substrates. Application prospects of the route in the field of catalysis is high as it can directly combine the benefits of mixed metal oxide catalysis and structured supports without the involvement of a third component. In this work the performance of such a catalytic device has been tested for low temperature decomposition of high Global Warming Potential (GWP) gas N2O to N2 and O2. 相似文献
12.
[reaction: see text] The microwave-mediated three-component reaction of acyl bromide, pyridine, and acetylene is catalyzed by basic alumina to give corresponding indolizines in excellent yields in a one-pot reaction. 相似文献
13.
Nabajyoti Saikia Shigeru Kato Toshinori Kojima 《Journal of Thermal Analysis and Calorimetry》2012,109(1):273-286
Tricalcium aluminate (Ca3Al2O6, C3A) containing 0?C5% of Sn was synthesized by solid-state method, and the products were characterized by XRD technique. Differential thermo-analytical technique (DTA) along with X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM) were applied to study the hydration behaviour of different C3A samples with and without the presence of gypsum. Results indicate that C3A can accommodate small amount of Sn in its structure and remaining amount forms SnO2. Hydration studies of the synthesized C3A shows that the additions of 0.5 and 1% Sn increase and 2% Sn decrease the reactivity of C3A at the initial period (<3?h) of hydration. Increasing additions of Sn also increase the amounts of amorphous phases and hexagonal calcium aluminate hydrates in the cement pastes. The stabilities of these hydration products also increase with increasing content of Sn in C3A at the experimental conditions. The presence of Sn significantly changes the hydration of C3A and gypsum solid mixture at the initial period of hydration by enhancing the formation of more amounts of AFt and AFm phases. However, at the later stage of hydration (on or after 3?days), the hydration products in C3A and gypsum pastes with and without the presence of Sn are almost similar. 相似文献
14.
It was observed that the reaction of CFCl3 with thiophenoxide gave only 10% of the corresponding thioether. On the other hand, these thioethers could be prepared in excellent yield from diaryl disulfides and CFCl3 in the presence of sodium hydroxymethanesulfinate in aqueous DMF at 4 atm pressure of nitrogen. Dechlorination of the thioether (PhSCFCl2) with different reducing agents were studied. Most of the reducing agents eliminated both fluorine and chlorine functionalities or gave the hydrolyzed products. But its sulfone on treatment with Zinc in methanol gave monochlorofluoromethyl and fluoromethyl phenyl sulfone in good yields. Darzens reaction of these compounds was also studied. 相似文献
15.
We obtain ratchet effect in inertial structureless systems in symmetric periodic potentials where the asymmetry comes from
the non-uniform friction offered by the medium and driven by symmetric periodic forces. In the adiabatic limit the calculations
are done by extending the matrix continued fraction method and also by numerically solving the appropriate Langevin equation.
For finite frequency field drive the ratchet effect is obtained only numerically. In the transient time scales the system
shows dispersionless behaviour as reported earlier when a constant force is applied. In the periodic drive case the dispersion
behaviour is more complex. In this brief communication we report some of the results of our work.
相似文献
16.
Decomposition of clay from Garo Hills of Meghalaya (India) was studied by dynamic thermogravimetry. A fourteen kinetic equation procedure was applied for analysis of non-isothermal weight change upto a temperature of 1223 K. Two stages of decomposition were clearly distinguised i.e. the initial dehydration period at temperature 373 K to 673 K and the dehydroxylation period in the temperature range 723 K to 1073 K. First order decomposition mechanism was found to be applicable to both dehydration and dehydroxylation steps. Activation energies of 67 kJ/mol and 278 kJ/mol are estimated for the first and second steps with frequency factors of 16.3 s–1 and 5.16×106s–1 respectively. The weight loss relating to the steps in TG curves allows determination of the contents of the basic mineral in the clay. Percentages of Al2O3.SiO2 and total volatiles as calculated from weight loss data are in accordance with the results of classical chemical analysis.
Zusammenfassung Mittels DTG wurde die thermische Zersetung von Ton aus der Garo-Hills-Gegend bei Meghalaya (Indien) untersucht. Zur Analyse der nicht-isothermen Gewichtsveränderungen bis zu einer Temperatur von 1223 K wurde ein Verfahren mit vierzehn kinetischen Gleichungen angewendet. Zwei Teilschritte der Zersetzung können eindeutig unterschieden werden, nämlich die anfängliche Dehydratationsperiode bei Temperaturen von 373 bis 673 K und die Dehydroxylierungsperiode bei Temperaturen zwischen 723 K un 1073 K. Für beide Vorgänge konnte als Reaktionsmechanismus eine Zersetzung erster Ordnung angewendet werden. Für den ersten un zweiten Teilschritt konnten Aktivierungsenergien von 67 kJ/mol bzw. 278 kJ/mol un Frequenzfaktoren von 16.3s–1 bzw. 5.16×106s–1 ermittelt werden. Der aus den TG-Kurven hervorgehende Gewichtsverlust läßt auf den Gehalt des Tones an Basismineral schließen. Der prozentuelle Gehalt an Al2O3, SiO2 und der gesamten flüchtigen Bestandteile, berechnet aus den Gewichtsverlusdaten, stimmt mit den Ergebnissen aus herkömmlichen chemischen Analysen überein.相似文献
17.
In this paper, we find new proofs of modular relations for the Göllnitz-Gordon functions established earlier by S.-S. Huang and S.-L. Chen. We use Schröter’s formulas and some simple theta-function identities of Ramanujan to establish the relations. We also find some new modular relations of the same nature. 相似文献
18.
Rupom Borah Eramoni Saikia Sankar Jyoti Bora Bolin Chetia 《Tetrahedron letters》2017,58(12):1211-1215
A green and facile novel procedure has been developed for the synthesis of Cu2O nanoparticles within a very short reaction time using banana pulp extract as a reducing agent. The synthesized nanoparticles are well characterized by SEM (Scanning Electron Microscope), TEM (Transmission Electron Microscope) and powder XRD (X-ray Diffraction) methods. An environmental benign and highly efficient protocol for the ipso-hydroxylation of aryl and hetero arylboronic acids using bio-fabricated Cu2O nanoparticles as a catalyst and aqueous H2O2 as an oxidant has also been developed. The main advantages of this protocol are the base free reaction condition, reusable and heterogeneous catalytic system, and short reaction time with excellent yields. 相似文献
19.
Reenamoni Saikia Chaliha K. Annapurna Anal Tarafder V.S. Tiwari P.K. Gupta Basudeb Karmakar 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2010,75(1):243-250
Precursor glass of composition 25K2O–25Nb2O5–50SiO2 (mol%) doped with Er2O3 (0.5 wt% in excess) was isothermally crystallized at 800 °C for 0–100 h to obtain transparent KNbO3 nanostructured glass–ceramics. XRD, FESEM, TEM, FTIRRS, dielectric constant, refractive index, absorption and fluorescence measurements were carried out to analyze the morphology, dielectric, structure and optical properties of the glass–ceramics. The crystallite size of KNbO3 estimated from XRD and TEM is found to vary in the range 7–23 nm. A steep rise in the dielectric constant of glass–ceramics with heat-treatment time reveals the formation of ferroelectric nanocrystalline KNbO3 phase. The measured visible photoluminescence spectra have exhibited green emission transitions of 2H11/2, 4S3/2 → 4I15/2 upon excitation at 377 nm (4I15/2 → 4G11/2) absorption band of Er3+ ions. The near infrared (NIR) emission transition 4I13/2 → 4I15/2 is detected around 1550 nm on excitation at 980 nm (4I15/2 → 4I11/2) of absorption bands of Er3+ ions. It is observed that photoluminescent intensity at 526 nm (2H11/2 → 4I15/2), 550 nm (4S3/2 → 4I15/2) and 1550 nm (4I13/2 → 4I15/2) initially decrease and then gradually increase with increase in heat-treatment time. The measured lifetime (τf) of the 4I13/2 → 4I15/2 transition also possesses a similar trend. The measured absorption and fluorescence spectra reveal that the Er3+ ions gradually enter into the KNbO3 nanocrystals. 相似文献
20.
Tin oxide (SnO2) thin films have been grown on glass substrates using atmospheric pressure chemical vapour deposition (APCVD) method. During
the deposition, the substrate temperature was kept at 400°C–500°C. The structural properties, surface morphology and chemical
composition of the deposited film were studied by X-ray diffraction (XRD), scanning electron microscope (SEM) and Rutherford
back scattering (RBS) spectrum. XRD pattern showed that the preferred orientation was (110) having tetragonal structure. The
optical properties of the films were studied by measuring the transmittance, absorbance and reflectance spectra between λ = 254 nm to 1400 nm and the optical constants were calculated. Typical SnO2 film transmits ∼ 94% of visible light. The electrical properties of the films were studied using four-probe method and Hall-voltage
measurement experiment. The films showed room temperature conductivity in the range 1.08 × 102 to 1.69 × 102 Ω−1cm−1. 相似文献