寄生虚反射对外差干涉椭偏测量的影响

研究了一种采用横向塞曼激光器并且没有任何运动部件的外差干涉椭偏测量系统。由非理想的激光源、偏振分光镜等器件所产生的非线性误差,是影响纳米测量精度的主要因素。采用琼斯矢量法,分析并建立了光学系统寄生虚反射所引入的误差模型,讨论了虚反射对误差漂移的影响。在不考虑其它误差因素的前提下,同一光路内部产生的同频率虚反射波对测量结果没有影响;而不同频率的参考光束与测量光束之间的交叉虚反射所产生的膜厚测量误差为亚纳米量级。讨论了消除和抑制虚反射误差的方法。     

一种蓝色聚合物激光材料

聚合物作为一种有机发光材料,由于在平板显示和光电子器件中的良好应用前景而受到广泛研究［１～２］．近年来,一个重要进展是在聚合物中观测到了受激发射（简称Ｐｏｌｙ－ｍｅｒ激光）现象［３～６］．Ｐｏｌｙｍｅｒ激光最早是在溶液中实现的［３～４］．作为一种新型...     

声光栅正弦结构光投射器的光学系统设计

针对一种新型的声光波干涉测量技术,对声光栅正弦结构光投射器的三维测量工作原理进行了系统的分析,讨论了影响投射器光学系统结构的因素和影响接收屏上的光照度的因素,并进行了光学系统设计。在优化设计过程中,采用了限制光线最大入射角的方法,达到控制投射系统的球差和保证接收屏上照明均匀的要求。所设计的声光栅正弦光投射器具有很好的成像质量。应用该系统对在500mm处的石膏像上投射干涉条纹,可以得到能量比较均匀、变形量很小的干涉条纹图,利用该条纹图和相关的算法可以对具有复杂几何形状的物体进行有效的三维测量。     

光纤耦合数码系统传像特性

建立了光纤传像元件与光电阵列器件的匹配耦合模型,引入变动因子反映像素光纤排列的不确定性,进行了光纤耦合传像特性的仿真研究.针对9×9 μm2光敏元的阵列器件,分析了光纤传像元件结构参数变化对系统分辨率的影响,在光纤直径约为光敏元尺寸1/3时获得了相对经济合理的匹配结构,表明光纤耦合数码系统设计时必须考虑优化匹配问题.仿真结果还解释了系统的图像输出存在条纹和局部结构背景的原因,给出了相应的数值分析方法.     

Non-Invasive Detection of Anti-Inflammatory Bioactivity and Key Chemical Indicators of the Commercial Lanqin Oral Solution by Near Infrared Spectroscopy

Quality control methods of current traditional Chinese medicine (TCM) preparation is time-consuming and difficult to assess in terms of overall efficiency of the drug. A non-destructive rapid near-infrared spectroscopy detection system for key chemical components and biological activity of Lanqin oral solution (LOS), one of the best-selling TCM formulations, was established for comprehensive quality evaluation. Near infrared spectral scanning was carried out on 101 batches of commercial LOS under the penetrated vial state and traditional state. RAW 264.7 cells were cultured to detect the anti-inflammatory ability of LOS, and the reference concentrations of epigoitrin, geniposide, and baicalin were obtained by HPLC. The quantitative models were optimized by three kinds of variable selection methods. The correlation coefficients of prediction value of the models were greater than 0.94. The system also passed the external validation. The performance of the non-invasive models was similar to the traditional models. The established non-destructive system can be applied to the rapid quality inspection of LOS to avoid unqualified drugs from entering the market and ensure drug effectiveness. The biological activity index of LOS was introduced and predicted by NIRs for the first time, which provides a new idea about the quality control of TCM formulations.     

化学教学中的素质教育

长期以来,人们习惯于把化学教育单纯地看成学科专业化教育,而"仅用专业知识教育人是不够的,通过专业教育,他可以成为一种有用的机器,但并不能成为一个和谐发展的人"(爱因斯坦语),这就要求化学教师在传授化学基础知识、基本技能的同时,充分利用化学知识的文化价值、社会价值和教育价值,积极探索化学教育实现素质教育的方法和途径,使得学生学会做人、学会学习、学会生活、学会劳动、学会健体、学会审美和学会创造.     

Synthesis of laterally substituted bistolane liquid crystals

Methods for synthesizing bistolane liquid crystal materials with lateral methyl and ethyl substituents are presented. Some of the bistolanes are nematic at room temperature. These highly conjugated mesogens exhibit wide nematic ranges, small enthalpies of fusion, high birefringence and modest viscosity. Their potential applications for flat panel displays employing light scattering or Bragg reflection and for infrared optically phased arrays are foreseeable.     

Ag/CNT‐catalyzed hydroamination of activated alkynes with aromatic amines

As a nanoparticle support material, carbon nanotubes (CNTs) provide a certain potential activation of catalysis in heterogeneous catalytic organic reactions. Herein, an efficient Ag/CNT‐catalyzed synthesis of enamines via hydroamination of activated alkynes with aromatic amines has been described. This catalyst still retains catalytic activity after being recycled and reused three times. In addition, it represents a green and environmentally friendly process for preparation of enamines. Copyright © 2013 John Wiley & Sons, Ltd.     

Determination of protoapigenone in rat plasma by high‐performance liquid chromatography with UV detection and its application in pharmacokinetic studies

A simple and sensitive HPLC method using UV detection was developed to determine the concentration of protoapigenone in rat plasma. Chromatographic separation was conducted on a C₁₈ column with a mobile phase consisting of an acetonitrile–methanol–aqueous phase (containing 0.2% acetic acid, pH 3.0) system at a flow rate of 1.0 mL/min. The UV detector was set at 248 nm. The calibration curve was linear over the range of 0.031–10.0 µg/mL. The lower limit of quantification was 31 ng/mL. The recoveries for plasma samples ranged from 70.3 to 82.5%. The intra‐ and inter‐day accuracy and precision fulfilled the international standards. This method was successfully applied to a pharmacokinetic study of protoapigenone in rats after oral administration of protoapigenone. It was shown that protoapigenone could be absorbed rapidly after oral administration and could reach the maximum concentration within 1 h. Copyright © 2013 John Wiley & Sons, Ltd.     

Simulation of a 2-site Langmuir model for characterizing the sorption capacity of Cs and Se in crushed mudrock under various ionic strength effects

The sorption capacity of cesium (Cs) and selenium (Se) in crushed mudrock was demonstrated in this study through a 2-site Langmuir model. To employ such a numerical analysis, batch tests were applied in this study in synthetic seawater and groundwater with sorption/desorption kinetic experiments (time-dependent) and different concentrations (10^?2–10^?7 M). The 2-site sorption models, which correspond to two rate constants (λ ₁ and λ ₂), might be more adequate than 1-site sorption models in characterizing Cs and Se sorption/desorption according to the least square errors between the numerical analysis and the results of the batch tests. The fitting results showed that a 2-site Langmuir model is capable of appropriately describing Cs and Se sorption in mudrock. Consequently, the sorption capacity was calculated at about 0.06 mol/kg for Cs and at 0.015 mol/kg for Se.