Anion⋅⋅⋅Anion Interactions Involving σ-Holes of Perrhenate,Pertechnetate and Permanganate Anions

In this communication experimental and theoretical results are reported affording strong evidence that interactions between electron rich atoms and the metal of tetroxide anions of group 7 elements are a new case of attractive and σ-hole interactions. Single crystal X-ray analyses, molecular electrostatic potentials, quantum theory of atoms-in-molecules, and noncovalent interaction plot analyses show that in crystalline permanganate and perrhenate salts the metal in Mn/ReO₄⁻ anion can act as electron acceptors, the oxygen of another Mn/ReO₄⁻ anion can act as the donor and supramolecular anionic dimers or polymers are formed. The name matere bond (MaB) is proposed to categorize these noncovalent interactions and to differentiate them from the classical metal-ligand coordination bond.     

Aquantitative assessment of stochastic electrodynamics with spin (SEDS): Physical principles and novel applications

Stochastic electrodynamics (SED) without spin, denoted as pure SED, has been discussed and seriously considered in the literature for several decades because it accounts for important aspects of quantum mechanics (QM). SED is based on the introduction of the nonrenormalized, electromagnetic stochastic zero-point field (ZPF), but neglects the Lorentz force due to the radiation random magnetic field Br. In addition to that rather basic limitation, other drawbacks remain, as well: i) SED fails when there are nonlinear forces; ii) it is not possible to derive the Schrödinger equation in general; iii) it predicts broad spectra for rarefied gases instead of the observed narrow spectral lines; iv) it does not explain double-slit electron diffraction patterns. We show in this short review that all of those drawbacks, and mainly the first most basic one, can be overcome in principle by introducing spin into stochastic electrodynamics (SEDS). Moreover, this modification of the theory also explains four observed effects that are otherwise so far unexplainable by QED, i.e., 1) the physical origin of the ZPF, and its natural upper cutoff; 2) an anomaly in experimental studies of the neutrino rest mass; 3) the origin and quantitative treatment of 1/f noise; and 4) the high-energy tail (～ 10²¹ eV) of cosmic rays. We review the theoretical and experimental situation regarding these things and go on to propose a double-slit electron diffraction experiment that is aimed at discriminating between QM and SEDS. We show that, in the context of this experiment, for the case of an electron beam focused on just one of the slits, no interference pattern due to the other slit is predicted by QM, while this is not the case for SEDS. A second experiment that could discriminate between QED and SEDS regards a transversely large electron beam including both slits obtained in an insulating wall, where the ZPF is reduced but not vanished. The interference pattern according to SEDS should be somewhat modified with respect to QED’s.     

An Alternative Approach to the Electric Charge Quantization with Non-global Potentials

We present an alternative approach to justify the electric charge quantization by means of non-global electromagnetic potentials. We adopt a non-global potential whose singularity does not goes over to infinity and can be entirely embedded into an arbitrarily small closed ball.     

Enantiopure 2-piperidylacetaldehyde as a useful building block in the diversity-oriented synthesis of polycyclic piperidine derivatives

Novel, simple, and convenient strategies for diversely functionalized piperidine derivatives have been developed by using different metal catalyzed reactions starting from enantiopure (R)- and (S)-2-piperidylacetaldehyde.     

X-ray Analysis of Chiral Thermotropic Liquid Crystal Copolyesters Based on Linear and Nonlinear Aromatic Ester Triads

A series of chiral thermotropic liquid crystalline copolyesters, based on linear mesogenic triads and nonlinear nonmesogenic triads consisting of two p-oxybenzoyl units coupled by a terephthaloyl or phthaloyl residue respectively, is studied by X-ray diffraction. Complementary data of differential calorimetry and polarizing microscopy are presented. The degree of crystallinity is found to depend significantly on the relative content of the nonlinear counit and to vary with thermal history. The occurrence of cholesteric phases is established, whose stability and breadth can be modulated on the basis of appropriate chemical compositions. The structural data of the investigated copolymer samples are compared with those previously obtained for an analogous series of copolymer samples based on the same linear aromatic triad and an isomeric triad containing a central isophthaloyl residue.

Keywords: liquid crystalline polymers, chiral thermotropic polymers, cholesteric copolyesters, 4,4'-(terephthaloyldioxy)dibenzoate mesogen, X-ray diffraction     

Acoustic behaviour of amorphous selenium

The attenuation of longitudinal sound waves in amorphous selenium has been measured at frequencies of 15 and 25 MHz and in the range of temperature between 10 and 310 K. It is shown that absorption exhibits a minimum around Tτ150 K, while a pronounced maximum takes place around 30 K. Such a behaviour is briefly discussed in the frame of acoustic properties of amorphous material below the glass temperature. It is shown that the experimental results can be described, almost qualitatively, in terms of a recently proposed theoretical model involving a stochastic resonance that seems to be characteristic of the disordered systems.