Heats of immersion of some ion-exchanged A and X zeolites of divalent cations

Heats of immersion in water (integral heats of hydration) of anhydrous zeolites NaA, CdA, ZnA, CoA, NaX, CdX, ZnX, CoX and NiX have been determined calorimetrically at 25°C. Sodium in NaA and NaX has been replaced by divalent cations to the extent of 70–100% . The data are correlated to the size of the cations and to the standard enthalpy changes of the corresponding ion-exchanged equilibria. The latter values are analysed in terms of three processes: hydration of ions in solution, hydration of zeolites, and electrostatic binding energy of cations to the zeolite framework.     

Selection rules for bound exciton Auger recombination in semiconductors

We use selection rules developed for Auger-electron spectroscopy to study non-radiative transitions of neutral acceptor bound excitons. We show that (total) angular momentum selection rule implies that excitons originating from the J = 0 and the J = 2 two-hole states have different Auger transition probabilities. The results are shown to be in agreement with photoluminescence experiments.     

Activation of tertiary paraffins by elemental fluorine

Elemental fluroine was found to substitute, in a regio and stereospecific way, tertiary unactivated hydrogens in alkanes - the most unreactive family of organic compounds.     

Mössbauer and magnetization studies of the U1−xNpxO2 fluorites

²³⁷Np Mössbauer effect and magnetic susceptibility measurements of the U_1?Np_xO₂ fluorite solid solution have been performed in the composition range 0.15 ? x ? 0.75. For x = 0.15 and 0.25, the Np ions order magnetically at a lower temperature T₀ than the bulk material (T_N) (T₀ ～ 19 K, T_N ～ 27 K for x = 0.15). For x = 0.50, T₀ ～ 10 K (T_N ～ 12 K from recent neutron diffraction measurements). For x = 0.75, T₀ ～ T_N ～ 9 K. The Np (induced) ordered moment is ～ 0.5 μ_B. The ²³⁷Np Mössbauer isomer shift shows that the Np ions are in a IV charge state.     

Spectrophotometric extractive titrations--V. Theoretical approach to titration of a single cation

The general equation of the titration curve for spectro-photometric extractive titrations is derived. The graphical location of the end-point is assumed and the significance of the general equation is discussed. Simple formulas for threshold pH and for sensitivity are obtained. An increased selectivity of spectrophotometric extractive titrations in comparison with that of the usual spectrophotometric extractive methods is demonstrated.     

The formation of,and the γ-radiation from,the p-shell hypernuclei

The physical factors relevant for the production of various low-lying Λ-hypernuclear states ${}_{\mathrm{\Lambda }}{}^{\mathrm{A}}\text{Z}{}^1$ through the K^? → π^? and K^? → π⁰ reactions, in flight or from rest, on the corresponding target nuclei ^AZ and ^A(Z + 1) are discussed, on the basis of the shell model for these nuclei and hypernuclei, together with the characteristics of the dominant γ-transitions resulting from the excited states thus produced. Detailed consideration is given for a number of hypernuclei of specific interest, including the cases of _Λ⁷He, _ΛLi for A = 7, 9 and 10, _ΛBe for A = 9 and 10, _ΛB for A = 10, 11, and 12, _ΛC for A = 12, 13, 14, and 15, _ΛN for A = 14 and 15, and _Λ¹⁶O. The importance of (γ, π^?) correlation studies for the determination of hypernuclear spin values is stressed, with the discussion of several examples.     

Two-nucleon production of hyperons and the search for strange dibaryons

The double charge exchange reaction³He(K^?,π ⁺)Xn was studied at 870 MeV/c. In the X missing mass range below the sigma-nucleon production threshold (2130 MeV/c²), events were detected which can be attributed to the two-nucleon process pp(K^?,π ⁺)λn. This reaction and mass range also offers good prospects for finding theI=1/2,l=1 (¹ P₁) spin-singlet dibaryon D_s suggested as the lowest massS=?1 dibaryon in the MIT Bag Model. Although the existence of the D_s is not ruled out by the present data, there is no need to invoke such an object to account for the observed events below σ production threshold. We show that the cross section level for these events is compatible with a dominant two-nucleon mechanism K^?p→π ⁰λ,π ⁰p →π ⁺n. We also offer an interpretation of the recent (K^?,K⁺) data on nuclear targets from Iijimaet al., which display a broad peak centered around a K⁺ momentum of 600 MeV/c. We find that the two-nucleon mechanism K^?N →πY,πN→K⁺Y produces cross sections which are at least an order of magnitude smaller than those observed, and we suggest that the one nucleon process K^?p →Φλ, followed by the decayΦ → K⁺K^?, accounts for the data.