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111.
Fausto Elisei Gian Gaetano Aloisi Helmut Görner 《Research on Chemical Intermediates》1995,21(7):725-734
The properties of the triplet state of five styrylphenanthrene (StPh) trans isomers were studied in 2-methyltetrahydrofuran (MTHF) as a function of temperature. At room temperature the T-T absorption was observed only for 4- and 9-StPh, while under these conditions 1-, 2-, and 3-StPh have too low a quantum yield of triplet formation (ΦT <0.02); their T-T absorption spectra were obtained at low temperature. ΦT of 1- and 2-StPh increases more than tenfold on going from 293 to 77 K, and the triplet lifetime (τT) increases by four orders of magnitude and approaches values of 5–40 ms at 77 K. The change in τT is explained in terms of an equilibrium between trans and perpendicular (perp) conformations of the lowest triplet state in fluid solution and temperature and viscosity effects on the trans → perp rotation. Evidence is presented for the existence of two conformeric trans triplet states of 3-StPh at 77 K. Semi-empirical calculations were performed to obtain the energy of the triplet state, the wavelengths of several T-T absorption maxima (λT), and the oscillator strength. The calculated λT values coincide with those measured in n-hexane. 相似文献
112.
Giuseppe Trapani Andrea Latrofa Antonia Reho Massimo Franco Gaetano Liso 《Journal of heterocyclic chemistry》1992,29(5):1155-1159
The title compounds 3a-j together with the N-alkylacylketene S,N-acetals 12a-j were obtained by reaction of N,N'-dialkyldithiodianilines with β-ketoesters compounds. A possible reaction pathway is suggested. 相似文献
113.
Enza Di Gregorio Luciano Lattuada Alessandro Maiocchi Silvio Aime Giuseppe Ferrauto Eliana Gianolio 《Chemical science》2021,12(4):1368
The set-up of reversible binding interactions between the hydrophobic region of macrocyclic GBCAs (Gadolinium Based Contrast Agents) and SO3−/OH containing pyrene derivatives provides new insights for pursuing relaxivity enhancements of this class of MRI contrast agents. The strong binding affinity allows attaining relaxation enhancements up to 50% at pyrene/GBCA ratios of 3 : 1. High resolution NMR spectra of the Yb-HPDO3A/pyrene system fully support the formation of a supramolecular adduct based on the set-up of hydrophobic interactions. The relaxation enhancement may be accounted for in terms of the increase of the molecular reorientation time (τR) and the number of second sphere water molecules. This effect is maintained in blood serum and in vivo, as shown by the enhancement of contrast in T1w-MR images obtained by simultaneous injection of GBCA and pyrene derivatives in mice.The set-up of reversible binding interactions between the hydrophobic region of macrocyclic gadolinium based contrast agents and SO3−/OH containing pyrene derivatives provides new insights for pursuing relaxivity enhancement of MRI contrast agents. 相似文献
114.
Changlun Chen Di Xu Xiaoli Tan Xiangke Wang 《Journal of Radioanalytical and Nuclear Chemistry》2007,273(1):227-233
The fate and transport of toxic metal ions and radionuclides in the environment is generally controlled by sorption reactions.
The extent of sorption of divalent metal cations is controlled by a number of factors including cosorbing or complexing. In
this work, the effects of pH, humic acid HA/Co(II) addition orders, ionic strength, concentration of HA, and foreign cations
on the Co(II) sorption on γ-Al2O3 in the presence of HA were investigated. The sorption isotherms of Co(II) on γ-Al2O3 in the absence and presence HA were also studied and described by using S-type sorption model. The experimental results showed
that the Co(II) sorption is strongly dependent on the pH values, concentration of HA, but independent of HA/Co(II) addition
orders, ionic strength, and foreign cations in the presence of HA under our experimental conditions. The results also indicated
that HA enhanced the Co(II) sorption at low pH, but reduced the Co(II) sorption at high pH. It was hypothesized that the significantly
positive influence of HA at low pH on the Co(II) sorption on γ-Al2O3 was attributed to strong surface binding of HA on γ-Al2O3 and subsequently the formation of ternary surface complexes such as ≡S-OOC-R-(COO−)
x
Co2−x
. Chemi-complexation may be the main mechanism of the Co(II) sorption on γ-Al2O3 in the presence of HA. 相似文献
115.
Pietro Schenone Alberto Bargagna Gaetano Bignardi Filippo Evangelisti 《Journal of heterocyclic chemistry》1976,13(5):1105-1107
The reaction of 2-carbonyl-1,3-dithiane, a sulfene prepared in situ from 2-chloroearbonyl-1,3-dithiane and triethylamine, with N,N-disubstituted 2-aminomethylvnecycloalkanones gave the 1,4-cycloadducts, namely N,N-disubstituted 4′-aminospiro[1,3-dithiane-2,3′-(5′,6′-poly-methylene-3′,4′-dihydro-α-pyrones)]. 相似文献
116.
Antonino Arcoria Emanuele Maccarone Gaetano A. Tomaselli Rosario Calí Salvatore Currieri 《Journal of heterocyclic chemistry》1975,12(2):333-335
The second order rate constants k2 and the activation parameters for the reaction of 2-thiophenesulfonyl chloride with aniline together with solution enthalpies of the reactants have been measured in methanol, ethanol, 2-propanol, acetonitrile and acetone. The reaction rates are slower in dipolar aprotic solvents than in protic ones due to a remarkable activation negative entropy. The rate constants k2 are correlated with empirical solvent polarity parameters. The data seem in accord with a SAN reaction mechanism. 相似文献
117.
本文研究滚装码头混合泊位分配和劳动力分配的联合调度优化问题。首先,考虑潮汐时间窗约束、装卸劳动力约束、泊位缆桩分布约束以及泊位不规则布局因素,建立以最小化船舶总服务时间为目标的混合整数规划模型。其次,采用内外嵌套算法设计策略,提出求解该类问题的组合算法。其中,外层是多种群并行进化的遗传算法,生成多种船舶计划顺序,内层为基于规则的启发式算法,用于计算给定计划顺序的目标函数值。然后,基于实际运营数据,生成多组不同规模的算例进行全面数值实验,结果表明所提出的算法可在10分钟内求解包含50艘船、100个泊段的算例。最后,开展基于真实滚装码头运营实例的案例分析,对所提模型和算法在实际码头调度问题中的适用性与高效性进行验证。 相似文献
118.
119.
In this paper we study a variable coefficient Sine-Gordon (vSG) equation given by theta(tt)-theta(xx)+F(x,t)sin theta=0 where F(x,t) is a real function. To establish if it may be integrable we have performed the standard test of Weiss, Tabor, and Carnevale (WTC). We have got that the (vSG) equation has the Painleve' property (Pp) if the function F(x,t) satisfies a well-defined nonlinear partial differential equation. We have found the general solution of this last equation and, consequently, the functions F(x,t) such that the (vSG) equation possesses the (Pp), are given by F(x,t)=F(1)(x+t)F(2)(x-t) where F(1)(x+t) and F(2)(x-t) are arbitrary functions. Using this last result we have obtained some particular solutions of the vSG equation. (c) 1995 American Institute of Physics. 相似文献
120.
M. Giaquinta G. Modica J. Souček 《Calculus of Variations and Partial Differential Equations》1994,2(1):65-100
On the ground of four axioms we define thekinematics of perfectly elastic bodies and in particular the notion ofweak deformations of a perfectly elastic body. Weak deformations turn out to agree withweak diffeomorphisms introduced in [10], a class of rectifiable currents which enjoys good closure and compactness properties. Defining thedynamics of perfectly elastic bodies in terms of twoconstitutive conditions on the stored energy function, we can therefore prove existence of stable equilibrium weak deformations for mixed boundary value problems, which moreover satisfy equilibrium and conservation equations.This work has been partially supported by the Ministero dell'Universitá e della Ricerca Scientifica, by C.N.R. contract n. 91.01343.CT01, by the European Research Project GADGET, and by Grant n.11957 of the zech Acad. of Sciences.This article was processed by the author using the LaTEX style filepljour1 from Springer-Verlag. 相似文献