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991.
Tapati Mallik Tanusree Kar Gabriele Bocelli Amos Musatti 《Crystal Research and Technology》2006,41(3):280-284
Crystal structure and thermal stability of the hydrated crystals of the basic amino acid L‐arginine named as L‐arginine dihydrate (LAD), a nonlinear optical material have been reported here. The title compound crystallized in the space group P212121 with Z=4 and unit cell dimensions a=11.856(2)Å, b=15.694(2)Å, c=5.664(3)Å. The arginine molecule is a zwitterion with the guanidyl group accepting an extra proton from the carboxylate group. DTA‐TG analysis gives an idea about the thermal behaviour of LAD and ruled out the possibility of structural changes independent of mass changes. © 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 相似文献
992.
Gabriele Eichfelder 《Mathematical Programming》2010,123(2):419-449
In this work nonlinear non-convex multiobjective bilevel optimization problems are discussed using an optimistic approach.
It is shown that the set of feasible points of the upper level function, the so-called induced set, can be expressed as the
set of minimal solutions of a multiobjective optimization problem. This artificial problem is solved by using a scalarization
approach by Pascoletti and Serafini combined with an adaptive parameter control based on sensitivity results for this problem.
The bilevel optimization problem is then solved by an iterative process using again sensitivity theorems for exploring the
induced set and the whole efficient set is approximated. For the case of bicriteria optimization problems on both levels and
for a one dimensional upper level variable, an algorithm is presented for the first time and applied to two problems: a theoretical
example and a problem arising in applications. 相似文献
993.
De Salvador D Napolitani E Mirabella S Bisognin G Impellizzeri G Carnera A Priolo F 《Physical review letters》2006,97(25):255902
B diffuses in crystalline Si by reacting with a Si self-interstitial (I) with a frequency g and so forming a fast migrating BI complex that can migrate for an average length lambda. We experimentally demonstrate that both g and lambda strongly depend on the free hole concentration p. At low p, g has a constant trend and lambda increases with p, while at high p, g has a superlinear trend and lambda decreases with p. This demonstrates that BI forms in the two regimes by interaction with neutral and double positive I, respectively, and its charge state has to change by interaction with free holes before diffusing. 相似文献
994.
Stefanie Poggendorf Gernique Adama Mba Dirk Engel Gabriele Sadowski 《Colloid and polymer science》2011,289(5-6):545-559
The diffusion behavior of poly(ethylene glycol) (PEG) in N-isopropylacrylamide (NIPAAm) hydrogels was investigated using confocal Raman spectroscopy with regard to temperature (25°C, 30°C and 35°C), PEG concentration (10 and 40?wt.%), PEG molecular weight (2,000 and 12,000?g/mol) and addition of the compatible solute ectoine (0.1 and 2?wt.%). Swelling and shrinking of the gels was observed by means of confocal Raman spectroscopy. The swelling behavior of NIPAAm gels in aqueous solutions of PEG and ectoine was found to resemble the swelling behavior in pure water with regard to temperature, i.e., the gel shrinks with increasing temperature. However, the presence and concentration of PEG and ectoine influence the swelling behavior by lowering the volume phase-transition temperature of the gel and facilitating shrinking. In some cases, a re-swelling of the gel was observed after the initial shrinking at the onset of PEG diffusion, which can be explained by PEG changing the chemical potential in the gel phase as it diffuses into the sample allowing the water to re-enter. The expulsion of water from the gel during shrinking and the so-caused increase of PNIPAAm and PEG concentrations in some cases led to the PEG diffusion seemingly being faster in more shrunken gels despite of their higher diffusion resistance. 相似文献
995.
996.
Cover Picture: Ultrafast Charge‐Transfer Reactions of Indoline Dyes with Anchoring Alkyl Chains of Varying Length in Mesoporous ZnO Solar Cells (ChemPhysChem 5/2015) 下载免费PDF全文
997.
Simona Quartieri Gabriele Montagna Giovanna Vezzalini 《Journal of solid state chemistry》2011,184(6):1505-1516
The elastic behavior of H-ZSM-5 was investigated by in-situ synchrotron X-ray powder diffraction, using both silicone oil (s.o.) and (16:3:1) methanol:ethanol:water (m.e.w.) as “non-penetrating” and “penetrating” pressure transmitting media, respectively. From Pamb to 6.2 GPa the volume reduction observed in s.o. is 16.6%. This testifies that H-ZSM-5 is one of the most flexible microporous materials up to now compressed in s.o. Volume reduction observed in m.e.w. up to 7.6 GPa is 14.6%. A strong increase in the total electron number of the extraframework system, due to the penetration of water/alcohol molecules in the pores, is observed in m.e.w. This effect is the largest up to now observed in zeolites undergoing this phenomenon without cell volume expansion. The higher compressibility in s.o. than in m.e.w. can be ascribed to the penetration of the extra-water/alcohol molecules, which stiffen the structure and contrast the channel deformations. 相似文献
998.
Jørgen M. Mollerup Martin P. BreilChristina Vogelpohl Gabriele Sadowski 《Fluid Phase Equilibria》2011,301(2):163-170
The chromatographic retention in hydrophobic and reversed phase chromatography and the solubility of proteins display some common features. The chromatographic retention, as well as the solubility, is modulated by the thermodynamic properties of the solute in the fluid phase. The retention measurements at linear conditions provide information of the solution properties of the protein at infinite dilution, and the solubility measurements produce the supplementary information about the solution properties at the saturation limit. This provides a useful approach to simultaneous correlation of the chromatographic retention and the solubility.The experimental data, used for the correlation, comprise retention measurements of lysozyme on different HIC adsorbents using an aqueous ammonium sulphate eluant, an aqueous ammonium sulphate eluant with an admixture of ethanol, as well as published solubility data.The chromatographic retention data and the corresponding solubility data have been correlated using a chemical potential model derived from Kirkwood's theory of solutions of charged macro-ions and zwitterions in electrolyte solutions. The model correlated the chromatographic retention factor and the solubility data within the precision of the measurements. The model was applied in a pH range from 4 to 11. It was demonstrated experimentally, as well as theoretically, that an admixture of ethanol to the aqueous eluant changes the thermodynamic retention factor on various adsorbents identically when compared to the thermodynamic retention factor in an ethanol free eluant. 相似文献
999.
1000.