Investigation of the compatibility between kaempferol and excipients by thermal,spectroscopic and chemometric methods

Journal of Thermal Analysis and Calorimetry - Compatibility is an important step in pre-formulation studies during the development of solid dosage forms. In the present study, we used thermal...     

Silver doping in lanthanum manganite materials: structural and electrical properties

Journal of Thermal Analysis and Calorimetry - Porous media are very useful tools used for energy management. They are used in vast fields such as in solar heat exchangers to enhance heat transfer...     

PageRank centrality for performance prediction: the impact of the local optima network model

A local optima network (LON) compresses relevant features of fitness landscapes in a complex network, where nodes are local optima and edges represent transition probabilities between different basins of attraction. Previous work has found that the PageRank centrality of local optima can be used to predict the success rate and average fitness achieved by local search based metaheuristics. Results are available for LONs where edges describe either basin transition probabilities or escape edges. This paper studies the interplay between the type of LON edges and the ability of the PageRank centrality for the resulting LON to predict the performance of local search based metaheuristics. It finds that LONs are stochastic models of the search heuristic. Thus, to achieve an accurate prediction, the definition of the LON edges must properly reflect the type of diversification steps used in the metaheuristic. LONs with edges representing basin transition probabilities capture well the diversification mechanism of simulated annealing which sometimes also accepts worse solutions that allow the search process to pass between basins. In contrast, LONs with escape edges capture well the diversification step of iterated local search, which escapes from local optima by applying a larger perturbation step.     

Adsorption of Lanthanide(III) Cations on Cross-Linked Ionic Polymer,Composition and Thermal Analysis of the Formed Composites

Colloid Journal - The adsorption of lanthanide(III) cations by a strongly basic cross-linked polymer containing R4N+ groups was studied at 21 and 50°C. At both temperatures the sorption is...     

Solid-state stability and kinetic study of three glucocorticoid hormones: prednisolone,prednisone and cortisone

Journal of Thermal Analysis and Calorimetry - In the class of steroid hormones, glucocorticoids are belonging to the subclass of corticosteroids, consisting of numerous synthetic or naturally...     

Minerals in Pregnancy and Their Impact on Child Growth and Development

During pregnancy, women undergo metabolic and physiological changes, and their needs are higher, to maintain growth and development of the fetus. If the nutritional status of the expectant mother is not satisfactory, some maternal and neonatal complications can occur. In the second and third trimester of pregnancy, there is a reserve of nutrients in the fetus that can be utilized after birth; thereby, children present an accelerated growth in the first years of life, which is a proven response to the available nutrition pattern. However, if such a pattern is insufficient, there will be deficits during development, including brain function. Therefore, despite many recent published works about gestational nutrition, uncertainties still remain on the mechanisms of absorption, distribution, and excretion of micronutrients. Further elucidation is needed to better understand the impacts caused either by deficiency or excess of some micronutrients. Thus, to illustrate the contributions of minerals during prenatal development and in children, iodine, selenium, iron, zinc, calcium, and magnesium were selected. Our study sought to review the consequences related to gestational deficiency of the referred minerals and their impact on growth and development in children born from mothers with such deficiencies     

Enrique San Román (1945–2019)

An homage to the Argentinian Photochemist Enrique San Román is presented. Enrique led the Photochemistry and Chemical Kinetics research group in the Department of Inorganic, Analytical and Physical Chemistry in the Faculty of Exact and Natural Sciences of the University of Buenos Aires from 1984 until his death in July 2019. He left a strong legacy in Chemical Kinetics and Photochemistry in Argentina. He is remembered as a meticulous and very knowledgeable scientist and teacher, a loyal friend and a generous and integer human being.