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121.
Gabriela Ciuperca 《Statistics & probability letters》2011,81(8):1267-1275
A general criterion is proposed to determine the number K of the change-points in a parametric nonlinear multi-response model. Schwarz criterion is a particular case. The change-points depend on regressor values and not on instant of measure. We prove that the proposed estimator for K is consistent. Simulation results, using Monte Carlo technique, for nonlinear models which have numerous applications, support the relevance of the theory. 相似文献
122.
Density, self-diffusion coefficient, and shear viscosity of pure liquid water are predicted for temperatures between 280 and 373 K by molecular dynamics simulation and the Green-Kubo method. Four different rigid nonpolarizable water models are assessed: SPC, SPC/E, TIP4P, and TIP4P/2005. The pressure dependence of the self-diffusion coefficient and the shear viscosity for pure liquid water is also calculated and the anomalous behavior of these properties is qualitatively well predicted. Furthermore, transport properties as well as excess volume and excess enthalpy of aqueous binary mixtures containing methanol or ethanol, based on the SPC/E and TIP4P/2005 water models, are calculated. Under the tested conditions, the TIP4P/2005 model gives the best quantitative and qualitative agreement with experiments for the regarded transport properties. The deviations from experimental data are of 5% to 15% for pure liquid water and 5% to 20% for the water + alcohol mixtures. Moreover, the center of mass power spectrum of water as well as the investigated mixtures are analyzed and the hydrogen-bonding structure is discussed for different states. 相似文献
123.
124.
Iulian Rusu Daniel Sutiman Gabriela Lisa Daniel Mareci Nicoleta Melniciuc Puică 《Journal of Thermal Analysis and Calorimetry》2011,104(2):423-430
The aim of this study was to investigate the effects of immersion time on the electrochemical corrosion behaviour of three
brass alloys (CuZn) coming from religious artefacts in simulated acid rain at 25 °C, utilising the electrochemical impedance
spectroscopy (EIS). The main parameters of the corrosion process were established. On the other hand, the alloys were also
analysed by means DSC and TG/DTA before and after immersion in the corrosive environment. Finally, the obtained results were
compared in order to correlate them with each other and with the corrosion process. 相似文献
125.
126.
Giuseppe Mele Roberta del Sole Giuseppe Vasapollo Elisa García-López Leonardo Palmisano Li Jun Rudolf Słota Gabriela Dyrda 《Research on Chemical Intermediates》2007,33(3-5):433-448
Photodegradation of organic compounds in water solutions by means of economically advantageous and environment-friendly processes is a topic of growing interest. In recent years a great attention has been devoted to TiO2-based photocatalysts for the oxidative degradation of various organic pollutants. In this context, we have prepared new photo-catalytic polycrystalline TiO2 systems impregnated with sensitizers, i.e., copper, iron or manganese porphyrins, and investigated their photoactivity for 4-nitrophenol oxidation compared with that of bare TiO2. A significant improvement of the photoreactivity was observed in the case of TiO2 impregnated with copper porphyrin, while only a slight beneficial effect was observed in the case of iron porphyrin. In contrast, the presence of manganese porphyrin appeared to be detrimental. 相似文献
127.
The electronic and energetic properties of bimetallic surfaces Pt/Ni(111) and Pt/Co(111) are examined using the FP-LAPW (Full-PotentialLinearized Augmented Plane Wave) method by means of spin-polarized and non-polarized calculations. We present both the results of the shifts in the d-band centers when one metal (Pt) is pseudomorfically deposited on another with smaller lattice constant (Ni, Co) and those corresponding to the surface and adhesion energies. The surface is modeled by a seven layer slab separated in z direction by a vacuum region of six substrate layers. The results obtained for pure Ni, Co and Pt surfaces are presented in order to compare with experimental and theoretical data reported in the literature 相似文献
128.
Gabriela R. Argiroffo Silvia M. Bianchi Graciela L. Nasini 《Mathematical Methods of Operations Research》2008,67(2):245-256
Lehman (Polyhedral combinatorics 1 of DIMACS series in discrete math. and theoretical computer science, pp 101–105, 1990) described some conditions regular
minimally nonideal (mni) matrices must satisfy. Although, there are few results on sufficient conditions for mni matrices.
In most of these results, the covering polyhedron must have a unique fractional extreme point. This condition corresponds
to ask the matrix to be the blocker of a near-ideal matrix, defined by the authors in a previous work (2006). In this paper
we prove that, having the blocker of a near-ideal matrix, only a few very easy conditions have to be checked in order to decide
if the matrix is regular mni. In doing so, we define the class of quasi mni matrices, containing regular mni matrices, and
we find a generalization on the number of integer extreme points adjacent to the fractional extreme point in the covering
polyhedron. We also give a relationship between the covering and stability number of regular mni matrices which allows to
prove when a regular mni matrix can be a proper minor of a quasi mni.
Partially supported by CONICET Grant PIP 2807/2000 (Argentina) and by CNPq/PROSUL Grant 490333/2004-4 (Brasil). 相似文献
129.
Letf(z, t) be a subordination chain fort ∈ [0, α], α>0, on the Euclidean unit ballB inC
n. Assume thatf(z) =f(z, 0) is quasiconformal. In this paper, we give a sufficient condition forf to be extendible to a quasiconformal homeomorphism on a neighbourhood of
. We also show that, under this condition,f can be extended to a quasiconformal homeomorphism of
onto itself and give some applications.
Partially supported by Grant-in-Aid for Scientific Research (C) no. 14540195 from Japan Society for the Promotion of Science,
2004. 相似文献
130.
A density functional theory (DFT) study aimed at understanding structure–reactivity relationships in the oxidized metabolites of cyclopenta‐fused polycyclic aromatic hydrocarbons (CP‐PAHs) is reported. Epoxidation at various positions was examined in order to identify the most stable epoxide in each class of CP‐PAHs. Relative energies of the carbocations resulting from O‐protonation and epoxide ring opening were analyzed and compared, taking into account the available biological activity data on these compounds. Geometrical, electronic, and conformational issues were considered. Charge delocalization modes in the resulting carbocations were deduced via the natural population analysis (NPA)‐derived changes in charges. Computational results pointed to the importance of the unsaturated cyclopenta ring on the reactivity of these compounds. The reported bioactivity of this highly mutagenic/carcinogenic family of PAHs was observed to parallel their relative carbocation stabilities. A different behavior was observed in crowded non‐planar structures possessing a distorted aromatic system. A covalent adduct formed between a CP‐PAH epoxide and a purine base was computed inside a DNA fragment employing the ONIOM method. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献