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91.
In this work preliminary results of amorphous zirconium crystallization using ion beam pulses are presented. Energetic argon- and oxygen-ion beams generated by a plasma focus device were used to promote crystallization on amorphous ZrO2-2.5 mol% Y2O3 film deposited by chemical solution deposition onto silica glass substrate. The films were burnt at 370 °C for 1 h in normal atmosphere previous to plasma irradiation. The irradiation was performed by means of successive pulses of ion beams. The evolution of the surface morphology and crystallization was followed by AFM and X-rays diffraction in a grazing incidence asymmetric Bragg geometry (GIAB), respectively. Argon-irradiated films showed highly nucleated cubic zirconia after 10 pulses. On the other hand, oxygen-irradiated films showed a delayed and less extensive cubic nucleation, but a more ordered structure and well-defined grains. 相似文献
92.
This work presents a formulation based on UPML for truncating conductive media by using a local and non-orthogonal coordinate
system to solve Maxwell’s equations by the FDTD method. The detailed procedure for obtaining the UPML equations for this case
is shown and the complete equation set is provided. 相似文献
93.
The Generalized Order Complementarity Problem studied by Isac and Kostreva is extended to multivalued mappings satisfying a condition proposed by Kneser. Existence of solutions to a related fixed point problem leads to existence theory for the new type of complementarity problem. Some important applications include problems in lubrication and in economics in which functions are set valued. 相似文献
94.
95.
D. Hugh Powell Andr E. Merbach Gabriel Gonzlez Ern Brücher Kroly Micskei M. Francesca Ottaviani Klaus Khler Alex Von Zelewsky Oleg Ya. Grinberg Yakob S. Lebedev 《Helvetica chimica acta》1993,76(5):2129-2146
EPR Spectra have been measured for aqueous solutions of a series of Gd3+ complexes at variable temperature and a range of magnetic fields; S-band (0.14 T), X-band (0.34 T), Q-band (1.2 T), and 2-mm-band (5.0 T). The major contribution to the observed line widths is magnetic-field-dependent and is interpreted as being due to the modulation of the zero-field splitting produced by distortion of the complexes from perfect symmetry. The transverse and longitudinal relaxation matrices for an 8S ion with such an interaction have been calculated using Redfield theory with vector-coupling methods, and diagonalised numerically to obtain relaxation rates and intensities for the degenerate transitions which contribute to the multiplet. The observed line width, which is inversely proportional to the magnetic field at low temperatures, is best described by the intensity-weighted mean transverse relaxation time for the four transitions with non-zero intensity. A least-squares fit of the data yields the square of the zero-field splitting tensor, Δ2, and a correlation time, τv, with activation energy, Ev. The physical significance of these parameters and the extent of validity of the theoretical approach are considered. The parameters are used to predict the magnetic-field dependence of the longitudinal and transverse electronic relaxation times, which are discussed in the context of their relevance to 1H-NMR relaxivity. 相似文献
96.
D. Kast A. Jungclaus K.P. Lieb M. Górska G. de Angelis P.G. Bizzeti A. Dewald C. Fahlander H. Grawe R. Peusquens M. De Poli H. Tiesler 《The European Physical Journal A - Hadrons and Nuclei》1998,3(2):115-128
In the neutron deficient isotopes 104,105In lifetimes of high spin states in the range from 0.5 ps to 600 ps have been measured in a coincidence recoil distance Doppler
shift (RDDS) experiment. By combining the Doppler shift attenuation (DSA) and RDDS methods at few μm flight distances, the
problem of delayed feeding has been avoided and very short lifetimes in the range 0.5–0.8 ps have been determined. Shell model
calculations with strong restrictions for the neutron orbitals reveal good agreement with experimental level energies and
still fair agreement for most measured B(M1) and B(E2) values.
Received: 30 June 1998 相似文献
97.
98.
This contribution discusses the phenomena of retrograde condensation of one or two liquids. It w1 be shown that both phenomena can be well understood. Also the relation of retrograde condensation of one liquid phase with the condensation behavior of natural gas will be discussed. Similarly that of two liquid phases with multiple phase behavior occurring in low temperature reservoir fluids will be pointed out. 相似文献
99.
J. H. de Araújo J. B. M. da Cunha A. Vasquez L. Amaral J. T. Moro F. C. Montenegro S. M. Rezende M. D. Coutinho Filho 《Hyperfine Interactions》1991,67(1-4):507-511
57Fe Mössbauer effect measurements in the diluted Ising antiferromagnet Fe x Zn1?x F2 withx=0.25 andx=0.57 at temperatures between 4.2 and 55 K, are reported. DC suceptibility measurements show a spin-glass (SG) phase at low temperatures forx≤0.31. Our Mössbauer spectra show a phase transition to a SG state with antiferromagnetic order (AFSG) forx=0.25 and only antiferromagnetic order forx=0.57. 相似文献
100.
P. A. J. van den Bogert R. de Borst 《Archive of Applied Mechanics (Ingenieur Archiv)》1994,64(2):136-146
Summary The mechanical behaviour of rubberlike materials is modelled in a phenomenological approach using a strain-energy formulation. Nonhomogeneous shear experiments on solid rubber specimens have been carried out as well as simple elongation tests on the same rubber compound. The elongation tests have been used to determine the model constants. By a comparison between experiment and numerical simulation of the nonhomogeneous shear test the predictive capabilities of the Mooney-Rivlin, the Ogden and the Besseling model have been assessed for compression-shear deformation paths. An analytical study explains the numerically observed behaviour.
Über das Verhalten von Gummimaterialien unter Druck und Schubverformungen
Übersicht Das mechanische Verhalten von Gummimaterialien wird phänomenologisch modelliert unter Anwendung einer Formänderungsenergiefunktion. Es sind nicht-homogene Schubversuche auf dreidimensionale Versuchsproben aus Gummi so wie auch einfache Verlängerungsversuche auf Gummiproben der gleichen Zusammenstellung durchgeführt worden. Die Verlängerungsversuche sind durchgeführt worden um die Stoffkennwerte feststellen zu können. In einer Vergleichung zwischen dem Experiment und der numerischen Simulation von nicht-homogenen Schubversuchen ist die Genauigkeit des Mooney-Rivlinschen Modells, des Ogdenschen Modells und des Besselingschen Modells für kombinierte Druck-Schubverformungen festgestellt worden. In einem analytischen Studium wird das numerisch betrachtete Verhalten auseinandergesetzt.相似文献