Electronic Structure and Magnetic Properties of SmCo7-xZrx

The electronic structure and magnetism of SmCo_7-xZr_x alloy are investigated using the spin-polarized MS-X. method. The results show that a few of electrons are transferred to the Sm(5d⁰) orbital due to orbital hybridization between Sm and Co atoms. The exchange interactions between 3d and 5d electrons are more important than the polarization effects of the conductive electrons, thus it is the main reason resulting in the long-range ferromagnetic order in SmCo_7-xZr_x. The Curie temperature of SmCo_7-xZr_x is generally lower than that of corresponding pure Co, which may be explained by the weaker average coupling strength between Co lattices due to some negative couplings mainly occurring of 2e site. The calculated results for the Sm₅Co₃₂Zr₂ cluster may lead to a better understanding of why SmCo_7-xZr_x is stable phase. Since the spin-up DOS peak of d electrons at E_F arises and the bonding of electrons at E_F strengthens with increasing Zr concentration, which results in the internal energy of the system decrease, the stable ferromagnetic order forms in SmCo_7-xZr_x.     

陆生植物黑麦草(Lolium multiflorum)对富营养化水体修复的围隔实验研究——氨氮的净化效应及其动态过程

采用浮床黑麦草（Lolium multi florum）对畜禽养殖富营养水体氨氮的净化效应及动态过程进行了研究．结果表明：浮床黑麦草对富营养水体中的氨氮具有明显的净化效果．当覆盖率30％时，对氨氮的去除率最高可达到95．89％．对其去除水体氨氮的动态过程拟合表明符合三次方程曲线．该研究为冬季陆生植物修复富营养水体提供重要依据．     

Syntheses and Vasodilatory Activities of New Pyrazolo [ 4,3-d ] pyrimidin-7-ones

IntroductionAdenosine 3′,5′-cyclic monophosphate (cAMP)and guanosine 3′,5′-cyclic monophosphate(cGMP) areubiquitous second messengers that mediate biologicalresponses to a variety of extracellular cues, includinghormones, neurotransmitters, chemokines…     

自集成透镜InGaAsP／InPDHLED及其离子束铣技术

本文报道在国内首次采用离子束铣技术研制自集成透镜InGaAsP/InP DH LED的实验结果。采用烘烤正性光致抗蚀剂来形成球状掩膜适合于离子束铣,且重复性很好。为了获得光洁的刻蚀表面,刻蚀条件均已最优化。     

合肥光源二分割三角型光位置检测器的研制

介绍了一种用于合肥光源的二分割三角型光位置检测器的研制,对其主要性能(如灵敏度和线性范围)进行了理论分析和实际测量,测量结果与理论分析相当吻合.文中还给出了光位置测量系统的组成     

Reaction Mechanism Investigation Using Vibrational Mode Analysis for the Multichannel Reaction of CH_3O+CO

ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｍｅｔｈｏｘｙｒａｄｉｃａｌ (ＣＨ3Ｏ)ｉｓａｎｉｍｐｏｒｔａｎｔｉｎｔｅｒ ｍｅｄｉａｔｅｉｎｔｈｅｐｈｏｔｏｃｈｅｍｉｃａｌｏｘｉｄａｔｉｏｎｏｆｈｙｄｒｏｃａｒｂｏｎｓｉｎｔｈｅａｔｍｏｓｐｈｅｒｅ ,1 3ａｎｄｐｌａｙｓａｓｉｇｎｉｆｉｃａｎｔｒｏｌｅｉｎｔｒａｎｓ ｆｏｒｍｉｎｇｎｉｔｒｉｃｏｘｉｄｅｔｏｎｉｔｒｏｇｅｎｄｉｏｘｉｄｅ .4 Ｓｉｍｉｌａｒｌｙ ,ｔｈｅｒｅａｃｔｉｏｎｍｅｃｈａｎｉｓｍｓｏｆｈｙｄｒｏｘｙｌａｎｄｃａｒｂｏｎｍｏｎｏｘｉｄｅ5,6ａｎｄｏ…     

管肋式辐射器排热特性的数值分析与优化设计

为得到按单面辐射方式布置的管肋式空间辐射器的排热特性，建立了相应的数学模型．采用数值模拟方法分析了管内流体温度、肋片几何尺寸和等效热沉温度对辐射器排热特性的影响，得到了不同参数值下辐射器单位面积排热量以及特定参数范围内的辐射器肋片最佳宽度和肋片效率．数值模拟结果对辐射器的工程结构设计以及空间站热管理方案的优化分析具有一定的参考价值．     

Szász型算子线性组合的同时逼近

本文利用ω^2r_φλ(f,t)代替ω^r_φλ(f,t)给出了Szász-Kantorovich算子线性组合同时逼近的估计。     

S波Kπ散射以及动力学产生标量介子

考虑Kπ和Kη两个耦合道, 用手征幺正方法研究了S波Kπ散射. 结果表明, 只用一个参数, 1.2GeV以下的散射相移数据就可以得到很好的描述, 并且散射长度也和实验值符合很好. 此方法可以动力学产生标量介子κ, 并预言其质量和宽度分别大约是752MeV和594MeV. 可以定性地产生对应于K^*₀(1430)的标量介子.     

Electrocatalytic activity of ordered intermetallic PtSb for methanol electro-oxidation

Ordered intermetallic PtSb had been synthesized by arc-melted and then sintering treatment. The electro-oxidation of liquid methanol on PtSb was investigated at room temperature by cyclic voltammetry and chronoamperometry. The results are compared to those at a polycrystalline platinum electrode surface. It was found that PtSb intermetallic was catalytically more active than pure platinum according to the onset potential and current density. X-ray diffraction (XRD) and XPS technologies had been used to investigate the crystal structure and electron effect.