氢化物的气相富集及其在超痕量分析中的应用

本文从富集原理及其在光谱超痕量分析的应用方面分别对这几种氢化物发生后的气相富集技术进行了较详细地综述.这些气相富集方法包括液氮冷却捕集技术、气球收集技术、石墨炉原位捕集技术、吸收液吸收技术及固体吸附技术等.并对这些氢化物气相富集技术的潜力,及与各种光谱分析法联用的发展前景也进行了讨论.     

Control of the Rendition Wavelength Shifts of Color Lippmann Holograms Recordedin Single-layer panchromatic Silver-halide Emulsion

1 Introductionther hologratns can be used for artWork fabrication, product advertisement,museum item presentation, etc., and have wide applicationS in the world of businessand everyday life. To be able to record high-quality color reflection holograrns, it isnecessary to use extremely low scattering recording materials, for example, the use ofultra-high resolution silver-halide emulsions. Russian PFG-03C panchromatic silverhallde Plate is such a recording material, which has some excellent c…     

Hyperpolarizabilities of Chelidamic Acid Complexes M_m(C_7H_3O_5N)_n (M=Cu, Ag): Theoretical Analysis

The frequency‐dependent hyperpolarizabilities of chelidamic acid complexes M_m(C₇H₃O₅N)_n (M?Cu, Ag) were investigated under the time dependent density functional theory (TDDFT) combined with the sum‐over‐states method (SOS). The relationship between molecular orbitals and nonlinear optical (NLO) properties has been explored. The results show that the charge transitions of π‐π* and 3d_M‐π* are very important to the second‐order polarizabilities, and the largest component of dynamic β is 3.84×10^?25 cm⁵·esu^?1 at 0.74 eV for Ag₂Cu₂(C₇H₃O₅N)₄. The charge transition between π‐π* is also highly crucial to the third‐order polarizabilities, and the largest component of dynamic γ is ?4.46×10^?29 esu at 0.50 eV for Ag₂Cu₂(C₇H₃O₅N)₄. The central Cu ion, as electron bridge, extends the range of delocalization and leads to an interesting phenomenon of spiroconjugation.     

Site-specifically Hydrolytic Cleavage of Oxidized Insulin B Chain With Cu(II) Ion

Selectively chemical cleavage of peptides and proteins is one of the most important reactions in both chemical and biochemical processes. Over the past decade, the interaction of palladium(II) complexes with methionine, cysteine and histidine-containing peptides and proteins and the hydrolytic cleavage of the corresponding amide bond by Pd(II) complexes have been extensively studied1-13. However, reports concerning the directly selective hydrolysis of peptides and proteins with other simple …     

复Fuzzy数列的度量收敛与水平收敛

研究复Ｆｕｚｚｙ数列科技的收敛性，讨论复Ｆｕｚｚｙ数列度量收敛与水平收敛的等价性问题。为复Ｆｕｚｚｙ分析的进一上研究打下良好的基础。     

微柱高效液相色谱与火焰光度检测器联用的初步研究

本文研究了常规高效液相色谱(HPLC)及微柱高效液相色谱(Micro-Column HPLC)与气相色谱火焰光度检测器(FPD)的联用技术及其应用.丁基锡等化合物经HPLC分离后,流出液通过FPD进行特效检测.接口采用将毛细管直接引入燃烧头的方式.文中对各有关参数进行了选择、优化和讨论, 对FPD作为HPLC的在线检测器的可能性作了初步探讨.     

Krichever-Novikov弦的BRST量子化及拟自由弦场论

在Krichever-Novikov(简称KN)弦的BRST量子化的基础上,采用Siegel的方法构造了任意给定亏格的KN弦的拟自由场论,并提出了一种非微扰拟自由弦场论的尝试。 关键词：     

Ni-Zr非晶合金晶化的透射电子显微镜研究(Ⅰ) ——Ni67Zr33晶化过程中的亚稳相

利用透射电子显微镜对Ni₆₇Zr₃₃非晶合金晶化的研究发现了两个新的亚稳相T₀与T₁0。其中T₁相为体心正交(准四方〕晶体,点阵常数a≌b=0.89nm,c=3.14nm,空间群为Iba2或Ibam。温度升高,T₁相转变为含有大量错排的A心正交Ni₁₀Zr₂相,用1/2(a+b)位移错排模型可以圆满地解释其电子衍射图中仅h+k为奇数的衍射斑沿c^*方向拉长的现象,晶化稳定相为Ni₁₀Zr,与Ni₂₁Zr₈(Ni₅Zr₂)相。 关键词：     

具有弱正规幂等元的rpp半群的结构

研究一类特殊的rpp半群，即含弱正规幂等元的rpp半群。作者首先给出了这类半群的若干特征，然后通过右正规带和具有某些相应性质的rpp半群建立了具有弱正规幂等元的rpp半群的结构。把郭小江在富足半群上得到的结果进行了很好的推广和发展。另外，（弱）正规幂等元与目前颇受重视的另一个概念一适当断面（adequatetransversal）有着密切的联系。自然，开展具有弱正规幂等元的各种半群的研究是有意义的。