全文获取类型
收费全文 | 4810篇 |
免费 | 1042篇 |
国内免费 | 1575篇 |
专业分类
化学 | 3562篇 |
晶体学 | 187篇 |
力学 | 324篇 |
综合类 | 138篇 |
数学 | 750篇 |
物理学 | 2466篇 |
出版年
2024年 | 11篇 |
2023年 | 31篇 |
2022年 | 150篇 |
2021年 | 134篇 |
2020年 | 145篇 |
2019年 | 130篇 |
2018年 | 149篇 |
2017年 | 214篇 |
2016年 | 169篇 |
2015年 | 236篇 |
2014年 | 285篇 |
2013年 | 391篇 |
2012年 | 358篇 |
2011年 | 357篇 |
2010年 | 347篇 |
2009年 | 378篇 |
2008年 | 481篇 |
2007年 | 408篇 |
2006年 | 426篇 |
2005年 | 400篇 |
2004年 | 299篇 |
2003年 | 232篇 |
2002年 | 260篇 |
2001年 | 202篇 |
2000年 | 252篇 |
1999年 | 158篇 |
1998年 | 93篇 |
1997年 | 58篇 |
1996年 | 66篇 |
1995年 | 67篇 |
1994年 | 49篇 |
1993年 | 64篇 |
1992年 | 35篇 |
1991年 | 42篇 |
1990年 | 45篇 |
1989年 | 44篇 |
1988年 | 42篇 |
1987年 | 41篇 |
1986年 | 23篇 |
1985年 | 13篇 |
1984年 | 21篇 |
1983年 | 17篇 |
1982年 | 21篇 |
1981年 | 26篇 |
1980年 | 14篇 |
1979年 | 16篇 |
1978年 | 6篇 |
1976年 | 3篇 |
1974年 | 3篇 |
1965年 | 3篇 |
排序方式: 共有7427条查询结果,搜索用时 187 毫秒
81.
Density of supercritical CO_2-tetrahydrofuran binary mixture and the partial molar volume of the cosolvent 总被引:1,自引:0,他引:1
The densities of supercritical CO2-tetrahydrofuran (cosolvent) binary mixture weremeasured at temperatures in range of 308.15 to 323.15 K and at pressure up to 16.5 MPa.The concentrations of tetrahydrofuran were from 0 to 0.57 mol/L.The partial molar volume of tetrahydrofuran was calculated based on the relationship between the density of the mixture and the concentration of the cosolvent.It is observed that the partial molar volume of the cosolvent is negative and the absolute value decreases with increasing pressure and the concentration of the cosolvent. 相似文献
82.
83.
84.
Ion-exchanger phase Spectrophotometry withp-nitrochlorophosphonazo (CPApN) has been developed for the determination of scandium. The linear range is 1–8 g of scandium in 50 ml of solution, using 0.8 g of resin, with an apparent molar absorptivity of 2.76 × 105 1 mol–1 cm–1. Aluminum and rare earth elements in reasonable amounts do not interfere. The method has been applied successfully to the determination of scandium in alloys, with relative standard deviations of 2–4%. 相似文献
85.
Shi Liang HUANG Yi LUO Zhi Shu HUANG Xian Zhang BU Pei Qing LIU Lin MA Yue Ming LI Albert S. C. CHAN Lian Quan GU 《中国化学快报》2006,17(6):769-772
Mansonone compounds represent a series of naturally occurring o-quinones mainly isolated from the heartwood of Mansonia Altissima1 and Ulmus Glabra2. Mansonone F contained oxaphenalene skeleton which was a relatively novel structure and rarely existed in … 相似文献
86.
聚醚聚氨酯双离子型离聚物的介电性能研究 总被引:1,自引:1,他引:1
以4,4'-二苯基甲烷二异氰酸酯(MDI)、N-甲基二乙醇胺(MDEA)和聚四氢呋喃(PTMD)以2:1:1(mol比)合成聚醚型聚氨酯,MDEA的叔胺基与γ-丙磺内酯反应,制备了不同磺化程度的双离子型离聚物.在不同温度与频率(-150-30℃,20Hz—100KHz)下,测定了其介电性能.结果表明,随离子化程度的提高,ε'增大,α弛豫介电损耗峰移向低温,说明相分离越趋完善;β弛豫单元的活化能(△Hβ)基本不变;α弛豫单元的活化能(△Hα)依次变小.介电测量结果与动态力学方法研究结果相吻合. 相似文献
87.
Shi-jun Zheng Kazuo Akagi Qun Xu Shao-kui Cao Qi-feng Zhou 《高分子科学》2006,(4):353-361
Novel shish-kebab type liquid crystalline poly(p-phenylenevinylene) derivatives were synthesized by Stille coupling reaction from 2,5-bis[(4-n-alkoxyl)benzoyloxy]1,4-dibromobenzene (monomer l) and 1,2-bis(tributylstannyl) ethylene (monomer 2). The polymers with alkoxy groups are soluble in common organic solvents and exhibit blue fluorescence. Both the cast film and the annealed film have large red-shifts in fluorescence spectra and show yellow fluorescence. The polymers with CN and NO2 groups show poor solubility and green fluorescence. All the polymers possess liquid crystalline smectic phases. The melting point (Tm) of the polymers decreases when the length of the alkoxy tails of the mesogenic units increases. The polymers are easily aligned under a magnetic field of 10 Tesla. It is found that the conjugated backbone and LC side chain are aligned perpendicular and parallel to the magnetic field, respectively. The polymers show optical dichroism in fluorescence spectra, suggesting that they are available for advance materials with linear optical polarization. 相似文献
88.
Knoevenagel condensation catalysed by poly(vinyl chloride) supported tetraethylenepentamine (PVC-TEPA) 总被引:1,自引:0,他引:1
Fen Dong Yi Qun Li Rong Feng Dai 《中国化学快报》2007,18(3):266-268
Poly(vinyl chloride) supported tetraethylenepentamine (PVC-TEPA) has been found to be an efficient catalyst for the Knoevenagel condensation. A wide range of aromatic aldehydes easily undergo condensations with ethyl cyanoacetate and malononitrile in the commercial 95% ethanol in refluxing using PVC-TEPA as catalyst to afford the desired products of good purity in moderate to excellent yields. A recycling study confirmed that the catalyst could be reused, the yield of the desired condensation product were not reduced. The merits of this protocol are environmentally benign, simple operation, convenient work-up and good yields. Furthermore, the catalyst can easily be recovered and reused at five times with comparable yields. 相似文献
89.
W/O型微乳液活化能和导电机理研究 总被引:15,自引:0,他引:15
电导行为是微乳液的重要性质之一。自Lagourette和Lagues发现了W/O型微乳液电导渗透(Percolation)现象后,人们开始了微乳液导电机理的研究。较流行的观点认为,界面层中表面活性剂分子的阴离子在微乳颗粒碰撞时发生跃迁而使W/O型微乳液具有导电性。 相似文献
90.