Crystal and molecular structure of crenatine carbonate

The crystal and molecular structure of 1-ethyl-4-methoxy-9H-pyrido[3,4b]indole (crenatine) carbonate C₁₄H₁₄N₂O·H₂CO₃, (MS, m/z 226)M _R 288.3, a-carboline alkaloid, has been determined from X-ray diffraction data. The compound crystallizes in the space group Pbca with cell parameters:a=11.616(4),b=18.450(8),c=12.992(5)Å,V=2784(2)ų,Z=8,D _calc=1.375 g cm^–3, (MoK)=0.71069Å,(Mo K)=0.94 cm^–1,F(000)=1216,R/R _w =8.2/10.3% for 1099 reflections. The ring system of the-carboline nucleus is planar. The title compound shows a two center hydrogen bond between the indole N-H group and the oxygen atom of a carbonate group. The structure does not display hydrogen bonding between-carboline groups but rather a bonding network involving the carbonate group.     

A certain functional algebra

We study the algebra of functions on the set of natural numbers with respect to the generalized convolution, generated by the generalized translation operator T_nf(k)=f(max (n, k)), n, k. With the help of the generalized Fourier transform, connected with this convolution, we establish numerous identities and recurrence relations, connecting, in particular, sums of powers of natural numbers.Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 42, No. 3, pp. 372–377, March, 1990.     

Consistency of decision processes

If a statistical or a voting decision procedure is used by several subpopulations and if each reaches an identical conclusion, then one might expect this conclusion to be the outcome for the full group. It is shown that this property fails to hold for large classes of decision procedures. The geometric reasons why the consistency does not hold are described. A general theorem is given to characterize the procedures that satisfy this property of weak consistency.This research was supported in part by NSF Grant IRI-8803505 and a Guggenheim Fellowship. Also, the author thanks a referee for some comments that stimulated certain revisions.     

A numerical analysis of chaotic behaviour in Bianchi IX models

In this paper we investigate the chaotic behaviour of the Bianchi IX cosmological models using techniques developed in the study of dynamical systems and chaotic behaviour. We numerically calculate the Lyapunov exponent, , and show that instead of converging to a constant value, it decreases steadily. We study this effect further by studying the Lyapunov exponent using short-time averages. We show that the usual method of calculating is invalid in the case of a cosmological model.     

Water 1H spin-lattice relaxation as a fingerprint of porous media

The 1H spin-lattice relaxation curves of water in samples of natural porous media can be thought of as "fingerprints" of the porous samples. Also the whole of traditional petrophysical properties (permeability, irreducible water saturation, etc.) can be thought of as "fingerprints" of the porous samples. The characteristics of the pore space determine on one hand the relaxation curve shape, and on the other the petrophysical properties. The understanding of this correspondence can contribute to a better definition of the concept of the architecture of a porous medium. At this purpose we have obtained 1H spin-lattice relaxation curves from a collection of standard sandstone cores of known petrophysical properties and characterized by the same surface properties. The results corroborate the idea that the structure of relaxation curves contains information on the distance scale and on the architecture of the pore space, even if it is difficult to extract it without ambiguities. Different methods of curve fitting were performed and compared with the aim of getting the maximum information from the relaxation curves. Several aspects of this kind of investigation indicate the analogies between 1H response of water confined in porous media and in biological tissues.     

Nonlinear properties of surface “screw” instability in symmetric semiconductor plates

For the first time we study the nonlinear properties of the surface screw instability (SSI) when waves are excited at both faces of a plate and the interaction between them must be taken into account. The nature of the SSI development and the stability of surface screw waves against modulation are examined. Diagrams of the regions where the SSI development is soft and explosive as well as the regions of modulated waves are given in the space of parameters characterizing the electro-hole plasma and external fields.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 30–34, April 1990.     

Theory of absorption and amplification spectra of a weak electromagnetic field by two-level quantum systems

A theory is developed of the absorption and amplification spectra of a weak (probe) electromagnetic field (EMF) by open two-level quantum systems in a strong quasiresonant EMF, assuming separability of the triplet spectrum components. The theory describes the intensity and the form of the spectral lines for arbitrary intensities and detunings of the strong EMF, and also the dependence of the parameters of the adiabatic relaxation on the frequency of the weak EMF. The influence of nonlinear dynamic effects (NDE) due to the dependence of the relaxation on the EMF parameters on the shape of the spectral lines is investigated. It is shown, in particular, that under certain conditions the NDE can lead to a nonlinear dynamic transformation of the dispersion of the sideband dispersion lines into Lorentzian lines and to a considerable increase of the absorption in the central region of the spectrum. Particular attention is paid to an investigation of the NDE on the characteristics of the central component of the spectrum. Methods and results of an investigation of the spectra in a basis of unperturbed wave functions in in a basis of dressed states are compared.Radiophysics Division, Lebedev Physics Institute. Translated from Preprint No. 117 of the Lebedev Physics Institute, Academy of Sciences of the USSR, Moscow, 1990.     

Disordered charge distributions and dielectric loss in extra dense flint glasses

The complex permittivities of some extra dense flint glasses (EDF glasses) have been studied. The dielectric features of the samples are dominated by their PbO content. Both refractive indices and dielectric losses exhibit a close relation to the concentration of Pb ions. The latter are located either at sites of the network atoms or filling the potential minima interstitially. They can be identified by their different relaxation mechanisms. The dispersion in the submillimeter wave and FIR area is characterized by a very broad distribution of comparably sharp resonant states. Thermal lens — or hysteresis effects can be excluded.     

Non-characteristic mixed problems for non-linear symmetric hyperbolic systems

In this paper the existence and uniqueness of solutions of the following initial boundary value problem for non-linear symmetric hyperbolic equations of the first order are shown, where M = I ⁺ ? S , has the same from as the Kreiss' condition, but S must be sufficiently small ( I ⁺ is the unit matrix in the space generated by eigenvectors of the matrix ? A · n? , corresponding to positive eigenvalues) and n? is a unit outward vector normal to the boundary. The main result of the paper is obtaining an a priori estimate for non-linear equations. This estimate is obtained for sufficiently small time and norms of given data functions. The existence of solutions is proved by the method of successive approximations, which can be used because at each step such properties as symmetry of matrices and the numbers of positive and negative eigenvalues of the matrix ? A · n? are assured. This can be done because we restrict our attention to such systems of equations for which these properties are satisfied for solutions from some neighbourhood of initial data u ₀. Therefore, using the fact that solutions in the class of continuous functions are sought, these properties can be satisfied for sufficiently small time. Moreover, some examples of initial boundary value problems for equations of hydrodynamics and magnetohydrodynamics are considered.