Application of ultrafine-dispersed diamonds in electroplating

The results obtained upon the electrochemical deposition of composite coatings containing ultrafine-dispersed diamonds produced by detonation synthesis are generalized. The main advantages of such coatings over the well-known composite electrochemical coatings are revealed.     

The mechanism of ionic conductivity in stabilized cubic zirconia

The electron-density functional method (in the gradient approximation) and the pseudopotential method are used to study the mechanism of ionic conductivity in the cubic phase of zirconia stabilized with magnesium or yttrium. The oxygen-ion migration in the stabilized zirconia is shown to be a two-stage process, which consists in the formation of active oxygen vacancies and in oxygen-ion jumps from one active vacancy to another. The total activation energy of these processes is calculated to be 1.0–1.5 eV, which agrees with experimental data.     

Photoanisotropic compositions with an extended spectral range of anisotropy

Experimental data for two-and three-component compositions (dyes embedded in gelatinous and polymeric matrices) that are Weigert-sensitive to polarized radiation in a wide spectral range are reported. It is shown that the matrix considerably affects the photoanisotropic properties of the compositions.     

Stability of the mechanical behavior of an arched TiNi strip under the conditions of the constrained shape memory effect

Unstable form changing (click) of an arched TiNi strip annealed at 773 K is investigated. After the annealing, the strip is placed into the grips of a deforming machine and is transferred to the martensitic state by bending in the direction opposite to its initial bend. Subsequent heating of the strip, which carries it to the austenitic state, is accompanied by a click under the conditions of constrained form changing. Analysis of the martensitic deformation in terms of the theory of diffuse martensitic transformations makes it possible to establish the conditions under which the form changing process becomes unstable.     

Solution of the Electrodiffusion Equations in the Quasi-Stationary Approximation

The electrodiffusion equations are solved together with the equation for the current running through the boundary of the examined system with the environment. The complete system of equations allows the volt-ampere characteristic of the system to be obtained for an arbitrary time dependence of the external potential. The procedure of finding the first-order approximation is developed to solve the system of electrodiffusion equations.     

Total cross section,inelasticity, and multiplicity distributions in proton-proton collisions

Multiparticle production in high-energy proton-proton collisions has been analyzed in the framework of the strongly correlated quark model of the hadron structure elaborated by the author. It is shown that inelasticity decreases at high energies and the violation of KNO scaling is a consequence of total cross-section growth and increases with collision energy masses of intermediate clusters.     

Effect of lattice deformation and phase transitions on the electronic spectra of TlGaS<Subscript>2</Subscript>, TlGaSe<Subscript>2</Subscript>, and TlInS<Subscript>2</Subscript> layered semiconductors

The effect of the lattice deformation on the electronic spectra of TlGaS₂, TlGaSe₂, and TlInS₂ layered semiconductor crystals is analyzed. It is shown that changes in the band gap of these semiconductors due to thermal expansion and a change in the composition under hydrostatic or uniaxial pressure can be described within a unified model of the deformation potential. The main feature of this model is the inclusion of deformation potentials with different signs, which is characteristic of other semiconductors with a layered structure. An analysis of the lattice deformation of the studied semiconductors in terms of the proposed model of the deformation potential has revealed that, in the immediate vicinity of the phase transitions, the crystal lattice under pressure undergo an unusual deformation.     

Mathematical Simulation of the Synthesis of cis-1,4-Polybutadiene on a Cobalt-Containing Catalyst in the Presence of Ethylene

Based on an analysis of experimental results and published data, the main elementary steps of the anionic coordination polymerization of butadiene rubber on a cobalt-containing catalyst in the presence of ethylene were found, and a mathematical model of the periodic process at an optimum water content was developed. The molecular-weight characteristics of the process depending on ethylene concentration were studied with the use of this model.     

Experience of Control over Process of Chemical-Informational Synthesis

Conditions under which various kinds of carbon nanoparticles are obtained by thermal oxidative conversion of methane in chlorine in the temperature range 20-500°C were studied. The influence exerted by conditions of synthesis of nanodispersed carbon on the properties of its samples was analyzed.