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941.
Mithlesh Kumar R. M. Kadam T. K. Seshagiri V. Natarajan A. G. Page 《Journal of Radioanalytical and Nuclear Chemistry》2004,262(3):633-637
Thermally stimulated luminescence (TSL) and electron paramagnetic resonance (EPR) investigations were carried out on gamma irradiated SrBPO5 samples doped with CeO2 and co-doped with CeO2 and Sm2O3. On gamma-irradiation at room temperature, BO3
2–, O2
– and O– radicals were produced. It was seen that the O– radical ion disappeared in the sample annealed at 500 K. It is proposed that the recombination between trapped electrons and O– radical ions results in transfer of recombination energy to the impurity centre Ce3+ resulting in TSL glow peak at 485 K. In the case of co-doped samples energy transfer occurs between Ce3+ to Sm3+ resulting in increase in the intensity of glow peak at 485 K.The authors are grateful to Dr. V. K. Manchanda, Head, Radiochemistry Division, BARC for his keen interest and encouragement during the course of this work. 相似文献
942.
E. V. McCloskey A. Dey R. M. Parr N. Aras A. Balogh J. Bostock A. Borell S. Krishnan G. Lobo L. L. Qin Y. Zhang S. Cvijetic V. Zaichick M. Lim-Abraham K. Bose S. Wynchank G. V. Iyengar 《Journal of Radioanalytical and Nuclear Chemistry》2004,259(2):341-345
In 1994, the International Atomic Energy Agency (IAEA) initiated a 5-year Co-ordinated Research Project (CRP) to determine
geographical and racial differences in peak bone mineral density (BMD) in men and women aged 15-49 years. The study demonstrates
that there are distinct global differences in BMD at the hip and spine in both men and women approximating to one population
standard deviation between populations with the highest and lowest BMD. These differences persist following adjustments for
age, sex and body size. Such information is valuable in understanding the reasons for global differences in fracture rate
and predicting future trends in fracture incidence.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
943.
L. I. Guseva G. S. Tikhomirova N. N. Dogadkin 《Journal of Radioanalytical and Nuclear Chemistry》2004,260(1):167-172
A simple and effective method has been developed for the continuous production of the short-lived isotope Pb as a homolog
of element 114 on the principle of a radionuclide generator. The method is based on the initial sorption of 227Ac or 223Ra on a small cation-exchange column, with subsequent “milking” of 211Pb (36.1 m) by a mixture of HCl/CH3OH. The optimum conditions for the repeated separation of 211Pb from radionuclides strongly sorbed by the cation-exchanger (Ac, Th, Ra, Pu, TPE) have been determined. Possibilities of
using the 211Pb generator for test experiments on the solution chemistry of element 114 have been shown. Advantages of aqueous alcohol
HCl solutions for the isolation of 211Pb (element 114) are discussed.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
944.
C. A. Laue D. Gates-Anderson T. E. Fitch 《Journal of Radioanalytical and Nuclear Chemistry》2004,261(3):709-717
This review focuses on dissolution/reaction systems capable of treating uranium metal waste to remove its pyrophoric properties.
The primary emphasis is the review of literature describing analytical and production-scale dissolution methods applied to
either uranium metal or uranium alloys. A brief summary of uranium's corrosion behavior is included since the corrosion resistance
of metals and alloys affects their dissolution behavior. Based on this review, dissolution systems were recommended for subsequent
screening studies designed to identify the best system to treat depleted uranium metal wastes at Lawrence Livermore National
Laboratory (LLNL).
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
945.
Peixiang Xing Gilles P. Robertson Michael D. Guiver Serguei D. Mikhailenko Serge Kaliaguine 《Journal of polymer science. Part A, Polymer chemistry》2004,42(12):2866-2876
A series of sulfonated poly(aryl ether ketone)s (SPAEKs) were prepared by aromatic nucleophilic polycondensation of 2,6‐dihydroxynaphthalene with 5,5′‐carbonyl‐bis(2‐fluorobenzenesulfonate) and 4,4′‐difluorobenzophenone. The structure and degree of sulfonation (DS) of the SPAEKs were characterized using 1H NMR spectroscopy. The experimentally observed DS values were close to the expected values derived from the starting material ratios. The thermal stabilities of the SPAEKs were characterized by thermogravimetric analysis, which showed that in acid and sodium salt forms they were thermally stable in air up to about 240 and 380 °C, respectively. Transparent membranes cast from the directly polymerized SPAEKs exhibited good mechanical properties in both dry and hydrated states. The dependence of water uptake and of membrane swelling on the DS at different temperatures was studied. SPAEK membranes with a DS from 0.72 to 1.60 maintained adequate mechanical properties after immersion in water at 80 °C for 24 h. The proton conductivity of SPAEK membranes with different degrees of sulfonation was measured as a function of temperature. The proton conductivity of the SPAEK films increased with increased DS, and the highest room temperature conductivity (4.2 × 10?2 S/cm) was recorded for a SPAEK membrane with a DS of 1.60, which further increased to 1.1 × 10?1 S/cm at 80 °C. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2866–2876, 2004 相似文献
946.
G. Ullrich D. Herzog R. Liska P. Burtscher N. Moszner 《Journal of polymer science. Part A, Polymer chemistry》2004,42(19):4948-4963
Camphorquinone (CQ), a widely used photoinitiator (PI) in dental applications, was covalently bonded to aromatic amines to enhance the rate of electron and proton transfer effect due to the close vicinity of the diketone and the amine group. 10‐bromocamphorquinone and 10‐bromomethylcamphorquinone were selected as suitable precursors for esterification with the carboxyl group containing aromatic amines based on 4‐dimethylaminobenzoic acid. Properties of the new photoinitiating systems were investigated by UV spectroscopy and differential scanning photocalorimetry in lauryl acrylate. Compared to physical mixtures, in all cases similar or even better performance was obtained. Surprisingly, 10‐acetyl derivatives 7 – 9 and 18 especially, were found to be highly reactive. Compared to CQ/ethyl 4‐dimethylaminobenzoate, the rate of photopolymerization was increased by a factor of up to 2. Intramolecular reaction was confirmed by photo‐differential scanning calorimetry experiments with varying PI concentrations. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4948–4963, 2004 相似文献
947.
Jeremy R. Lizotte Sara G. Anderson Timothy E. Long 《Journal of polymer science. Part A, Polymer chemistry》2004,42(7):1547-1556
A novel dinitroxide mediating agent that was suitable for stable free‐radical polymerization was synthesized and used in the block copolymerization of styrene and t‐butyl styrene. Quantitative yields of a novel dinitroxide based on 1,6‐hexamethylene diisocyanate and 4‐hydroxy‐2,2,6,6‐tetramethyl‐1‐piperidinyloxy were obtained. Various experimental parameters, including the nitroxide‐to‐initiator molar ratio, were examined, and it was determined that the polymerization was most controlled under conditions similar to those of conventional 2,2,6,6‐tetramethyl‐1‐piperidinyloxy‐mediated stable free‐radical polymerization. Moreover, the dinitroxide mediator proved to be a viable route for the facile two‐step synthesis of triblock copolymers of styrene and t‐butyl styrene. However, the dinitroxide mediation process resulted in a higher than expected level of nitroxide decomposition, which resulted in polymers possessing a terminal alkoxyamine and an adjacent hydroxylamine rather than a preferred internal bisalkoxyamine. This decomposition resulted in the formation of diblock copolymer species during the triblock copolymer synthesis. Gel permeation chromatography was used to monitor the chain‐end decomposition kinetics, and the determined observed rate constant (5.89 × 10?5 s?1) for decomposition agreed well with previous studies for other dinitroxide mediating agents. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1547–1556, 2004 相似文献
948.
Panagiota G. Fragouli Hermis Iatrou Nikos Hadjichristidis 《Journal of polymer science. Part A, Polymer chemistry》2004,42(3):514-519
A series of five tetrablock quarterpolymers of styrene, isoprene, dimethylsiloxane, and 2-vinylpyridine with molecular weights varying from 117 × 103 to 177 × 103 and having different compositions were synthesized. The synthesis was based on recent advances in the controlled high-vacuum anionic polymerization of hexamethylcyclotrisiloxane and on the selective linking of poly(dimethylsiloxane)lithium with the chlorosilane group of the heterofunctional linking agent chloromethylphenylethylene dimethylchlorosilane. Combined characterization results by size exclusion chromatography, membrane osmometry, and NMR spectroscopy suggested that the synthesized multiblock multicomponent polymers had a high degree of structural and compositional homogeneity. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 514–519, 2004 相似文献
949.
Thorsten Brand Kyle Ratinac Jeffrey V. Castro Robert G. Gilbert 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5706-5713
A method was developed for free‐radical polymerization in the confines of a hollow latex particle. Hollow particles were prepared via the dynamic swelling method from polystyrene seed and divinylbenzene and had hollows of 500–1000 nm. So that these hollow poly(divinylbenzene) particles could function as submicrometer reactors, the particles were filled with a monomer (N‐isopropylacrylamide) via the dispersion of the dried particles in the molten monomer. The monomer that was not contained in the hollows was removed by washing and gentle abrasion. Free‐radical polymerization was then initiated by γ radiolysis in the solid state. Transmission electron microscopy showed that poly(N‐isopropylacrylamide) formed in the hollow interior of the particles, which functioned as submicrometer reactors. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5706–5713, 2004 相似文献
950.
Michael A. Brook Yang Chen Kui Guo Zheng Zhang Wen Jin Anil Deisingh Jorge Cruz-Aguado John D. Brennan 《Journal of Sol-Gel Science and Technology》2004,31(1-3):343-348
The preparation of discrete polyol based silane precursors derived from glycerol by a simple one-pot process is described. These polyol-based silanes could be hydrolyzed under mild pH conditions and upon gelation resulted in the formation of optically clear, monolithic, mesoporous silica. The hydrolysis and condensation reactions lead to cure rates that are very sensitive to ionic strength, but are almost unaffected by pH in contrast to those of alkoxysilanes derived from primary alcohols such as Si(OEt)4. Residual glycerol in the silica monolith could be removed by washing, or could be left in the silica to reduce the magnitude of shrinkage during long term storage. The biocompatible glyceroxysilane precursors lead to materials that were able to retain the activity of entrapped enzymes over repeated cycles of use for periods of up to several months. 相似文献