Diffusive motion of iron microcrystals studied by Mössbauer spectroscopy

A new model is presented which explains well the dramatic decrease of the Mössbauer line intensities with raising temperatures for freely dispersed iron microscrystals. In contrast to other theories which consider mainly vibration to be responsible we discuss here the decrease in terms of large amplitude diffusive rotational or translational jumps of the particles. Such diffusive jumps lead — in agreement with the observation — to a strong reduction of the Mössbauer-intensity without broadening the line width in a noticeable way. The typical potential well for a diffusing particle in an equilibrium position is derived quantitatively to be 13 meV. The model might be important also for a new understanding of the dynamics of catalytic clusters either in contact with each other or with larger solid surfaces.Part of this work was supported by the DFG Sonderforschungsbereich 306, Konstanz     

A Study of premixed propagating flame vortex interaction

Experimental data is presented for the interaction between a propagating flame and a simple vortex flow field structure generated in the wake of solid obstacles. The interaction between gas movement and obstacles creates vortex shedding forming a simple flow field recirculation. The presence of the simple turbulent structure within the gas mixture curls the flame front increasing curvature and enhancing burning rate. A novel twin camera Particle Image Velocimetry, PIV, was employed to characterise the flow field recirculation and the interaction with the flame front. The technique allowed the quantification of the flame/vortex interaction. The twin camera technique provides data to define the spatial variation of both the velocity of the flow field and flame front. Experimentally obtained values of local flame displacement speed and flame stretch rate are presented for simple flame/vortex interactions.     

Cosmic γ-ray bursts: Observations and modeling

It is now commonly accepted that cosmic γ-ray bursts (GRBs) are of cosmological origin. This conclusion is based on the statistical analysis of GRBs and the measurements of line redshifts in GRB optical afterglows, i.e., in the so-called long GRBs. In this review, the models of radiation and models of GRB sources are considered. In most of these models, if not in all of them, the isotropic radiation cannot provide the energy release necessary for the appearance of a cosmological GRB. No correlation is noted between the redshift, the GRB-spectrum shape, and the total detected energy. The comparison between data obtained in the Soviet experiment KONUS and the American experiment BATSE shows that they substantially differ in statistical properties and the detection of hard x-ray lines. The investigation of hard gamma (0.1–10 GeV) afterglows, the measurement of prompt optical spectra during the GRB detection, and the further investigation of hard x-ray lines is of obvious importance for gaining insight into the GRB origin. Observations of two bright optical GRB afterglows point to the fact that an initially bright optical flare is directly related to the GRB itself, and the subsequent weak and much more continuous optical radiation is of a different nature. The results of observations of optical GRB afterglows are discussed. They point to the fact that the GRBs originate in distant galaxies with a high matter density, where intense star formation takes place. The interaction of the cosmological GRB radiation with a dense surrounding molecular cloud results in the appearance of long-duration (up to 10 years) weak optical afterglows associated with the heating and reradiation of gas. Results of 2D numerical simulation of the heating and reradiation of gas in various variants of the relative disposition of GRB and molecular clouds are presented. In conclusion, the possible relation between the so-called short GRBs and recurrent sources of soft γ rays in our Galaxy, the so-called “soft gamma repeaters,” is discussed.     

Nonstoichiometry and low-temperature magnetic properties of FeSi crystals

The results of experimental and theoretical studies of the low-temperature properties of FeSi crystals are presented. The specific features of the magnetic susceptibility are shown to be related to the superparamagnetic behavior of impurity clusters. The thermomagnetic hysteresis phenomena observed are explained using the model of exchange-coupled clusters.     

Laser-induced breakdown threshold and fracture versus the nanostructure of two-phase glass

The radiation hardness and mechanical strength of single-and two-phase glasses are studied for the case when nanosecond laser pulses (λ= 1.06 μm, τ_0.5 ≈ 12.5 ns) are focused inside the material. Laser interferometry is applied to measure the displacement of the free surface, find optical breakage thresholds, and carry out the fractographic analysis of damaged regions. It is shown that breakdown channels and damage regions develop in a nonlinear manner according to optical breakdown mechanisms, changing each other with an increase in the laser energy. The strength of the two-phase glass is found to be more than four times that of the single-phase glass, although their elastic properties differ insignificantly. Such a considerable difference in the hardness of these materials with chemically similar constitutents is attributed to the presence of the double-lattice nanometer-scale structure of the two-phase glass.     

Visualization of industrial engineering data in Augmented Reality

This paper presents an innovative application of Augmented Reality (AR) techniques in the field of industrial engineering in which the user explores data from numerical simulations or the results of measurements and experiments, superimposed to the real object that they refer to. The user observes the object through a tablet PC, used as a video see-through handheld display. Data are visualized superimposed to the real object that represents a spatial reference relative to which the user can refer to, so the exploration is more natural compared to a traditional visualization software. Moreover, we have developed a new framework, called VTK4AR, that provides a set of useful software classes for the rapid development of AR applications for scientific visualization. VTK4AR is built on top of VTK (an open source API for scientific visualization), so it will be possible to employ a wide range of visualization techniques in many application fields, and moreover, it is possible to interactively manipulate data-sets in order to achieve a more effective way of visualization.     

Sorption of uranium, radium, and thorium from saline solutions on hydrolyzed wood lignin

Sorption of U, Ra, and Th from multicomponent aqueous salt solutions on hydrolyzed wood lignin is studied. The mechanism of radionuclide sorption from saline solutions is suggested on the basis of the results of sequential extraction.     

Synthesis and properties of carbon-chain polymers with pendant 1,3,4-oxadiazole rings

Carbon-chain polymers with 1,3,4-oxadiazole rings were prepared by radical polymerization and polymer-analogous transformations. The kinetic relationships of the polymerization of vinyl-1,3,4-oxadiazole monomers and some properties of the resulting polymers were studied. The thermodynamics of interaction of poly-2-vinyl-5-methyl-1,3,4-oxadiazole, a nonionic water-soluble polymer, with water was examined.