Optical detection of NO3 and NO2 in “pure” HNO3 vapor,the liquid-phase decomposition of HNO3

Flowing and static gas-phase samples of HNO₃ in O₂ and N₂ were analyzed by long-path ultraviolet/visible (UV/VIS) spectroscopy to reveal the presence of both NO₂ and NO₃, the concentrations of which were calculated using differential absorption cross sections. NO₂ is produced predominantly by the heterogeneous decomposition of HNO₃, whereas NO₃ is generated in the gas phase by the thermal decomposition of N₂O₅, a product of the self-disproportionation of liquid HNO₃. © 1993 John Wiley & Sons, Inc.     

The effect of radiofrequency modulation of 57Fe hyperfine interaction by rotating magnetic field

The effect of ⁵⁷Fe hyperfine interaction radiofrequency (rf) modulation by external rotating magnetic field was studied in thin Permalloy foil by means of Mössbauer spectroscopy. The rf effect was investigated as a function of intensity for several rf field frequencies. The experiments show that the external rotating rf field causes considerable changes in the hyperfine pattern. The obtained spectra are in disagreement with those obtained by Perlow [Phys. Rev. 172 (1968) 319]. They also are inconsistent with magnetostriction hypothesis. Proceeding from the Mössbauer spectrum analysis one may conclude that the magnetization of investigated foil changes its direction in a complex manner. However, the undertaken experiments show that the essential number of Mössbauer nuclei experience the rotating magnetic field influence.     

An application of radon inversion to diffraction tomography

Basic equations of linear computer tomography are considered; a connection of the mathermatical formulation of problems of computer tomography with problems of integral geometry is indicated; the properties of the Radon transform for even- and odd-dimensional spaces are analyzed, and applications of Radon inversion to problems of diffraction tomography are presented. Bibliography: 5 titles. Translated fromZapiski Nauchnykh Seminarov POMI, Vol. 230, 1995, pp. 264–277. Translated by V. N. Troyan.     

Inclusive two-jet production at HERA: direct and resolved cross sections in next-to-leading order QCD

We have calculated inclusive two-jet cross sections in next-to-leading order QCD for low Q ² ep collisions superimposing direct and resolved contributions. Infrared and collinear singularities in the virtual and real contributions are cancelled with the phase space slicing method. Various inclusive two-jet distributions have been computed. The results are compared with recent data from the ZEUS collaboration at HERA.     

Role of stationary photon statistics in a high-Q cavity mode while it is exciting the active laser medium

It has been shown by Yu. M. Golubev, M. I. Kolobov, and I. V. Sokolov, Zh. éksp. Teor. Fiz. 111, 1579 (1997) [JETP 84, 864 (1997)], that when an optical cavity is excited by external radiation from a sub-Poisson laser the cavity mode may be in either a sub-Poisson or a Poisson stationary state. This is not important for a resonant medium which is excited into the upper laser level while interacting with this mode inside the cavity. The degree of regularity of the excitation will be identical to that of the initial light flux incident on the cavity, and this ultimately ensures the same sub-Poisson lasing as for strictly regular pumping of the resonant medium. Zh. éksp. Teor. Fiz. 113, 1223–1234 (April 1998)     

Positron annihilation in polycrystalline metals

The empirical relation θ _p ⁶ /I _p=aK (where θ _p is the limiting angle of the parabolic component in the angular distributions of annihilation photons in metals, I _p is the integrated contribution of this component, K=1, 2, 3, ... is an integer, and a is a constant independent of the type of metal) observed earlier has been tested on magnesium, aluminum, copper, zinc, lead, and bismuth samples. The validity of this relation has been substantiated. The value of the dimensionless constant a has been determined and was found to coincide within experimental error with the result obtained in previous measurements. It is shown that the value of K for the same metal but for different samples may be different. It is conjectured that this may be due to different defect concentrations in samples. Fiz. Tverd. Tela (St. Petersburg) 40, 600–602 (April 1998)     

The multiple-scale wave equation

An analytic and numerical study of the behavior of the linear nonhomogeneous wave equation of the form ε²u_tt = Δu + tf with high wave speed (ε 1) is carried out. This study was initially motivated by meteorological observations which have indicated the presence of large spatial scale gravity waves in the neighborhood of a number of summer and winter storms, mainly from visible images of ripples in clouds in satellite photos. There is a question as to whether the presence of these waves is caused by the nearby storms. Since the linear wave equation is an approximation to the full system describing pressure waves in the atmosphere, yet is considerably more tractable, we have chosen to analyze the behavior of the linear nonhomogeneous wave equation with high wave speed. The analysis is shown to be valid in one, two, and three space dimensions. Partly because of the high wave speed, the solution is known to consist of behavior which changes on two different time scales, one rapid and one slow. Additionally, because of the presence of the nonhomogeneous forcing term tf, we show that there is a component of the solution which will vary only on a very large spatial scale. Since even the linearized wave equation can give rise to persistent large spatial scale waves under the right conditions, the implication is that certain storms could be responsible for the generation of large-scale waves. Numerical simulations in one and two dimensions confirm analytic results.     

Experimental Determination of Four-Time Stimulated Echoes in Liquids, Colloidal Suspensions, and Crystals

Four-time stimulated echo experiments have been used to monitor the temporal evolution of the reorientation rates of deuterated molecules or colloidal suspensions. We present extended phase cycles for this seven-pulse experiment. In order to test its performance three vastly different materials are chosen. These include a crystal in which the molecules carry out well-defined 180° flips and a supercooled liquid characterized by a distribution of jump angles centered around 10°. As an example for rotational diffusion, data on a concentrated suspension of polystyrene spheres in a viscous medium are presented.     

Selective quenching of tryptophanyl fluorescence in bovine serum albumin by the iodide ion

Modified Stern-Volmer equation is obeyed by bovine serum albumin (BSA)-iodide system showing selective quenching of tryptophanyl fluorescence of BSA. The fraction of accessible protein fluorescence is 0.56 and the effective Stern-Volmer constant is 290 M^-1 at pH 7.4 in 0.005 M phosphate buffer at 25°C. Collisional quenching is operative both in the BSA -I⁻¹ system and the model system, tryptophan-I⁻¹. It is supported by the observed relationship between the ratio of quenching rate constants (k _q ) and diffusion coefficients and alsok _q with bulk viscosity.