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951.
R. L. Safiullin L. R. Enikeeva S. Yu. Serenko V. D. Komissarov G. A. Tolstikov 《Russian Chemical Bulletin》1991,40(2):280-284
Alkanesulfonic peracids RSO4H effectively oxidize olefins to the corresponding epoxides. The kinetics and mechanism of this reaction are studied. It was shown that both the monomer and dimer form of the peracid act as oxidizing agents. The dependence of the weight constant of the reaction of monomer RSO4H with substituted acyclic olefins on the structure of the latter is described by the Taft equation. A linear correlation is established between log k2 and the inductive constants of the substituents on the oxygen atom in the peracid.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 333–337, February, 1991. 相似文献
952.
Exact cylindrically symmetric solutions are obtained for a class of interacting scalar and vector fields in a rotating Godel Universe. We select those with the properties of solitons with smooth decrease of the fields to asymptotics and those with sharp boundaries (droplets). It is shown that only some of the droplets are stable with respect to perturbations that preserve cylindrical symmetry.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 24–27, May, 1991. 相似文献
953.
V. G. Artjuschenko K. I. Kalaidjian M. M. Mirakian 《International Journal of Infrared and Millimeter Waves》1991,12(10):1175-1185
The results of the efficiency of low-mode excitation of a parallel-plate hollow metallic waveguides (HMW) as a function of beam and waveguide parameters are represented. Coupling of two waveguides is also discussed. 相似文献
954.
L. Cianchi F. Del Giallo F. Pieralli M. Mancini S. Sciortino G. Spina 《Hyperfine Interactions》1991,66(1-4):387-391
Mössbauer parameters of151Eu in Eu1+x Ba2?x Cu3O7+δ have been studied as a function of temperature, forx=0.15 andx=0.25. The areas of the absorption spectra for the two samples are almost equal. This could mean that thef-Mössbauer factor for151Eu at the barium sites is much smaller than that for151Eu at the rare earth sites, i.e. we only observe the spectra of the latter sites. According to this, the fits of the spectra with a single quadrupolar pattern and with two quadrupolar patterns have given equivalent χ2 values. 相似文献
955.
D. G. Sannikov 《Physics of the Solid State》1997,39(7):1139-1142
A theoretical temperature-electric field phase diagram is constructed for thiourea SC(ND2)2 using a phenomenological approach based on the representation of the thermodynamic potentials for all phases. The theoretical
diagram is compared with the experimental diagram.
Fiz. Tverd. Tela (St. Petersburg) 39, 1282–1286 (July 1997) 相似文献
956.
An estimate of the decomposition stability of the Poisson distribution is obtained under the condition that the components
are identical. The estimate is much sharper than that in the general case.
Supported in part by the International Science Foundation (grant No. NJY000).
Proceedings of the XVII Seminar on Stability Problems for Stochastic Models. Kazan, Russia, 1995, Part II. 相似文献
957.
A. A. Collyer D. W. Clegg M. Morris D. G. Parker G. W. Wheatley G. C. Corfield 《Journal of polymer science. Part A, Polymer chemistry》1991,29(2):193-200
High molecular weight alternating block copolymers of polyethesulphone (PES) and polydimethylsiloxane (PDMS) were prepared by the condensation of dimethylamino-terminated PDMS oligomers and hydroxy-terminated PES oligomers in 1,2-dichlorobenzene. Microphase separation of the block copolymers at exceptionally short block lengths was observed by differential scanning calorimetry (DSC) and transmission electron microscopy (TEM). The Si? O? C intersegment linkage in these materials appeared to display poor hydrolytic stability which is contrary to results obtained for other block copolymers. 相似文献
958.
A. Jarid M. Aaid Y. Legoux J. Merini M. Loudet D. Gonbeau G. Pfister-Guillouzo 《Chemical physics》1991,150(3):353-360
The electronic and structural characteristics of CrF5, CrF4, RuF5 and RuF4 were studied. Ab initio (SCF-CI) calculations were performed with different structures and spin states for each complex. The favored conformation always corresponds to the highest multiplicity: doublet for CrF5 in D3h, triplet for CrF4 in Td, quadruplet for RuF5 in C4v and quintuplet for RuF4 in D4h symmetry. 相似文献
959.
In this work, on the basis of a semiempirical model of bonding forces that allows for three-particle interaction and uses the pseudopotential method, the mechanical and electrical properties of barium chalcogenides are studied at hydrostatic pressure. Equations of state are formulated from hydrostatic compression, parameters of the type B1–B2 structural phase transitions are calculated, the change in the energy band spectrum under the influence of the pressures is studied, and an estimate is made of the critical amount of compression that induces a dielectric-metal phase transition. The results obtained are in agreement with the available data.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 44–52, November, 1991. 相似文献
960.
M. A. Macrì C. Del Gratta L. Di Donato S. Di Luzio G. L. Romani S. Della Penna A. Pasquarelli 《Il Nuovo Cimento D》1994,16(5):425-432
Summary A preliminary study is here reported on a new potential marker for biomagnetic measurements. The marker consists of superparamagnetic
polymer microspheres which were detected in the presence of external steady magnetic fields by means of an r.f.-SQUID magnetometer.
The particles were prepared in samples differing in the concentration value and immersed in a homogeneous magnetic field of
variable intensity. A simple model was taken into account for the distribution of the microspheres in the samples, so that
the theoretical values were compared to the marker field values measured by the biomagnetic sensor. The overall sensitivity
of the experimental apparatus and the minimum concentration value of the marker were then estimated. 相似文献