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排序方式: 共有252条查询结果,搜索用时 15 毫秒
151.
Kiyoshi Suzuki Takahiro Totsuka Daisuke Ishiguro Shun Okubo Hidetaka Tobita 《大分子反应工程》2021,15(1):2000040
A following new interpretation of apparent induction period is proposed considering the experimental results obtained: octamethylcyclotetrasiloxane (D4) is activated by the reaction with acid to generate an activated derivative (A4). A4 reacts with D4 to generate A8, an active species containing eight dimethylsiloxane units. A8 backbites to generate mostly A4 and D4, which causes retardation in polymerization, but occasionally to form A3 and D5. A3 is highly reactive, and when the concentration of A3 exceeds a certain limit, much Ai where i is large enough is formed and promotes fast growth of chain at the interfacial area due to high concentration of D4. The interpretation assumes that A3 accelerates growth of chain faster than other species, and that A8 tends to backbite rather than grow. The interpretation is supported by the experimental results of polymerization conducted with D4 and D3, or D5 and D3 charged. 相似文献
152.
Fujii K Seki S Fukuda S Kanzaki R Takamuku T Umebayashi Y Ishiguro S 《The journal of physical chemistry. B》2007,111(44):12829-12833
Anion conformation of a low-viscosity room-temperature ionic liquid 1-ethyl-3-methylimidazolium bis(fluorosulfonyl) imide (EMI+FSI-) has been studied by Raman spectra and theoretical DFT calculations. Three strong Raman bands were found at 293, 328, and 360 cm(-1), which are ascribed to the FSI- ion. These Raman bands show significant temperature dependence, implying that two FSI- conformers coexist in equilibrium. This is supported by theoretical calculations that the FSI- ion is present as either C2 (trans) or C1 (cis) conformer; the former gives the global minimum, and the latter has a higher SCF energy of about 4 kJ mol(-1). Full geometry optimizations followed by normal frequency analyses show that the observed bands at 293, 328, and 360 cm(-1) are ascribed to the C2 conformer. The corresponding vibrations at 305, 320, and 353 cm(-1) were extracted according to deconvolution of the observed Raman bands in the range280-400 cm(-1 )and are ascribed to the C1 conformer. The enthalpy DeltaH degrees of conformational change from C2 to C1 was experimentally evaluated to be ca. 4.5 kJ mol(-1), which is in good agreement with the predicted value by theoretical calculations. The bis(trifluoromethanesulfonyl) imide anion (TFSI-) shows a conformational equilibrium between C1 and C2 analogues (DeltaH degrees = 3.5 kJ mol(-1)). However, the profile of the potential energy surface of the conformational change for FSI- (the F-S-N-S dihedral angle) is significantly different from that for TFSI- (the C-S-N-S dihedral angle). 相似文献
153.
T. Nozaki A. Satoh H. Muraoka J. Ishiguro K. Yoda K. Ogawa 《Journal of Radioanalytical and Nuclear Chemistry》1999,239(3):661-665
Aerosol particles of99mTc-labeled carbon were prepared by sublimation and introduced in various liquid media. The adsorption of the aquasol and organosol
particles were studied for various adsorbing substances and media, with the effect of surface treatment and voltage application.
The particles often accumulated at the aqueous-organic interface, and also on the vessel surface in the presence of both aqueous
and organic phases. The distribution of the particles was examined by a gamma-camera for different organic phases under various
concentrations of electrolytes in the aqueous phase. 相似文献
154.
Keiichi Kamada Kouichi Nawashiro Fumiyasu Tamagawa Cha-Yeol Lee Hiroshi Yoshida Sunao Kawasaki Ritoku Ando Masaru Masuzaki 《International Journal of Infrared and Millimeter Waves》2000,21(9):1441-1449
A relativistic electron beam (500 keV, 200 A, 10 ns) generated magnetically tunable microwave radiation in a frequency range of 9-13 GHz when it is injected into an X-band rectangular waveguide immersed in a uniform axial magnetic field (4-10 kG). The mechanism of the microwave radiation was identified as the gyrotron backward wave interaction. The output power of the radiated microwave increased exponentially with the increase of the cavity length. 相似文献
155.
Foundations of Chemistry - A large variety of periodic tables of the chemical elements have been proposed. It was Mendeleev who proposed a periodic table based on the extensive periodic law and... 相似文献
156.
The small heat shock proteins (sHSPs) solubilize thermo-denatured proteins without adenosine triphosphate energy consumption to facilitate protein refolding. sHSP20.8 is one of the silkworm (Bombyx mori) sHSPs having only one cystein in the N-terminal domain: Cys43. We report a simple measurement of oligomeric transition of sHSP20.8 using high hydrostatic pressure native polyacrylamide gel electrophoresis (high hydrostatic pressure (HP) native polyacrylamide gel electrophoresis (PAGE)). At ambient pressure under oxydative condition, the native PAGE of thermal transition of sHSP20.8 oligomer displayed a cooperative association. In contrast, HP native PAGE clearly demonstrated that sHSP20.8 dissociated at 80 MPa and 25°C, and the resultant molecular species gradually reassociated with time under that condition. In addition, the reassociation process was suppressed in the presence of the reductant. These results are consistent with the idea that sHSP20.8 oligomer temporally dissociates at the first thermo-sensing step and reassociates with the oxidation of Cys43. 相似文献
157.
K. Murata H. Anzai K. Kajimura T. Ishiguro G. Saito 《Molecular Crystals and Liquid Crystals》2013,570(1):639-644
Abstract Superconducting transition of (TMTSF)2ClO4 was studied by conductivity measurements along the most conductive a-axis in magnetic fields applied along three different principal crystallographic axes. The GL coherence lengths at OK along the a-, b-, and c*-axes, ?a(0)≈ 600A, ?(0) ≈ 540A, and ?c*(0) ≈ 60A were obtained from the measurements of the temperature dependence of the upper critical field HC2 near the transition temperature. The anisotropy is discussed in terms of the dimensionality arising from the crystal structure and of the conductivity anisotropy in the normal state. 相似文献
158.
Maity N Wattanakit C Muratsugu S Ishiguro N Yang Y Ohkoshi S Tada M 《Dalton transactions (Cambridge, England : 2003)》2012,41(15):4558-4565
A site-isolated SiO(2)-supported Ru-monomer complex, whose structure was characterized by means of solid-state NMR, XPS, UV/vis, and Ru K-edge EXAFS, was found to be efficient for sulfoxidation using an O(2)/aldehyde system. Significant enhancement of sulfoxidation rates was observed on the SiO(2)-supported Ru complex for various sulfide derivatives. 相似文献
159.
Weng Z Muratsugu S Ishiguro N Ohkoshi S Tada M 《Dalton transactions (Cambridge, England : 2003)》2011,40(10):2338-2347
Molecularly imprinted Ru-complex catalysts acting in water were prepared on a SiO(2) surface by molecular imprinting of a SiO(2)-supported Ru-complex using organic polymers as surface matrix overlayers. (R)-1-(o-fluorophenyl)ethanol, which is one of the hydrogenated products of o-fluoroacetophenone, was imprinted on the supported Ru-complex as a template, and an active Ru-complex with a shape-selective reaction space (molecularly imprinted cavity) was prepared inside the wall of the hydrophobic organic polymer matrix overlayers. Structures of the SiO(2)-supported and molecularly imprinted Ru catalysts were characterized by means of solid-state NMR, XPS, XRF, ICP, UV/vis, XAFS, TGA, and SEM. The molecularly imprinted Ru catalysts exhibited fine shape selectivity and enantioselectivity for the asymmetric transfer hydrogenation of o-fluoroacetophenone and its derivatives. 相似文献
160.
A new polyketide, untenolide A (1), has been isolated from an Okinawan marine sponge Plakortis species, and the structure was elucidated from spectroscopic data and X-ray analysis. Untenolide A (1) is a new polyketide possessing a fused-pentacyclic skeleton with two hexadecanyl chains. 相似文献