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11.
Fumio Hiai 《Linear and Multilinear Algebra》1994,36(4):239-249
The equality cases in several matrix norm (trace) inequalities are characterized. Norm inequalities of Golden-Thompson type and of its complement type are treated as well as a logarithmic trace inequality and norm inequalities for matrix exponentials. 相似文献
12.
Fumio Sanda Ritsuya Kawasaki Masashi Shiotsuki Toshio Masuda 《Journal of polymer science. Part A, Polymer chemistry》2007,45(19):4450-4458
Novel chiral acetylene monomers containing carbazole, 2‐ethynyl‐9‐[(S)‐2‐methylbutoxycarbonyl]carbazole ( 1 ), 3‐ethynyl‐9‐[(S)‐2‐methylbutoxycarbonyl]carbazole ( 2 ), 2‐ethynyl‐9‐[(S)‐2‐methylbutyl]carbazole ( 3 ), and 2‐ethynyl‐9‐[(S)‐4‐methylhexyl]carbazole ( 4 ) were synthesized and polymerized with [(nbd)RhCl]2? Et3N. The corresponding polyacetylenes with number‐average molecular weights ranging from 68,700 to 310,000 were obtained in good yields. Poly( 1 ) exhibited a large specific rotation and an intense Cotton effect in toluene, indicating that it formed a helix with predominantly one‐handed screw sense, while the other three polymers showed no evidence for taking a helical structure. Poly( 1 ) largely decreased the CD intensity upon heating from ?10 to 60 °C. Poly( 1 ) showed a Cotton effect in film state in a manner similar to solution state. No chiral amplification was observed in the copolymerization of 1 with achiral 2‐ethynyl‐9‐tert‐butoxycarbonylcarbazole ( 5 ). © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4450–4458, 2007 相似文献
13.
Toshiki Kono Toshikazo Sakaguchi Yanming Hu Masashi Shiotsuki Fumio Sanda Toshio Masuda 《Journal of polymer science. Part A, Polymer chemistry》2006,44(20):5943-5953
Phenylacetylene (PA) derivatives having two polar groups (ester, 2a – d ; amide, 4) or one cyclic polar group (imide, 5a – c ) were polymerized using (nbd)Rh+[(η6‐C6H5)B?(C6H5)3] catalyst to afford high molecular weight polymers (~1 × 106 – 4 × 106). The hydrolysis of ester‐containing poly(PA), poly( 2a) , provided poly(3,4‐dicarboxyPA) [poly ( 3 )], which could not be obtained directly by the polymerization of the corresponding monomer. The solubility properties of the present polymers were different from those of poly(PA) having no polar group; that is, poly( 2a )–poly( 2d ) dissolved in ethyl acetate and poly( 4 ) dissolved in N,N‐dimethylformamide, while poly(PA) was insoluble in such solvents. Ester‐group‐containing polymers [poly( 2a )–poly( 2d )] afforded free‐standing membranes by casting from THF solutions. The membrane of poly( 2a ) showed high carbon dioxide permselectivity against nitrogen (PCO2/PN2 = 62). © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5943–5953, 2006 相似文献
14.
Synthesis and structures of the title compounds 2a–d are described. In spite of non-parallel orientation of the two base rings, fairly large hypochromism was observed for 2a–d. 相似文献
15.
The title racemate-to-conglomerate transformation which occurs in the solid state on heating or contact with MeOH vapour has been studied by IR and DTA spectral measurements, microscopic observation, and by X-ray structural and X-ray powder diffraction analysis. 相似文献
16.
17.
Some o-xylylene (o-quinodimethane) derivatives were isolated as stable cyrstalline materials. A strong through-bond interaction in tetracyanoethylene addition product of tetraphenylbenzodicyclobutadiene ( is suggested. 相似文献
18.
19.
Fumio Hamada Kyoko Ishikawa Riko Ito Hisanori Shibuya Sanyo Hamai Iwao Suzuki Tetsuo Osa Akihiko Ueno 《Journal of inclusion phenomena and macrocyclic chemistry》1994,20(1):43-51
-Cyclodextrin with two sodium anthranilate moieties (1) has been prepared as a sensor for detecting organic compounds including terpenoids and steroids. Compound1 shows a pure monomer fluorescence whose intensity is increased or decreased upon addition of the guest species examined. In this system, the sodium anthranilate moieties act either as a spacer, which enables the cyclodextrin to form a 1:1 host-guest complex by narrowing the -cyclodextrin cavity, or as a hydrophobic cap.1 recognizes steroids with much higher sensitivity than terpenoids, in which the appended moieties act as a hydrophobic cap for terpenoids and a spacer for steroids, respectively. 相似文献
20.
Hiroshi Saito Hitoshi Kurabe Eiichi Suzuki Fumio Watari 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》1995,51(14)
The IR spectra (4000-250 cm−1) of CH3SCl and CD3SCl in solid argon have been obtained. Fundamental vibrations, except the torsional vibrations, have been assigned. Normal coordinate analysis has been carried out omitting the torsional modes. 相似文献